Planar perovskite solar cells (PSCs) made entirely via solution processing at low temperatures (<150°C) offer promise for simple manufacturing, compatibility with flexible substrates, and perovskite-based tandem devices. However, these PSCs require an electron-selective layer that performs well with similar processing. We report a contact-passivation strategy using chlorine-capped TiO2 colloidal nanocrystal film that mitigates interfacial recombination and improves interface binding in low-temperature planar solar cells. We fabricated solar cells with certified efficiencies of 20.1 and 19.5% for active areas of 0.049 and 1.1 square centimeters, respectively, achieved via low-temperature solution processing. Solar cells with efficiency greater than 20% retained 90% (97% after dark recovery) of their initial performance after 500 hours of continuous room-temperature operation at their maximum power point under 1-sun illumination (where 1 sun is defined as the standard illumination at AM1.5, or 1 kilowatt/square meter).

https://science.sciencemag.org/content/sci/early/2017/02/01/science.aai9081.full.pdf

Efficient and stable solution-processed planar perovskite solar cells via contact passivation.

The photovoltaics of organic–inorganic lead halide perovskite materials have shown rapid improvements in solar cell performance, surpassing the top efficiency of semiconductor compounds such as CdTe and CIGS (copper indium gallium selenide) used in solar cells in just about a decade. Perovskite preparation via simple and inexpensive solution processes demonstrates the immense potential of this thin-film solar cell technology to become a low-cost alternative to the presently commercially available photovoltaic technologies. Significant developments in almost all aspects of perovskite solar cells and discoveries of some fascinating properties of such hybrid perovskites have been made recently. This Review describes the fundamentals, recent research progress, present status, and our views on future prospects of perovskite-based photovoltaics, with discussions focused on strategies to improve both intrinsic and extrinsic (environmental) stabilities of high-efficiency devices. Strategies and challenges regardi...

Halide Perovskite Photovoltaics: Background, Status, and Future Prospects

Multi-Criteria Decision Aid (MCDA) or Multi-Criteria Decision Making (MCDM) methods have received much attention from researchers and practitioners in evaluating, assessing and ranking alternatives across diverse industries. Among numerous MCDA/MCDM methods developed to solve real-world decision problems, the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) continues to work satisfactorily across different application areas. In this paper, we conduct a state-of-the-art literature survey to taxonomize the research on TOPSIS applications and methodologies. The classification scheme for this review contains 266 scholarly papers from 103 journals since the year 2000, separated into nine application areas: (1) Supply Chain Management and Logistics, (2) Design, Engineering and Manufacturing Systems, (3) Business and Marketing Management, (4) Health, Safety and Environment Management, (5) Human Resources Management, (6) Energy Management, (7) Chemical Engineering, (8) Water Resources Management and (9) Other topics. Scholarly papers in the TOPSIS discipline are further interpreted based on (1) publication year, (2) publication journal, (3) authors' nationality and (4) other methods combined or compared with TOPSIS. We end our review paper with recommendations for future research in TOPSIS decision-making that is both forward-looking and practically oriented. This paper provides useful insights into the TOPSIS method and suggests a framework for future attempts in this area for academic researchers and practitioners.

Review: A state-of the-art survey of TOPSIS applications

The validity of the cubic law for laminar flow of fluids through open fractures consisting of parallel planar plates has been established by others over a wide range of conditions with apertures ranging down to a minimum of 0.2 µm. The law may be given in simplified form by Q/Δh = C(2b)3, where Q is the flow rate, Δh is the difference in hydraulic head, C is a constant that depends on the flow geometry and fluid properties, and 2b is the fracture aperture. The validity of this law for flow in a closed fracture where the surfaces are in contact and the aperture is being decreased under stress has been investigated at room temperature by using homogeneous samples of granite, basalt, and marble. Tension fractures were artificially induced, and the laboratory setup used radial as well as straight flow geometries. Apertures ranged from 250 down to 4µm, which was the minimum size that could be attained under a normal stress of 20 MPa. The cubic law was found to be valid whether the fracture surfaces were held open or were being closed under stress, and the results are not dependent on rock type. Permeability was uniquely defined by fracture aperture and was independent of the stress history used in these investigations. The effects of deviations from the ideal parallel plate concept only cause an apparent reduction in flow and may be incorporated into the cubic law by replacing C by C/ƒ. The factor ƒ varied from 1.04 to 1.65 in these investigations. The model of a fracture that is being closed under normal stress is visualized as being controlled by the strength of the asperities that are in contact. These contact areas are able to withstand significant stresses while maintaining space for fluids to continue to flow as the fracture aperture decreases. The controlling factor is the magnitude of the aperture, and since flow depends on (2b)3, a slight change in aperture evidently can easily dominate any other change in the geometry of the flow field. Thus one does not see any noticeable shift in the correlations of our experimental results in passing from a condition where the fracture surfaces were held open to one where the surfaces were being closed under stress.

/pdf/validity-of-cubic-law-for-fluid-flow-in-a-deformable-rock-2ynq4id3hq.pdf

VALIDITY OF CUBIC LAW FOR FLUID FLOW IN A DEFORMABLE ROCK FRACTURE - eScholarship

Time is divided by geologists according to marked shifts in Earth's state. Recent global environmental changes suggest that Earth may have entered a new human-dominated geological epoch, the Anthropocene. Here we review the historical genesis of the idea and assess anthropogenic signatures in the geological record against the formal requirements for the recognition of a new epoch. The evidence suggests that of the various proposed dates two do appear to conform to the criteria to mark the beginning of the Anthropocene: 1610 and 1964. The formal establishment of an Anthropocene Epoch would mark a fundamental change in the relationship between humans and the Earth system.

Defining the Anthropocene

Elastic properties of rocks play a major and crucial role for the design of any engineering structure. Determination of elastic properties in laboratory is tedious, laborious, very time consuming, as well as expertise is required, whereas determination of uniaxial compressive strength (UCS) and tensile strength in laboratory is simple, easy, and less expertise is required. Here, an attempt has been made to predict the elastic properties (Poisson’s ratio and Young’s modulus) of the schistose rocks from unconfined strength (UCS and tensile strength) using artificial neural network (ANN). A three-layer feed-forward back propagation neural network with 2-5-2 architecture was trained up to 855 epochs to predict the elastic properties of rock mass. The network was trained and tested by 120 data sets, and validation of the network was done by 20 new randomly selected data sets of UCS and tensile strength. The samples were collected from the schistose rocks of Nathpa-Jhakri hydropower project site, SJVNL, Himachal Pradesh, India. To check the validity and suitability of the artificial neural network technique, multivariate regression analysis (MVRA) is also performed, and comparison has been made. It was found that ANN gives closer values of predicted Poisson’s ratio and Young’s modulus as compared to MVRA. The coefficient of determination for Poisson’s ratio was 0.9809 and 0.843 by ANN and MVRA, respectively, whereas 0.9922 and 0.9362 for Young’s modulus by ANN and MVRA, respectively. The mean absolute percentage error (MAPE) for Young’s modulus is 11.13 and 28.21 by ANN and MVRA, respectively; whereas MAPE for Poisson’s ratio is 3.64 and 9.23 by ANN and MVRA, respectively.

Predicting elastic properties of schistose rocks from unconfined strength using intelligent approach

Slope failure is a recurrent phenomenon in hilly regions. It is hazardous because of the accompanying rapid mass movement of soil and rock mass. To alleviate the damage caused by landslide, slope-stability analyses and stabilization techniques require in-depth understanding and appraisal of the process that govern the failure behaviour of slopes. Once the instability behaviour is understood, remedial measures such as retaining walls, rock bolts, anchoring, etc., can be recommended to stabilize the slope.  This article deals with a comparative study used for the analysis of the stability of slopes of Amiyan area, near Kathgodam, Nainital, Uttarakhand assuming that the rock mass follow the Mohr–Coulomb failure criterion under static and dynamic loading conditions. The area constantly experiences local as well as regional slides along the river bank. A field study was carried out in the landslide area to collect the representative samples to determine the various physio-mechanical properties of rock as well ...

https://www.tandfonline.com/doi/pdf/10.1080/19475705.2010.521354

Static and dynamic analysis of a landslide

High performance perovskite solar cell via multi-cycle low temperature processing of lead acetate precursor solutions

This paper reports stability analysis of active and recurrent Amiyan landslide at Kathgodam in Uttarakhand State, India. The height of the affected slope is approximately 501 m, having two terraces with varying slope inclinations. Lower bench, above the basement, always fails and leads failure paths for others. The problem of slide is further adverse due to fluctuation in water level of Gaula river, which is passing along the slope masses. These rocks mainly belong to Siwalik system suffered by many structural disturbances. The stability assessment of the area is very critical to avoid and manage further damage to surrounding agricultural land as well as population along the river. The slopes' failures increase the siltation, reduce carrying capacity of the river with time and further increase the water level on the bank of the slope. The slope was simulated using two modelling methods, namely limit equilibrium method and finite element method. Results indicate that the stress is mostly confined in the te...

Probabilistic analysis of slope in Amiyan landslide area, Uttarakhand

A 12.24 km long tunnel between Maroshi and Ruparel College is being excavated by tunnel boring machine (TBM) to improve the water supply system of Greater Mumbai, India. In this paper, attempt has been made to establish the relationship between various litho-units of Deccan traps, stability of tunnel and TBM performances during the construction of 5.83 km long tunnel between Maroshi and Vakola. The Maroshi–Vakola tunnel passes under the Mumbai Airport and crosses both runways with an overburden cover of around 70 m. The tunneling work was carried out without disturbance to the ground. The rock types encountered during excavation are fine compacted basalt, porphyritic basalt, amygdaloidal basalt, pyroclastic rocks with layers of red boles and intertrappean beds consisting of various types of shales. Relations between rock mass properties, physico-mechanical properties, TBM specifications and the corresponding TBM performance were established. A number of support systems installed in the tunnel during excavation were also discussed. The aim of this paper is to establish, with appropriate accuracy, the nature of subsurface rock mass condition and to study how it will react to or behave during underground excavation by TBM. The experiences gained from this project will increase the ability to cope with unexpected ground conditions during tunneling using TBM.

https://cyberleninka.org/article/n/258735.pdf

Trilok Singh

Papers

Predicting elastic properties of schistose rocks from unconfined strength using intelligent approach

Static and dynamic analysis of a landslide

High performance perovskite solar cell via multi-cycle low temperature processing of lead acetate precursor solutions

Probabilistic analysis of slope in Amiyan landslide area, Uttarakhand

Performance characteristics of tunnel boring machine in basalt and pyroclastic rocks of Deccan traps - A case study