Planar perovskite solar cells (PSCs) made entirely via solution processing at low temperatures (<150°C) offer promise for simple manufacturing, compatibility with flexible substrates, and perovskite-based tandem devices. However, these PSCs require an electron-selective layer that performs well with similar processing. We report a contact-passivation strategy using chlorine-capped TiO2 colloidal nanocrystal film that mitigates interfacial recombination and improves interface binding in low-temperature planar solar cells. We fabricated solar cells with certified efficiencies of 20.1 and 19.5% for active areas of 0.049 and 1.1 square centimeters, respectively, achieved via low-temperature solution processing. Solar cells with efficiency greater than 20% retained 90% (97% after dark recovery) of their initial performance after 500 hours of continuous room-temperature operation at their maximum power point under 1-sun illumination (where 1 sun is defined as the standard illumination at AM1.5, or 1 kilowatt/square meter).

https://science.sciencemag.org/content/sci/early/2017/02/01/science.aai9081.full.pdf

Efficient and stable solution-processed planar perovskite solar cells via contact passivation.

The photovoltaics of organic–inorganic lead halide perovskite materials have shown rapid improvements in solar cell performance, surpassing the top efficiency of semiconductor compounds such as CdTe and CIGS (copper indium gallium selenide) used in solar cells in just about a decade. Perovskite preparation via simple and inexpensive solution processes demonstrates the immense potential of this thin-film solar cell technology to become a low-cost alternative to the presently commercially available photovoltaic technologies. Significant developments in almost all aspects of perovskite solar cells and discoveries of some fascinating properties of such hybrid perovskites have been made recently. This Review describes the fundamentals, recent research progress, present status, and our views on future prospects of perovskite-based photovoltaics, with discussions focused on strategies to improve both intrinsic and extrinsic (environmental) stabilities of high-efficiency devices. Strategies and challenges regardi...

Halide Perovskite Photovoltaics: Background, Status, and Future Prospects

Multi-Criteria Decision Aid (MCDA) or Multi-Criteria Decision Making (MCDM) methods have received much attention from researchers and practitioners in evaluating, assessing and ranking alternatives across diverse industries. Among numerous MCDA/MCDM methods developed to solve real-world decision problems, the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) continues to work satisfactorily across different application areas. In this paper, we conduct a state-of-the-art literature survey to taxonomize the research on TOPSIS applications and methodologies. The classification scheme for this review contains 266 scholarly papers from 103 journals since the year 2000, separated into nine application areas: (1) Supply Chain Management and Logistics, (2) Design, Engineering and Manufacturing Systems, (3) Business and Marketing Management, (4) Health, Safety and Environment Management, (5) Human Resources Management, (6) Energy Management, (7) Chemical Engineering, (8) Water Resources Management and (9) Other topics. Scholarly papers in the TOPSIS discipline are further interpreted based on (1) publication year, (2) publication journal, (3) authors' nationality and (4) other methods combined or compared with TOPSIS. We end our review paper with recommendations for future research in TOPSIS decision-making that is both forward-looking and practically oriented. This paper provides useful insights into the TOPSIS method and suggests a framework for future attempts in this area for academic researchers and practitioners.

Review: A state-of the-art survey of TOPSIS applications

The validity of the cubic law for laminar flow of fluids through open fractures consisting of parallel planar plates has been established by others over a wide range of conditions with apertures ranging down to a minimum of 0.2 µm. The law may be given in simplified form by Q/Δh = C(2b)3, where Q is the flow rate, Δh is the difference in hydraulic head, C is a constant that depends on the flow geometry and fluid properties, and 2b is the fracture aperture. The validity of this law for flow in a closed fracture where the surfaces are in contact and the aperture is being decreased under stress has been investigated at room temperature by using homogeneous samples of granite, basalt, and marble. Tension fractures were artificially induced, and the laboratory setup used radial as well as straight flow geometries. Apertures ranged from 250 down to 4µm, which was the minimum size that could be attained under a normal stress of 20 MPa. The cubic law was found to be valid whether the fracture surfaces were held open or were being closed under stress, and the results are not dependent on rock type. Permeability was uniquely defined by fracture aperture and was independent of the stress history used in these investigations. The effects of deviations from the ideal parallel plate concept only cause an apparent reduction in flow and may be incorporated into the cubic law by replacing C by C/ƒ. The factor ƒ varied from 1.04 to 1.65 in these investigations. The model of a fracture that is being closed under normal stress is visualized as being controlled by the strength of the asperities that are in contact. These contact areas are able to withstand significant stresses while maintaining space for fluids to continue to flow as the fracture aperture decreases. The controlling factor is the magnitude of the aperture, and since flow depends on (2b)3, a slight change in aperture evidently can easily dominate any other change in the geometry of the flow field. Thus one does not see any noticeable shift in the correlations of our experimental results in passing from a condition where the fracture surfaces were held open to one where the surfaces were being closed under stress.

/pdf/validity-of-cubic-law-for-fluid-flow-in-a-deformable-rock-2ynq4id3hq.pdf

VALIDITY OF CUBIC LAW FOR FLUID FLOW IN A DEFORMABLE ROCK FRACTURE - eScholarship

Time is divided by geologists according to marked shifts in Earth's state. Recent global environmental changes suggest that Earth may have entered a new human-dominated geological epoch, the Anthropocene. Here we review the historical genesis of the idea and assess anthropogenic signatures in the geological record against the formal requirements for the recognition of a new epoch. The evidence suggests that of the various proposed dates two do appear to conform to the criteria to mark the beginning of the Anthropocene: 1610 and 1964. The formal establishment of an Anthropocene Epoch would mark a fundamental change in the relationship between humans and the Earth system.

Defining the Anthropocene

The spacing–burden (S/B) ratio plays significant role on rock fragmentation and proper utilization of explosive energy to minimize the undesirable damage. Low S/B ratio generates fine fragments due to pressure rings coalescence of two blast holes, whereas boulder generations were observed above optimum S/B ratio. Both conditions are not acceptable because of wastage of explosive energy. Therefore, to resolve this issue, a numerical model study was conducted to optimize the S/B ratio and to envisage its effect on rock fragmentation based on utilization of explosive energy. Finite element simulation tool was used to see the extent of two blast hole influence area variation with varying S/B ratio. The better results were obtained at S/B ratio of 1:2 with optimum utilization of peak explosive energy. The performance was observed based on peak kinetic energy, peak pressure, radial and hoop stresses on centre of the two blast holes, where pressure rings coalescence.

Numerical assessment of spacing–burden ratio to effective utilization of explosive energy

The knowledge of fluid flow through rock fractures is directly related to hydrocarbon migration, waste disposal, and carbon dioxide sequestration. The hydraulic nature and response of the fractures are directly controlled by the roughness of the fracture surfaces. However, this parameter is hard to understand because it can behave differently under different ambient conditions. The prevalent controlling parameters are the fracture inflow pressure, aperture of the fracture, and shearing displacement during flow. To understand the influence of these parameters, a systematic study was carried out numerically on different fracture geometries. In this paper, two-dimensional fractures with different surface roughness were simulated in a finite-element modeling (FEM) program, and the fluid-flow parameters were evaluated. The Navier–Stokes (NS) equation was used to model the fluid flow through the roughness profiles generated using Barton’s joint roughness coefficient. By simulating the laminar fluid flow...

Fluid Flow through Rough Rock Fractures: Parametric Study

Effective Explosive Energy Utilization for Engineering Blasting – Initial Results Of An Inventive Stemming Plug, SPARSH

The paper presents experimental observations of the anisotropic effect of dry and saturated lineated schistose rock on deformational behaviour and fracture patterns under indirect tensile loading conditions. Dry mylonitic quartz–mica schist (M-QMS) shows strength minima in between lineation orientation of 20°–30° with loading direction, whereas dry crenulated quartz–mica schist (C-QMS) shows strength minima in between 45° and 60°. Water saturation significantly reduces the failure strength and shifts the strength minima towards a higher angle. In addition, the water saturation effect induces plasticity along the lineation direction. P-wave velocity is found to be maximum along lineation direction, which continuously decreases to a minimum value across the lineation. Three types of fracture patterns, namely layer activation, central and non-central, are observed for both the rock types. For both the rock types, tensional fractures occur when the lineation is inclined at 0° and 90° to the loading direction, whereas shear and mixed-mode fractures occur at all other orientations. Fracture through the layer activation is prominent in saturated specimens compared to the dry specimens for β angle range of 15°–60° and 15°–45° in the case of M-QMS and C-QMS, respectively.

The Effect of Lineation on Anisotropy in Dry and Saturated Himalayan Schistose Rock Under Brazilian Test Conditions

Artificial neural networks (ANNs) are rapidly gaining popularity in the area of oil exploration. This article discusses the importance of ANNs to petroleum engineers and geoscientists and its advantages over other conventional methods of computing. ANNs can assist geoscientists in solving some fundamental problems such as formation, permeability prediction, and well data interpretation from geophysical well log responses with a greater degree of confidence comparable to actual well test interpretation. The main goal of the present article is to use the artificial neural network from a petroleum geoscientist's point of view and encourage geoscientists and researchers to consider it as a valuable alternative tool in the petroleum industry. A three-layer feed-forward back-propagation network has been used to predict neutron log (NPHI) and density log (RHOB) values using gamma ray (CGR), resistivity log (IDPH), and sonic log (DTCO) input parameters. The results are also compared by analysis performed...

Trilok Singh

Papers

Numerical assessment of spacing–burden ratio to effective utilization of explosive energy

Fluid Flow through Rough Rock Fractures: Parametric Study

Effective Explosive Energy Utilization for Engineering Blasting – Initial Results Of An Inventive Stemming Plug, SPARSH

The Effect of Lineation on Anisotropy in Dry and Saturated Himalayan Schistose Rock Under Brazilian Test Conditions

Artificial Neural Networks as a Valuable Tool for Well Log Interpretation