T
Tsutomu Morikawa
Researcher at University of Tokyo
Publications - 51
Citations - 649
Tsutomu Morikawa is an academic researcher from University of Tokyo. The author has contributed to research in topics: Radical cyclization & Ring (chemistry). The author has an hindex of 15, co-authored 51 publications receiving 633 citations.
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Synthesis of 2,2-difluoroesters by iododifluoroacetate-copper with organic halides
Takeo Taguchi,Osamu Kitagawa,Tsutomu Morikawa,Tohru Nishiwaki,Hideya Uehara,Hatsumi Endo,Yoshiro Kobayashi +6 more
TL;DR: In this article, the formation of CC bond through reactions of iododifluoroacetate-copper with various organic halides in aprotic solvent proceeds effectively to give 2,2-difluoroesters in good yield.
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Synthesis of optically active cis- and trans-1,2-disubstituted cyclopropane derivatives by the Simmons-Smith reaction of allyl alcohol derivatives derived from (R)-2,3-O-isopropylideneglyceraldehyde
TL;DR: The Simmons-Smith reactions of Z- and E-allyl alcohol derivatives derived from (R)-2,3-O-isopropylideneglyceraldehyde (6) were used for the synthesis of optically active cis- and trans-1,2-disubstituted cyclopropane derivatives.
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Studies on Organic Fluorine Compounds. XXXI. Oxidative Coupling of Ketone Enolates and Trimethylsilyl Enol Ethers by Means of Cu(OTf)2
TL;DR: In this paper, the oxidative coupling of ketone enolates and trimethylsilyl enol ethers by means of cupric trifluoromethanesulfonate [Cu(OTf)2] is described in detail.
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Simmons-Smith Reactions of Fluoroallyl Alcohol Derivatives
TL;DR: In this paper, a cyclopropanation of the fluoroallyl alcohol derivative obtained from (R)-2, 3-O-isopropylidene glyceraldehyde was successfully carried out.
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Radical cyclization to fluorinated double bonds: 5-Exo ring closure of bromoacetals derived from fluoroallyl alcohols
TL;DR: Cyclisations radicalaires des butyl alkyl-1' fluoro-2' alcene-2yl]- et [butyl alkyl- 1' difluoro-3',3' allyl] acetal du bromoacetaldehyde et du broma-3 [fluoro- 2' methyl- 1" phenyl-4' butene- 2" yloxy]-2 perhydro pyranne: obtention de butoxy-2 per-hydro furannes fluores (et per hydro f