Vadim G. Kessler

TL;DR: The octanuclear complex of bismuth ethoxide ethanol solvate, [Bi(OEt)3]8·(7+x)EtOH (1) has been isolated on crystallization from the ethanol solution of the products from the BiCl3 metathesis with NaOEt as mentioned in this paper.

TL;DR: In this article, a review of synthetic approaches to modern rhenium-based catalysts is presented, where the authors consider the creation of an active center as a process of obtaining a nanoparticle or a molecule, immobilized within a matrix of the substrate, and trace structure-property relationships for these catalysts in relation to such processes as alkylation and isomerization, olefin metathesis, selective oxidation of olefins, methanol to formaldehyde conversion, etc.

TL;DR: In this article, the authors describe the principles of the Single Source Precursor approach to inorganic materials and introduce the Geometrical Molecular Structure Design Concept (MSDC) based on the choice of a proper molecular structure type for the desired precursor and completing it with ligands providing both the necessary number of donor atoms and the sterical protection of the chosen core.

TL;DR: It is shown that wet impregnation of ZrO2 nanoparticles with 10% and 20% Eu oxide followed by thermal anneal in air above 500 °C produces full stabilization of the tetragonal phase of ZRO2 without evidencing any phase separation.

TL;DR: The most important role of oxo-alkoxides in the processes of formation of oxides has been demonstrated using as an example preparation of BaTiO3 from alkoxides.