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Vincent Robert

Researcher at University of Strasbourg

Publications -  63
Citations -  1099

Vincent Robert is an academic researcher from University of Strasbourg. The author has contributed to research in topics: Electron transfer & Molecular orbital. The author has an hindex of 20, co-authored 63 publications receiving 961 citations. Previous affiliations of Vincent Robert include École normale supérieure de Lyon.

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Helical Chirality Induces a Substrate-Selectivity Switch in Carbohydrates Recognitions.

TL;DR: A new chiral hemicryptophane cage combining an electron-rich cyclotriveratrylene (CTV) unit and polar amine functions has been synthesized and displays both remarkable enantioselectivities in the recognition of carbohydrates and good binding constants.
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Hemicryptophane-assisted electron transfer: a structural and electronic study

TL;DR: Three copper(II)@hemicryptophane complexes with various cavity sizes and shapes were synthesized and characterized by near-IR/vis and EPR spectroscopies, consistent with the presence of a trigonal-bipyramidal geometry of the N(4)Cu·H(2)O core, in accord with the energy-minimized structures obtained from DFT calculations.
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A 1D coordination polymer built on asymmetric μ1,1,3-azide bridge: from unusual topology to magnetic properties and Cu(II)/Cu(I) redox reversibility

TL;DR: An azide-bridged Cu(II) one dimensional polymer was synthesized in a one pot reaction in the presence of ammonia as discussed by the authors, and the refined crystal structure evidenced the unusual asymmetric μ 1, 1, 3 coordination mode of the azide ion leading to a {Cu(μ1,1,3-N3)(μ1-N 3)(NH3)0.8(H2O)1.2}n chain.
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Hemicryptophane host as efficient primary alkylammonium ion receptor

TL;DR: Hemicryptophane 3 was found to be an efficient and selective primary alkylammonium receptor and efficient complexation of dopamine emphasizes the use of this host for neurotransmitter complexation.
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Synthesis of the First Water-Soluble Hemicryptophane Host: Selective Recognition of Choline in Aqueous Medium

TL;DR: The first water-soluble hemicryptophane cage compound, 4, was synthesized in seven steps from commercially available products, and its complexation properties were studied.