The low-salinity effect (LSE) in carbonate rock has been less explored in comparison to sandstone rock. Laboratory experiments have shown that brine composition and (somewhat reduced) salinity can have a positive impact on oil recovery in carbonates. However, the mechanism leading to improved oil recovery in carbonate rock is not well understood. Several studies showed that a positive low-salinity flooding (LSF) effect might be associated with dissolution of rock; however, because of equilibration, dissolution may not contribute at reservoir scale, which would make LSF for carbonate rock less attractive for field applications. This raises now the question whether calcite dissolution is the primary mechanism of the LSF effect. In this paper, we aim to first demonstrate the positive response of carbonate rock to low salinity and then to gain insight into the underlying mechanism(s) specific to carbonate rock. We followed a similar methodology as in sandstone rock [Mahani, H.; Berg, S.; Ilic, D.; Bartels, W....

Insights into the Mechanism of Wettability Alteration by Low-Salinity Flooding (LSF) in Carbonates

Review of the litterature available outside the petroleum industry concerning wettability. This litterature discusses surface forces and their effects on wettability, including van der Waal and electrostatic forces. Hydrogen bonding and ion/water interactions, are also discussed. Advancing and receding contact angles for oil/water/mineral systems in terms of these surface forces are described.

Wettability : fundamentals and surface forces

Significance The simultaneous flow of multiple fluid phases through a porous solid occurs in many natural and industrial processes—for example, rainwater infiltrates into soil by displacing air, and carbon dioxide is stored in deep saline aquifers by displacing brine. It has been known for decades that wetting—the affinity of the solid to one of the fluids—can have a strong impact on the flow, but the microscale physics and macroscopic consequences remain poorly understood. Here, we study this in detail by systematically varying the wetting properties of a microfluidic porous medium. Our high-resolution images reveal the fundamental control of wetting on multiphase flow, elucidate the inherently 3D pore-scale mechanisms, and help explain the striking macroscopic displacement patterns that emerge. Multiphase flow in porous media is important in many natural and industrial processes, including geologic CO2 sequestration, enhanced oil recovery, and water infiltration into soil. Although it is well known that the wetting properties of porous media can vary drastically depending on the type of media and pore fluids, the effect of wettability on multiphase flow continues to challenge our microscopic and macroscopic descriptions. Here, we study the impact of wettability on viscously unfavorable fluid–fluid displacement in disordered media by means of high-resolution imaging in microfluidic flow cells patterned with vertical posts. By systematically varying the wettability of the flow cell over a wide range of contact angles, we find that increasing the substrate’s affinity to the invading fluid results in more efficient displacement of the defending fluid up to a critical wetting transition, beyond which the trend is reversed. We identify the pore-scale mechanisms—cooperative pore filling (increasing displacement efficiency) and corner flow (decreasing displacement efficiency)—responsible for this macroscale behavior, and show that they rely on the inherent 3D nature of interfacial flows, even in quasi-2D media. Our results demonstrate the powerful control of wettability on multiphase flow in porous media, and show that the markedly different invasion protocols that emerge—from pore filling to postbridging—are determined by physical mechanisms that are missing from current pore-scale and continuum-scale descriptions.

Wettability control on multiphase flow in patterned microfluidics

Electrokinetics of Carbonate/Brine Interface in Low-Salinity Waterflooding: Effect of Brine Salinity, Composition, Rock Type, and pH on ζ-Potential and a Surface-Complexation Model

A comprehensive review of low salinity/engineered water injections and their applications in sandstone and carbonate rocks

Literature review of low salinity waterflooding from a length and time scale perspective

Low-salinity waterflooding (LSF) is one of the least-understood enhanced-oil-recovery (EOR)/improved-oil-recovery (IOR) methods, and proper understanding of the mechanism(s) leading to oil recovery in this process is needed. However, the intrinsic complexity of the process makes fundamental understanding of the underlying mechanism(s) and the interpretation of laboratory experiments difficult. Therefore, we use a model system for sandstone rock of reduced complexity that consists of clay minerals (Na-montmorillonite) deposited on a glass substrate and covered with crude-oil droplets and in which different effects can be separated to increase our fundamental understanding. We focus particularly on the kinetics of oil detachment when exposed to lowsalinity (LS) brine. The system is equilibrated first under high-salinity (HS) brine and then exposed to brines of varying (lower) salinity while the shape of the oil droplets is continuously monitored at high resolution, allowing for a detailed analysis of the contact angle and the contact area as a function of time. It is observed that the contact angle and contact area of oil with the substrate reach a stable equilibrium at HS brine and show a clear response to the LS brine toward less-oil-wetting conditions and ultimately detachment from the clay substrate. This behavior is characterized by the motion of the three-phase (oil/water/solid) contact line that is initially pinned by clay particles at HS conditions, and pinning decreases upon exposure to LS brine. This leads to a decrease in contact area and contact angle that indicates wettability alteration toward a more-waterwet state. When the contact angle reaches a critical value at approximately 40 to 50 , oil starts to detach from the clay. During detachment, most of the oil is released, but in some cases a small amount of oil residue is left behind on the clay substrate. Our results for different salinity levels indicate that the kinetics of this wettability change correlates with a simple buoyancyover adhesion-force balance and has a time constant of hours to days (i.e., it takes longer than commonly assumed). The unexpectedly long time constant, longer than expected by diffusion alone, is compatible with an electrokinetic ion-transport model (Nernst-Planck equation) in the thin water film between oil and clay. Alternatively, one could explain the observations only by more-specific [nonDerjaguin–Landau–Verwey–Overbeek (DLVO) type] interactions between oil and clay such as cation-bridging, direct chemical bonds, or acid/base effects that tend to pin the contact line. The findings provide new insights into the (sub) pore-scale mechanism of LSF, and one can use them as the basis for upscaling to, for example, pore-network scale and higher scales (e.g., core scale) to assess the impact of the slow kinetics on the time scale of an LSF response on macroscopic scales.

Kinetics of Low-Salinity-Flooding Effect

Oil Configuration Under High-Salinity and Low-Salinity Conditions at Pore Scale: A Parametric Investigation by Use of a Single-Channel Micromodel

Darcy-scale multiphase flow in geological formations is significantly influenced by the wettability of the fluid-solid system. So far it has not been understood how wettability impacts the pore-scale flow regimes within rocks, which were in most cases regarded as an alteration from the base case of strongly water-wet conditions by adjustment of contact angles. In this study, we directly image the pore-scale flow regime in a carbonate altered to a mixed-wet condition by aging with crude oil to represent the natural configuration in an oil reservoir with fast synchrotron-based X-ray computed tomography. We find that the pore-scale flow regime is dominated by ganglion dynamics in which the pore space is intermittently filled with oil and brine. The frequency and size of these fluctuations are greater than in water-wet rock such that their impact on the overall flow and relative permeability cannot be neglected in modeling approaches.

W. B. Bartels

Papers

Insights into the Mechanism of Wettability Alteration by Low-Salinity Flooding (LSF) in Carbonates

Literature review of low salinity waterflooding from a length and time scale perspective

Kinetics of Low-Salinity-Flooding Effect

Oil Configuration Under High-Salinity and Low-Salinity Conditions at Pore Scale: A Parametric Investigation by Use of a Single-Channel Micromodel

The Effect of Mixed Wettability on Pore-Scale Flow Regimes Based on a Flooding Experiment in Ketton Limestone