Metamaterials, artificial electromagnetic media that are structured on the subwavelength scale, were initially suggested for the negative-index 'superlens'. Later metamaterials became a paradigm for engineering electromagnetic space and controlling propagation of waves: the field of transformation optics was born. The research agenda is now shifting towards achieving tunable, switchable, nonlinear and sensing functionalities. It is therefore timely to discuss the emerging field of metadevices where we define the devices as having unique and useful functionalities that are realized by structuring of functional matter on the subwavelength scale. In this Review we summarize research on photonic, terahertz and microwave electromagnetic metamaterials and metadevices with functionalities attained through the exploitation of phase-change media, semiconductors, graphene, carbon nanotubes and liquid crystals. The Review also encompasses microelectromechanical metadevices, metadevices engaging the nonlinear and quantum response of superconductors, electrostatic and optomechanical forces and nonlinear metadevices incorporating lumped nonlinear components.

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From metamaterials to metadevices.

Metamaterials, artificial composite structures with exotic material properties, have emerged as a new frontier of science involving physics, material science, engineering and chemistry. This critical review focuses on the fundamentals, recent progresses and future directions in the research of electromagnetic metamaterials. An introduction to metamaterials followed by a detailed elaboration on how to design unprecedented electromagnetic properties of metamaterials is presented. A number of intriguing phenomena and applications associated with metamaterials are discussed, including negative refraction, sub-diffraction-limited imaging, strong optical activities in chiral metamaterials, interaction of meta-atoms and transformation optics. Finally, we offer an outlook on future directions of metamaterials research including but not limited to three-dimensional optical metamaterials, nonlinear metamaterials and “quantum” perspectives of metamaterials (142 references).

Metamaterials: a new frontier of science and technology

We analyze the design of ultrathin quarter-wave plates based on plasmonic metasurfaces. After exploring the general theoretical possibilities offered by thin surfaces to manipulate the impinging polarization, we propose optimal designs to realize quarter-wave metasurface plates, analyzing their frequency and angular response. Our designs may provide a large degree of linear polarization output for circularly polarized input over a broad bandwidth in the optical regime. The geometry may be implemented within currently available lithographic techniques and easily integrated with other optical devices for polarization manipulation, detection, and sensing at the nanoscale.

Manipulating light polarization with ultrathin plasmonic metasurfaces

Metasurfaces are a topic of significant research and are used in various applications due to their unique ability to manipulate electromagnetic waves in microwave and optical frequencies. These artificial sheet materials, which are usually composed of metallic patches or dielectric etchings in planar or multi-layer configurations with subwavelength thickness, have the advantages of light weight, ease of fabrication, and ability to control wave propagation both on the surface and in the surrounding free space. Recent progress in the field has been classified by application and reviewed in this article. Starting with the development of frequency-selective surfaces and metamaterials, the unique capabilities of different kinds of metasurfaces have been highlighted. Surface impedance can be varied and manipulated by patterning the metasurface unit cells, which has broad applications in surface wave absorbers and surface waveguides. They also enable beam shaping in both transmission and reflection. Another important application is to radiate in a leaky wave mode as an antenna. Other applications of metasurfaces include cloaking, polarizers, and modulators. The controllable surface refractive index provided by metasurfaces can also be applied to lenses. When active and non-linear components are added to traditional metasurfaces, exceptional tunability and switching ability are enabled. Finally, metasurfaces allow applications in new forms of imaging.

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Metasurfaces and their applications

We experimentally demonstrate an on-chip nanoscale silicon surface-plasmon Schottky photodetector based on internal photoemission process and operating at telecom wavelengths. The device is fabricated using a self-aligned approach of local-oxidation of silicon (LOCOS) on silicon on insulator substrate, which provides compatibility with standard complementary metal-oxide semiconductor technology and enables the realization of the photodetector and low-loss bus photonic waveguide at the same fabrication step. Additionally, LOCOS technique allows avoiding lateral misalignment between the silicon surface and the metal layer to form a nanoscale Schottky contact. The fabricated devices showed enhanced detection capability for shorter wavelengths that is attributed to increased probability of the internal photoemission process. We found the responsivity of the nanodetector to be 0.25 and 13.3 mA/W for incident optical wavelengths of 1.55 and 1.31 μm, respectively. The presented device can be integrated with other nanophotonic and nanoplasmonic structures for the realization of monolithic opto-electronic circuitry on-chip.

Locally Oxidized Silicon Surface-Plasmon Schottky Detector for Telecom Regime

We have fabricated a metamaterial of metal/semiconductor/metal sandwich nanostrips structure comprising a pair of gold strips and a vanadium dioxide (VO2) strip. The optical response of the metamaterial has been studied. The results indicate the nanostructure with VO2 strips can be used as a temperature-controlling optical switch and the mechanism of this switch can be explained by the magnetic resonance.

Optical switching of a metamaterial by temperature controlling

The optical properties of a planar metamaterial with gammadion-shaped chiral symmetry breaking holes array have been investigated both theoretically and experimentally. The results indicate that the introduction of the chiral symmetry breaking causes the split of the transmission peak and exerts large influence on the optical rotation and circular dichroism. Our metamaterials might have potential applications in future design of plasmonic devices.

Optical properties of a planar metamaterial with chiral symmetry breaking

The enhanced optical transmission (EOT) and the enhanced fluorescence emission (EFE) of the metallic nanohole arrays have been widely studied. Here, the dielectric thickness detection sensor based ...

Dielectric Thickness Detection Sensor Based on Metallic Nanohole Arrays

We demonstrate that Ag–Si photodiodes allow photocurrents to be modulated by changing periods of nanopatterns on Ag film. The maximum and minimum photocurrents occur in certain periods corresponding to the excitation of surface plasmon polariton and Wood’s anomaly, which can be predicted with the help of related theories. Therefore, it is feasible to design nanopatterns to satisfy special requirements.

Photocurrent in Ag–Si photodiodes modulated by plasmonic nanopatterns

The optical properties of a composite metamaterial, composed of asymmetric split-ring resonators (SRR) inserted into the periodic circular holes, have been investigated both experimentally and theoretically. Transmission peaks and dip associated with the localized plasmon excitations have been found: the peaks originate from the resonances of the smaller or bigger SRR, and the dip stems from the strong coupling between them. To understand the results, a composite LC circuit model has been employed.

Wan-xia Huang

Papers

Optical switching of a metamaterial by temperature controlling

Optical properties of a planar metamaterial with chiral symmetry breaking

Dielectric Thickness Detection Sensor Based on Metallic Nanohole Arrays

Photocurrent in Ag–Si photodiodes modulated by plasmonic nanopatterns

Optical resonances in a composite asymmetric plasmonic nanostructure