Smart window refers to the on-demand window that can dynamically modulate light transmittance. It is recognized as a promising technology to economize building energy A smart window that dynamically modulates light transmittance is crucial for building energy efficiently, and promising for on-demand optical devices. The rapid development of technology brings out different categories that have fundamentally different transmittance modulation mechanisms, including the electro-, thermo-, mechano-, and photochromic smart windows. In this review, recent progress in smart windows of each category is overviewed. The strategies for each smart window are outlined with particular focus on functional materials, device design, and performance enhancement. The advantages and disadvantages of each category are summarized, followed by a discussion of emerging technologies such as dual stimuli triggered smart window and integrated devices toward multifunctionality. These multifunctional devices combine smart window technology with, for example, solar cells, triboelectric nanogenerators, actuators, energy storage devices, and electrothermal devices. Lastly, a perspective is provided on the future development of smart windows. Smart Windows

Smart Windows: Electro-, Thermo-, Mechano-, Photochromics, and Beyond

Soft tubular actuators can be widely found both in nature and in engineering applications. The benefits of tubular actuators include (i) multiple actuation modes such as contraction, bending, and expansion; (ii) facile fabrication from a planar sheet; and (iii) a large interior space for accommodating additional components or for transporting fluids. Most recently developed soft tubular actuators are driven by pneumatics, hydraulics, or tendons. Each of these actuation modes has limitations including complex fabrication, integration, and nonuniform strain. Here, we design and construct soft tubular actuators using an emerging artificial muscle material that can be easily patterned with programmable strain: liquid crystal elastomer. Controlled by an externally applied electrical potential, the tubular actuator can exhibit multidirectional bending as well as large (~40%) homogenous contraction. Using multiple tubular actuators, we build a multifunctional soft gripper and an untethered soft robot.

Electrically controlled liquid crystal elastomer–based soft tubular actuator with multimodal actuation

The authors acknowledge generous support of the King Abdullah University of Science and Technology (KAUST). The authors acknowledge Dr. Joanna M. Nassar, Dr. Galo A. Torres, Dr. Mohamed T. Ghoneim, Andres A. Aguirre-Pablo, Davide Priante, Dr. Jhonathan P. Rojas, Sigurdur T. Thoroddsen, and Prof. Boon S. Ooi who contributed to the “pause-embed-resume” data. The authors thank Kelly Rader for proof reading this manuscript.

https://onlinelibrary.wiley.com/doi/pdf/10.1002/aisy.202000128

Soft Actuators for Soft Robotic Applications: A Review

In this work, we advance printed active composites by combining 3D printing, printed electronics, and liquid crystal elastomers (LCEs) to achieve soft actuators with free-standing two-way shape changing behaviors. Incorporated LCE strips are activated by Joule heating produced by printed conductive wires, while uniaxial deformation of the LCE strip is utilized as a driving force to achieve bending in the printed composite. The bending behavior of laminated hinges is first characterized in order to obtain a precise control of actuation, which is then exploited to actuate four demonstrative designs: a morphing airplane, a miura-ori structure, a cubic box, and a soft crawler. The soft morphing airplane and miura-ori structure are designed and fabricated with multiple laminated hinges to demonstrate the synergistic actions during actuation. The cubic box is constructed to show the capability of sequential folding by implementing multiple groups of conductive wires to achieve accurately addressable heating with temporal control. Finally, the two-way transformation is utilized as a driving force for the locomotion of a soft crawler stimulated by a periodic rectangular wave current. These examples show the great potential of using the hybrid 3D printing and pick-and-place method and using LCEs to achieve controllable shape change structures for a variety of potential practical applications.

3D printed reversible shape changing soft actuators assisted by liquid crystal elastomers

Wearable Sensors-Enabled Human–Machine Interaction Systems: From Design to Application

As a promising actuating material, liquid crystal elastomer (LCE) has been intensively explored in building diverse active structures and devices. Recently, direct ink writing technique has been developed to print LCE structures with various geometries and actuation behaviors. Despite the advancement in printing LCE, it remains challenging to print three-dimensional (3D) LCE structures with graded properties. Here, we report a facile method to tailor both the actuation behavior and mechanical properties of printed LCE filaments by varying printing parameters. On the basis of the comprehensive processing-structure-property relationship, we propose a simple strategy to print functionally graded LCEs, which greatly increases the design space for creating active morphing structures. We further demonstrate mitigation of stress concentration near the interface between an actuatable LCE tube and a rigid glass plate through gradient printing. The strategy developed here will facilitate potential applications of LCEs in different fields.

Three-dimensional printing of functionally graded liquid crystal elastomer.

Fibers capable of generating axial contraction are commonly seen in nature and engineering applications. Despite the broad applications of fiber actuators, it is still very challenging to fabricate fiber actuators with combined large actuation strain, fast response speed, and high power density. Here, we report the fabrication of a liquid crystal elastomer (LCE) microfiber actuators using a facile electrospinning technique. Owing to the extremely small size of the LCE microfibers, they can generate large actuation strain (~60 percent) with a fast response speed (<0.2 second) and a high power density (400 watts per kilogram), resulting from the nematic-isotropic phase transition of liquid crystal mesogens. Moreover, no performance degradation is detected in the LCE microfibers after 106 cycles of loading and unloading with the maximum strain of 20 percent at high temperature (90 degree Celsius). The small diameter of the LCE microfiber also results in a self-oscillatory behavior in a steady temperature field. In addition, with a polydopamine coating layer, the actuation of the electrospun LCE microfiber can be precisely and remotely controlled by a near-infrared laser through photothermal effect. Using the electrospun LCE microfiber actuator, we have successfully constructed a microtweezer, a microrobot, and a light-powered microfluidic pump.

Electrospun liquid crystal elastomer microfiber actuator.

Liquid crystal elastomer (LCE) is a newly emerging soft actuating material that has been extensively explored for building novel soft robots and diverse active devices, thanks to its large actuation stress and strain, high work density, and versatile actuation modes. However, there have also been several widely recognized limitations of LCE-based actuators for practical applications, including slow response and narrow range of operation temperature. Herein, we develop fluid-driven disulfide LCE actuators through facile laminate manufacturing enabled by a dynamic bond exchange reaction. Because of the merits of the active heating/cooling mechanism of the fluidic structure, this newly developed disulfide LCE actuator can generate large cyclic actuation at a frequency around 1 Hz and can operate in a wide range of temperatures. The unique combination of the fluidic structure design and the dynamic covalent bonds in the elastomer has also enabled the full recyclability and self-repairability of the actuator. Using the newly developed actuator as building block, we further constructed soft robotic systems that can realize manipulating and programmable movement. The design principle demonstrated in the current work opens a promising avenue for exploring more novel applications of LCE-based soft actuators.

Recyclable and Self-Repairable Fluid-Driven Liquid Crystal Elastomer Actuator.

Liquid crystal elastomers (LCEs) have recently been intensively explored in various applications as soft actuating materials and opto-mechanical coupling materials. Since the orientation of mesogens in the elastomer largely determines its properties, various methods of programming the alignment of mesogens in LCEs have recently been developed. However, most of the methods either involve complex fabrication processes or have intrinsic limitations in their applicability. In this article, we synthesize a LCE with dynamic disulfide bonds and propose a facile room-temperature mechanical programming method via a "living" exchange reaction without requiring additional stimuli and catalysts. We also, for the first time, reveal the "living" exchange reaction of disulfide bonds at room temperature in a bulk polymer. Such a "living" exchange reaction relies on the significantly prolonged lifetime of free radicals generated during the breakage of disulfide bonds, which is counterintuitive and in contrast to most previous understandings. Thanks to the disulfide bond, the patterned orientation of the mesogens in the LCE is erasable and reprogrammable. In addition, the synthesized LCE also exhibits a shape memory effect, enabling the design of deployable soft actuating devices.

Yang Wang

Papers

Electrically controlled liquid crystal elastomer–based soft tubular actuator with multimodal actuation

Three-dimensional printing of functionally graded liquid crystal elastomer.

Electrospun liquid crystal elastomer microfiber actuator.

Recyclable and Self-Repairable Fluid-Driven Liquid Crystal Elastomer Actuator.

Programmable actuation of liquid crystal elastomers via "living" exchange reaction