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Yasunori Okada
Researcher at Kwansei Gakuin University
Publications - 11
Citations - 194
Yasunori Okada is an academic researcher from Kwansei Gakuin University. The author has contributed to research in topics: Glycosylation & Reagent. The author has an hindex of 5, co-authored 11 publications receiving 175 citations.
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Journal ArticleDOI
Highly beta-selective O-glucosidation due to the restricted twist-boat conformation.
TL;DR: 6-O-pivaloylated substrate provided the best selectivity up to alpha/beta = 3:97 with cyclohexylmethanol, and the substrate was used for glucosidations with secondary and tertiary alcohols in a highly beta-selective manner.
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Completely β-Selective Glycosylation Using 3,6-O-(o-Xylylene)-Bridged Axial-Rich Glucosyl Fluoride
TL;DR: A completely β-selective glycosylation that does not rely on neighboring group participation is described and is attributed to the synergy of the axial-rich conformation and convergent isomerization caused by HB(C(6)F(5))(4) generated in situ.
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Highly beta-selective and direct formation of 2-O-glycosylated glucosides by ring restriction into twist-boat.
TL;DR: Three disaccharide donors, ethyl 2-O-(2,3,4-tris-O-tert-butyldimethylsilyl-beta-D-xylopyranosyl)-3,2,4,6-tr isomeric units, produced a highly beta-selective glycosidation up to alpha/beta = 2/98 using MeOTf as the activator and 2, 6-lutidine as an additive
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Benzyl N-Phenyl-2,2,2-trifluoroacetimidate: A New and Stable Reagent for O-Benzylation
TL;DR: A new O-benzylation reagent, benzyl N-phenyl-2, 2,2,2-trifluoroacetimidate, has been developed that reacts with sterically hindered alcohols and base-sensitive hydroxy esters to afford the corresponding benzyl ethers catalyzed by TMSOTf in 1,4-dioxane.
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Facile and regioselective preparation of partly O-benzylated d-glucopyranose acetates via acid-mediated simultaneous debenzylation–acetolysis
TL;DR: Fully O-benzylated methyl alpha-D-glucopyranoside shows a steady order in stepwise debenzylation when it is treated with sulfuric acid in acetic anhydride.