Y
Yuki Kakeno
Researcher at Kanazawa University
Publications - 3
Citations - 305
Yuki Kakeno is an academic researcher from Kanazawa University. The author has contributed to research in topics: Carbene & Aryl. The author has an hindex of 3, co-authored 3 publications receiving 126 citations.
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Journal ArticleDOI
N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes
TL;DR: It is found that N-heterocyclic carbene catalysis promoted the unprecedented decarboxylative coupling of aryl aldehydes and tertiary or secondary alkyl carboxylic acid-derived redox-active esters to produce ary lkyl ketones.
Journal ArticleDOI
Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis
TL;DR: In this article, a N-heterocyclic carbene (NHC) catalyst with an N-neopentyl group and seven-membered backbone structure was designed using aliphatic aldehydes as acyl donors.
Journal ArticleDOI
Aryl radical-mediated N-heterocyclic carbene catalysis.
Yuki Matsuki,Nagisa Ohnishi,Yuki Kakeno,Shunsuke Takemoto,Takuya Ishii,Kazunori Nagao,Hirohisa Ohmiya,Hirohisa Ohmiya +7 more
TL;DR: In this paper, the enolate form of the Breslow intermediate derived from an aldehyde and thiazolium-type NHC in the presence of a base undergoes single electron transfer to an aryl iodide, providing an annealing radical.