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Yuri Georgievskii
Researcher at Argonne National Laboratory
Publications - 74
Citations - 4512
Yuri Georgievskii is an academic researcher from Argonne National Laboratory. The author has contributed to research in topics: Reaction coordinate & Transition state theory. The author has an hindex of 37, co-authored 70 publications receiving 3787 citations. Previous affiliations of Yuri Georgievskii include Sandia National Laboratories & Weizmann Institute of Science.
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Reformulation and Solution of the Master Equation for Multiple-Well Chemical Reactions
TL;DR: This work considers an alternative formulation of the master equation for complex-forming chemical reactions with multiple wells and bimolecular products and considers the situation where some of the chemical eigenvalues approach the energy relaxation time scale and how to modify the phenomenological rate coefficients.
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Long-range transition state theory.
TL;DR: The implementation of variational transition state theory for long-range asymptotic potential forms is considered, with particular emphasis on the energy and total angular momentum resolved (microJ-VTST) implementation, which is shown to yield capture-rate coefficients that compare favorably with those from trajectory simulations.
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A two transition state model for radical-molecule reactions: a case study of the addition of OH to C2H4.
TL;DR: A two transition state model is applied to the study of the addition of hydroxyl radical to ethylene, which serves as a prototypical example of a radical-molecule reaction with a negative activation energy in the high-pressure limit.
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Predictive theory for the combination kinetics of two alkyl radicals
TL;DR: Comparisons with experiment suggest that the present dynamically corrected VRC-TST approach provides quantitatively accurate predictions for the capture rate, and the present approach should be applicable to a wide array of radical-radical combination reactions.
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Predictive theory for hydrogen atom-hydrocarbon radical association kinetics.
TL;DR: Procedures for accurately predicting the kinetics of hydrogen atom associations with hydrocarbon radicals are described and applied to a series of reactions, and theory and experiment essentially agree to within their error bars.