J. Appl. Cryst.の発刊に際して

4.3. Reaction Mechanism 2373 4.4. Asymmetric Synthesis 2374 4.5. Outlook 2374 5. Alternating Polymerization of Oxiranes and CO2 2374 5.1. Reaction Outlines 2374 5.2. Catalyst 2376 5.3. Asymmetric Polymerization 2377 5.4. Immobilized Catalysts 2377 6. Synthesis of Urea and Urethane Derivatives 2378 7. Synthesis of Carboxylic Acid 2379 8. Synthesis of Esters and Lactones 2380 9. Synthesis of Isocyanates 2382 10. Hydrogenation and Hydroformylation, and Alcohol Homologation 2382

Transformation of carbon dioxide.

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

Catalysis for the valorization of exhaust carbon: from CO2 to chemicals, materials, and fuels. technological use of CO2.

This critical review presents a comprehensive study of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) towards construction and synthesis of metal–organic frameworks (MOFs). We describe the geometries of 131 SBUs, their connectivity and composition. This contribution presents a comprehensive list of the wide variety of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) in the construction and synthesis of metal–organic frameworks. The SBUs discussed here were obtained from a search of molecules and extended structures archived in the Cambridge Structure Database (CSD, version 5.28, January 2007) which included only crystals containing metal carboxylate linkages (241 references).

/pdf/secondary-building-units-nets-and-bonding-in-the-chemistry-o0m4ttzsgz.pdf

Secondary building units, nets and bonding in the chemistry of metal–organic frameworks

Synthesis of (Z)‐1‐Aza‐1,3‐enynes by the Cross‐Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare‐Earth Metal Complexes

Synthesis, Structures, and Reactivity of the First Silylene-Linked Cyclopentadienyl-Phosphido Lanthanide Complexes

http://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00116

Mechanistic Insights into Scandium-Catalyzed Hydroaminoalkylation of Olefins with Amines: Origin of Regioselectivity and Charge-Based Prediction Model

Lanthanides in organic synthesis. Samarium metal promoted selective formation of azoxy compounds

Well-defined molecular polyhydrides composed of two substantially different types of metals — such as rare-earth and d transition metals — are interesting both in terms of structure and potential properties, but have been largely unexplored so far. Now, a series of such hydride clusters are reported and are found to exhibit unprecedented structural features as well as unique hydrogen addition and release properties.

Zhaomin Hou

Papers

Synthesis of (Z)‐1‐Aza‐1,3‐enynes by the Cross‐Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare‐Earth Metal Complexes

Synthesis, Structures, and Reactivity of the First Silylene-Linked Cyclopentadienyl-Phosphido Lanthanide Complexes

Mechanistic Insights into Scandium-Catalyzed Hydroaminoalkylation of Olefins with Amines: Origin of Regioselectivity and Charge-Based Prediction Model

Lanthanides in organic synthesis. Samarium metal promoted selective formation of azoxy compounds

Molecular heterometallic hydride clusters composed of rare-earth and d -transition metals