Z
Zhen-Yao Dai
Researcher at University of Science and Technology of China
Publications - 4
Citations - 156
Zhen-Yao Dai is an academic researcher from University of Science and Technology of China. The author has contributed to research in topics: Allylic rearrangement & Catalysis. The author has an hindex of 3, co-authored 4 publications receiving 76 citations.
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Journal ArticleDOI
Nucleophile-Dependent Z/ E- and Regioselectivity in the Palladium-Catalyzed Asymmetric Allylic C-H Alkylation of 1,4-Dienes.
Hua-Chen Lin,Pei-Pei Xie,Zhen-Yao Dai,Shuo-Qing Zhang,Pu-Sheng Wang,Yu-Gen Chen,Tian-Ci Wang,Xin Hong,Liu-Zhu Gong +8 more
TL;DR: Experimental and computational studies on the reaction mechanism suggest a novel concerted proton and two-electron transfer process for the allylic C-H cleavage and reveal that the Z/ E- and regioselectivities are governed by the geometry and coordination pattern of nucleophiles.
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Asymmetric α-Allylation of Aldehydes with Alkynes by Integrating Chiral Hydridopalladium and Enamine Catalysis
TL;DR: A palladium-catalyzed asymmetric α-allylation of aldehydes with alkynes has been established by integrating the catalysis of enamine and chiral hydridopalladium complex that is reversibly formed from the oxidative addition of Pd(0) to chiral phosphoric acid.
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Asymmetric Photocatalytic C(sp3)–H Bond Addition to α-Substituted Acrylates
TL;DR: In this article, an asymmetric photocatalytic C(sp3)-H bond addition to α-substituted acrylates by using tetrabutylammonium decatungstate (TBADT) as a hydrogen atom transfer (HAT) photocatalyst and chiral phosphoric acid as a chiral proton-transfer shuttle is described.
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Access to chiral γ-butenolides via palladium-catalyzed asymmetric allylic C–H alkylation of 1,4-dienes
TL;DR: Asymmetric allylic C-H alkylation of 1,4-pentadienes with α-angelica lactones has been developed by tri-axial phosphoramidite-palladium catalysis as mentioned in this paper.