Showing papers in "Bulletin of Volcanology in 1990"

Pahoehoe and aa in Hawaii: volumetric flow rate controls the lava structure

Abstract: The historical records of Kilauea and Mauna Loa volcanoes reveal that the rough-surfaced variety of basalt lava called aa forms when lava flows at a high volumetric rate (>5–10 m3/s), and the smooth-surfaced variety called pahoehoe forms at a low volumetric rate (<5–10 m3/s). This relationship is well illustrated by the 1983–1990 and 1969–1974 eruptions of Kilauea and the recent eruptions of Mauna Loa. It is also illustrated by the eruptions that produced the remarkable paired flows of Mauna Loa, in which aa formed during an initial short period of high discharge rate (associated with high fountaining) and was followed by the eruption of pahoehoe over a sustained period at a low discharge rate (with little or no fountaining). The finest examples of paired lava flows are those of 1859 and 1880–1881. We attribute aa formation to rapid and concentrated flow in open channels. There, rapid heat loss causes an increase in viscosity to a threshold value (that varies depending on the actual flow velocity) at which, when surface crust is torn by differential flow, the underlying lava is unable to move sufficiently fast to heal the tear. We attribute pahoehoe formation to the flowage of lava at a low volumetric rate, commonly in tubes that minimize heat loss. Flow units of pahoehoe are small (usually <1 m thick), move slowly, develop a chilled skin, and become virtually static before the viscosity has risen, to the threshold value. We infer that the high-discharge-rate eruptions that generate aa flows result from the rapid emptying of major or subsidiary magma chambers. Rapid near-surface vesiculation of gas-rich magma leads to eruptions with high discharge rates, high lava fountains, and fast-moving channelized flows. We also infer that long periods of sustained flow at a low discharge rate, which favor pahoehoe, result from the development of a free and unimpeded pathway from the deep plumbing system of the volcano and the separation of gases from the magma before eruption. Achievement of this condition requires one or more episodes of rapid magma excursion through the rift zone to establish a stable magma pathway.

Structural control and origin of volcanism in the Taupo volcanic zone, New Zealand

Abstract: Taupor volcanic zone (TVZ) is the currently active volcanic arc and back-arc basin of the Taupo-Hikurangi arc-trench system, North Island, New Zealand. The volcanic arc is best developed at the southern (Tongariro volcanic centre) end of the TVZ, while on the eastern side of the TVZ it is represented mainly by dacite volcanoes, and in the Bay of Plenty andesite/dacite volcanoes occur on either side of the Whakatane graben. The back-arc basin is best developed in the central part of the TVZ and comprises bimodal rhyolite and high-alumina basalt volcanism. Widespread ignimbrite eruptions have occurred from this area in the past 0.6 Ma. Normal faults occur in both arc and back-arc basin. They are generally steeply dipping (>40°) and strike between 040° and 080°. In the back-arc basin, fault zones are en echelon and have the same trend as alignments of rhyolite domes and basalt vents. Open fissures have formed during historic earthquakes along some of the faults, and geodetic measurements on the north side of Lake Taupo suggest extension of 14±4 mm/year. In the Bay of Plenty and ML=6.3 earthquake occurred on 2 March 1987. Modelling of known structure in the area together with data derived from this earthquake suggests block faulting with faults dipping 45°±10° NW and a similar dip is suggested by seismic profiling of faults offshore of the Bay of Plenty where extension is estimated to be 5±2 mm/year. To the east of the TVZ, the North Island shear belt (NISB) is a zone of reverse-dextral, strike-slip faults, the surface expression of which terminates at the eastern end of the TVZ. On the opposite side of the TVZ in the offshore western Bay of Plenty and on line with the NISB is the Mayor Island fault belt. If the two fault belts were once continuous, as seems likely, strike-slip faults probably extend through the basement of the TVZ. When extension associated with the arc and back-arc basin is combined with these strike-slip faults, the resulting transtension provides a suitable tectonic environment for caldera formation and voluminous ignimbrite eruptions in the back-arc basin. The types of volcano in the TVZ are considered to be related to the source of magma and overlying crustal structure. Lavas of the arc are probably formed by a multistage process involving (1) subsolidus slab dehydration, (2) anatexis of the mantle wedge, (3) fractionation and minor crustal assimilation and (4) magma mixing. High-alumina basalts of the back-arc basin may be derived by partial melting of peridotite at the top of the mantle wedge, while rhyolitic magmas are thought to come from partial melting of lavas and subvolcanic reservoirs associated with the southern end of the Coromandel volcanic zone. Extreme thinning associated with transtension in the back-arc basin will favour the eruption of large-volume, gas-rich ignimbrites accompanied by caldera formation.

The Taylor Creek Rhyolite of New Mexico: a rapidly emplaced field of lava domes and flows

Abstract: The Tertiary Taylor Creek Rhyolite of southwest New Mexico comprises at least 20 lava domes and flows. Each of the lavas was erupted from its own vent, and the vents are distributed throughout a 20 km by 50 km area. The volume of the rhyolite and genetically associated pyroclastic deposits is at least 100 km3 (denserock equivalent). The rhyolite contains 15%–35% quartz, sanidine, plagioclase, ±biotite, ±hornblende phenocrysts. Quartz and sanidine account for about 98% of the phenocrysts and are present in roughly equal amounts. With rare exceptions, the groundmass consists of intergrowths of fine-grained silica and alkali feldspar. Whole-rock major-element composition varies little, and the rhyolite is metaluminous to weakly peraluminous; mean SiO2 content is about 77.5±0.3%. Similarly, major-element compositions of the two feldsparphenocryst species also are nearly constant. However, whole-rock concentrations of some trace-elements vary as much as several hundred percent. Initial radiometric age determinations, all K−Ar and fission track, suggest that the rhyolite lava field grew during a period of at least 2 m.y. Subsequent 40Ar/39Ar ages indicate that the period of growth was no more than 100 000 years. The time-space-composition relations thus suggest that the Taylor Creek Rhyolite was erupted from a single magma reservoir whose average width was at least 30 km, comparable in size to several penecontemporaneous nearby calderas. However, this rhyolite apparently is not related to a caldera structure. Possibly, the Taylor Creek Phyolite magma body never became sufficiently volatile rich to produce a large-volume pyroclastic eruption and associated caldera collapse, but instead leaked repeatedly to feed many relatively small domes and flows.

Effusive natrocarbonatite activity of Oldoinyo Lengai, June 1988

Abstract: Oldoinyo Lengai in the Tanzanian rift valley is the only active carbonatite volcano in the world and its natrocarbonatitic lavas are unique in composition. The characteristics of effusive natrocarbonatite activity in June 1988 were studied and fresh samples were directly collected from active carbonatitic lava lakes and flows. Analyses of these samples provide the first information on natrocarbonatites since these unusual volcanic rock type was first described from the 1960–1961 eruptions. The analytical results constrain the original chemistry of fresh natrocarbonatite. Temperatures in lava lakes and of carbonatite lava flows range 491–544°C. The natrocarbonatite lava is extremely fluid at these temperatures and reaches incandescence. The most common variety of natrocarbonatite is porphyritic with abundant phenocrysts of nyerereite (Na0.82K0.19)2(Ca, Sr, Ba)0.975(CO3)2 and gregoryite Na1.74K0.1(Ca, Sr, Ba)0.16CO3, with complex substitution of (CO3)2- by (SO4)2-, (PO4)3-, F-, and Cl-. A phenocryst-poor to aphyric natrocarbonatite variety reflects residual liquids separating from the crystal-rich porphyritic flows. Sylvite, fluorite, and Fe-alabandite (Mn0.7Fe0.3S) have been identified as additional primary magmatic phases. Rare phases in the matrix are witherite (BaCO3) and sellaite (MgF2). Sylvite and gregoryite, and to a lesser extent nyerereite, are water-soluble and are responsible for the immediate decomposition and chemical alteration of natrocarbonatites under atmospheric conditions. A peralkaline combeite-bearing nephelinite lava is closely related to the natrocarbonatite activity, and is isotopically indistinguishable. It is likely that these two magma compositions are related by liquid immiscibility. The unusual hyperalkaline composition of both magma types makes Oldoinyo Lengai an exotic volcano, and its carbonatites have extreme compositions, and are not representative of carbonatites in general.

Volcanic geology and eruption frequency, São Miguel, Azores

Abstract: Six volcanic zones comprise Sao Miguel, the largest island in the Azores. All are Quaternary in age except the last, which is partly Pliocene. From west to east the zones are (1) the trachyte stratovolcano of Sete Cidades, (2) a field of alkali-basalt cinder cones and lava flows with minor trachyte, (3) the trachyte stratovolcano of Agua de Pau, (4) a field of alkali-basalt cinder cones and lava flows with minor trachyte and tristanite, (5) the trachyte stratovolcano of Furnas, and (6) the Nordeste shield, which includes the Povoacao caldera and consists of alkali basalt, tristanite, and trachyte. New radiocarbon and K-Ar ages augment stratigraphic data obtained during recent geologic mapping of the entire island and provide improved data to interpret eruption frequency. Average dormant intervals for the past approximately 3000 years in the areas active during that time are about 400 years for Sete Cidades, 145 for zone 2, 1150 for Agua de Pau, and 370 for Furnas. However, the average dormant interval at Sete Cidades increased from 400 to about 680 years before each of the past two eruptions, and the interval at Furnas decreased from 370 to about 195 years before each of the past four eruptions. Eruptions in zone 4 occurred about once every 1000 years during latest Pleistocene and early Holocene time; none has occurred for about 3000 years. The Povoacao caldera truncates part of the Nordeste shield and probably formed during the middle to late Pleistocene. Calderas formed during latest Pleistocene time at the three younger stratovolcanoes in the sequence: outer Agua de Pau (between 46 and 26.5 ka), Sete Cidades (about 22 ka), inner Agua de Pau (15.2 ka), and Furnas (about 12 ka). Normal faults are common, but many are buried by Holocene trachyte pumice. Most faults trend northwest or west-northwest and are related to the Terceira rift, whose most active segment on Sao Miguel passes through Sete Cidades and zone 2. A major normal fault displaces Nordeste lavas 150–250 m and may mark the location of an ancestral Terceira rift. Recent seismicity (e.g., in the 1980s) generally has been scattered, but some small earthquake swarms have occurred beneath the north-eastern flank of Agua de Pau.

A comparison of rift-zone tectonics in Iceland and Hawaii

Abstract: Observations of eroded volcanic rift zones indicate that dikes in Iceland are typically several times thicker than those in Hawaii. Geodetic and seismic observations of active rifts, however, suggest that dike heights in the two regions are similar. Provided the elastic properties of the rift zones are the same, this implies that dikes are intruded with higher driving pressures (magma pressure minus compressive stress perpendicular to the dike plane) in Iceland than Hawaii. A second major difference between the two regions is the greater prevalence of large normal fault scarps in rift zones in Iceland. From this it can be infered that a lower percentage of dikes breach the surface in Iceland than in Hawaii. Thus, although dikes in Iceland are intruded with higher driving pressures, they possess lower absolute magma pressures than in Hawaii. These differences can be interpreted in terms of the tectonic settings in the two regions. In Iceland, a steady remote extension reduces the horizontal stress perpendicular to the rift zone, allowing dikes to be intruded with low absolute pressures but high driving pressures when magma becomes available. In Hawaii, a more continuous magma supply on the timescale over which the dike-induced stresses are relaxed, and perhaps a greater role for intrusions in driving long-term rift extension, ensure that the rift-compressive stress is not relaxed significantly before the next dike is intruded. Thus the magma pressure must be nearly sufficient for eruption in order for intrusion to occur. If the mechanism for relaxing the rift-compressive stress were less efficient still, then an even higher percentage of dikes would erupt, and at times the rift zone trend could become an unfavorable orientation for dike intrusion. Such might be the case at Mauna Loa, which lacks large rift-zone faults and fissures and possesses numerous radial vents outside its two main rift zones.

Phreatomagmatic and phreatic fall and surge deposits from explosions at Kilauea volcano, Hawaii, 1790 a.d.: Keanakakoi Ash Member

Abstract: In or around 1790 a.d. an explosive eruption took place in the summit caldera of Kilauea shield volcano. A group of Hawaiian warriors close to the caldera at the time were killed by the effects of the explosions. The stratigraphy of pyroclastic deposits surrounding Kilauea (i.e., the Keanakakoi Ash Member) suggests that the explosions referred to in the historic record were the culmination of a prolonged hydrovolcanic eruption consisting of three main phases. The first phase was phreatomagmatic and generated well-bedded, fine fallout ash rich in glassy, variably vesiculated, juvenile magmatic and dense, lithic pyroclasts. The ash was mainly dispersed to the southwest of the caldera by the northeasterly trade winds. The second phase produced a Strombolian-style scoria fall deposit followed by phreatomagmatic ash similar to that of the first phase, though richer in accretionary lapilli and lithics. The third and culminating phase was phreatic and deposited lithic-rich lapilli and block fall layers, interbedded with cross-bedded surge deposits, and accretionary lapilli-rich, fine ash beds. These final explosions may have been responsible for the deaths of the warriors. The three phases were separated by quiescent spells during which the primary deposits were eroded and transported downwind in dunes migrating southwestward and locally excavated by fluvial runoff close to the rim. The entire hydrovolcanic eruption may have lasted for weeks or perhaps months. At around the same time, lava erupted from Kilauea's East Rift Zone and probably drained magma from the summit storage. The earliest descriptions of Kilauea (30 years after the Keanakakoi eruption) emphasize the great depth of the floor (300–500 m below the rim) and the presence of stepped ledges. It is therefore likely that the Keanakakoi explosions were deepseated within Kilauea, and that the vent rim was substantially lower than the caldera rim. The change from phreatomagmatic to phreatic phases may reflect the progressive degassing and cooling of the magma during deep withdrawal: throughout the phreatomagmatic phases magma vesiculation contributed to the explosive interaction with water by initiating the fragmentation process: thereafter, the principal role of the subsiding magma column was to supply heat for steam production that drove the phreatic explosions of the final phase.

Evaluation of gases, condensates, and SO2 emissions from Augustine volcano, Alaska: the degassing of a Cl-rich volcanic system

Abstract: After the March–April 1986 explosive eruption a comprehensive gas study at Augustine was undertaken in the summers of 1986 and 1987. Airborne COSPEC measurements indicate that passive SO2 emission rates declined exponentially during this period from 380±45 metric tons/day (T/D) on 7/24/86 to 27±6 T/D on 8/24/87. These data are consistent with the hypothesis that the Augustine magma reservoir has become more degassed as volcanic activity decreased after the spring 1986 eruption. Gas samples collected in 1987 from an 870°C fumarole on the andesitic lava dome show various degrees of disequilibrium due to oxidation of reduced gas species and condensation (and loss) of H2O in the intake tube of the sampling apparatus. Thermochemical restoration of the data permits removal of these effects to infer an equilibrium composition of the gases. Although not conclusive, this restoration is consistent with the idea that the gases were in equilibrium at 870°C with an oxygen fugacity near the Ni−NiO buffer. These restored gas compositions show that, relative to other convergent plate volcanoes, the Augustine gases are very HCl rich (5.3–6.0 mol% HCl), S rich (7.1 mol% total S), and H2O poor (83.9–84.8 mol% H2O). Values of δD and δ18O suggest that the H2O in the dome gases is a mixture of primary magmatic water (PMW) and local seawater. Part of the Cl in the Augustine volcanic gases probably comes from this shallow seawater source. Additional Cl may come from subducted oceanic crust because data by Johnston (1978) show that Cl-rich glass inclusions in olivine crystals contain hornblende, which is evidence for a deep source (>25km) for part of the Cl. Gas samples collected in 1986 from 390°–642°C fumaroles on a ramp surrounding the inner summit crater have been oxidized so severely that restoration to an equilibrium composition is not possible. H and O isotope data suggest that these gases are variable mixtures of seawater, FMW, and meteoric steam. These samples are much more H2O-rich (92%–97% H2O) than the dome gases, possibly due to a larger meteoric steam component. The 1986 samples also have higher Cl/S, S/C, and F/Cl ratios, which imply that the magmatic component in these gases is from the more degassed 1976 magma. Thus, the 1987 samples from the lava dome are better indicators than the 1986 samples of degassing within the Augustine magma reservoir, even though they were collected a year later and contain a significant seawater component. Future gas studies at Augustine should emphasize fumaroles on active lava domes. Condensates collected from the same lava-dome fumarole have enrichments ot 107–102 in Cl, Br, F, B, Cd, As, S, Bi, Pb, Sb, Mo, Zn, Cu, K, Li, Na, Si, and Ni. Lower-temperature (200°–650°C) fumaroles around the volcano are generally less enriched in highly volatile elements. However, these lower-termperature fumaroles have higher concentration of rock-forming elements, probably derived from the wall rock.

Flow directions in ash-flow tuffs: a comparison of geological and magnetic susceptibility measurements, Tshirege member (upper Bandelier Tuff), Valles caldera, New Mexico, USA

Abstract: This study concludes that the elongation axis (K 1) of the ellipsoid of anisotropic magnetic susceptibility (AMS) is a suitable proxy for flow axis in ashflow tuffs. 153 oriented samples (176 specimens) were studied from 18 sites in the 1.1 Ma Tshirege member of the Bandelier Tuff. These sites are distributed around the Valles caldera at distances of 5–25 km outside of the rim.K 1 axes correlate well with postulated radial flow axes at 13 sites.K 1 also agrees with measured geological flow indicators, mainly imbricated larger clasts, at 7 sites. At 2 of the 5 sites where significant disagreement is seen between theoretical radial flow directions and measuredK 1 axes, theK 1 axes correspond well with geological flow indicators, indicating that the divergence of flow from the predicted radial flow pattern is real. Two major topographic buttresses are suggested as the cause of flow divergence for the Tshirege ash flows: the San Pedro buttress northwest of the caldera, and the San Miguel buttress in the southeast. In situK 1 axes plunge about 7° toward the source at two-thirds of the sites; therefore the plunge ofK 1 is a plausible in situ indicator for thedirection of flow. Multiple flow zones in sections of several meters thickness indicate changes of flow direction that are both rapid and large during ash-flow emplacement. These observations raisre the question of how best to represent ‘mean’ flow directions in ash-flow sheets: by eigenvector methods, by vector-sum methods, or by modes. A method for measuring imbrication of larger clasts using apparent dips in vertical joints is outlined. Imbrication, determined in this way at one-third of the sites, dips toward the source, i.e., up-flow. The minimum (K 3) axis of the AMS ellipsoid correlates with the flow foliation rather than with the larger clast imbrication. The flow axes of ash flows correspond with theK 1 axes, not with the declination ofK 3 axes as suggested by some authors. Initial dip of the sampled ash flows is not large and does not affect the paleomagnetic remanence direction, which is reversed with a mean ofD=173.5°,I=-38.4°, α95=3.4°N=18. This mean is not different at the 95% confidence level from that of earlier workers. The mean pole, at 098.0°E, 74.8°N,A 95=3.3°,N=18, is about 15° far-sided relative to the expected time-averaged geomagnetic pole, suggesting a history of emplacement too short to adequately average secular variation.

Medical effects of volcanic eruptions

Abstract: Excluding famine and tsunamis, most deaths in volcanic eruptions have been from pyroclastic flows and surges (nuees ardentes) and wet debris flows (lahars). Information on the causes of death and injury in eruptions is sparse but the available literature is summarised for the benefit of volcanologists and emergency planners. In nuees, thermal injury may be at least as important as asphyxia in causing immediate deaths. The high temperature of the gases and entrained particles readily causes severe burns to the skin and the air passages and the presence of both types of injury in an individual may combine to increase the delayed mortality risk from respiratory complications or from infection of burns. Trauma from missiles or body displacement is also common, but the role of asphyxiant or irritant gases, and steam, remains unclear. The ratio of dead: injured is much higher than in other natural disasters. At the periphery of a nuee being protected inside buildings which remain intact appears to greatly increase the chances of survival. In lahars, infected wounds and crush injury are the main delayed causes of death, and the scope for preventive measures, other than evacuation, is small. The evidence from Mount St. Helens, 1980, and other major eruptions indicates that, although mortality is high within the main zone of devastation and in the open, emergency planning should concentrate on the periphery of a nuee where preventive measures are feasible and could save many lives in densely populated areas.

The Ninole Basalt — Implications for the structural evolution of Mauna Loa volcano, Hawaii

Abstract: Lava flows of the Ninole Basalt, the oldest rocks exposed on the south side of the island of Hawaii, provide age and compositional constraints on the evolution of Mauna Loa volcano and the southeastward age progression of Hawaiian volcanism. Although the tholeiitic Ninole Basalt differs from historic lavas of Mauna Loa volcano in most major-element contents (e.g., variably lower K, Na, Si; higher Al, Fe, Ti, Ca), REE and other relatively immobile minor elements are similar to historic and prehistoric Mauna Loa lavas, and the present major-element differences are mainly due to incipient weathering in the tropical environment. New K-Ar whole-rock ages, from relatively fresh roadcut samples, suggest that the age of the Ninole Basalt is approximately 0.1–0.2 Ma, although resolution is poor because of low contents of K and radiogenic Ar. Originally considered the remnants of a separate volcano, the Ninole Hills are here interpreted as faulted remnants of the old south flank of Mauna Loa. Deep canyons in the Ninole Hills, eroded after massive landslide failure of flanks of the southwest rift zone, have been preserved from burial by younger lava due to westward migration of the rift zone. Landslide-induced depressurization of the southwest rift zone may also have induced phreatomagmatic eruptions that could have deposited widespread Basaltic ash that overlies the Ninole Basalt. Subaerial presence of the Ninole Basalt documents that the southern part of Hawaii Island had grown to much of its present size above sea level by 0.1–0.2 Ma, and places significant limits on subsequent enlargement of the south flank of Mauna Loa.

Subaqueous, rhyolitic dome-top tuff cones: a model based on the Devonian Bunga Beds, southeastern Australia and a modern analogue

Abstract: The relics of two Late Devonian subaqueous rhyolitic dome-top tuff and pumice cone successions are preserved in the Bunga Beds outlier of the Boyd Volcanic Complex, southeastern Australia. These cone successions and other rhyolitic volcanics of the Bunga Beds are associated with turbidite and other deep-water massflow sedimentary rocks. The two cone successions have a generally similar stratigraphy. At the base, flow-banded, variably autobrecciated and quench-fragmented rhyolite, representing an intrusive to extrusive dome, is overlain by rhyolitesediment breccia, representing extrusion of the dome through the deep-water sediment pile and resedimentation down its flanks. In the northern cone succession an overlying, succession of bedded pumiceous crystal-rich to crystal-poor tuffs represents the onset of pyroclastic activity and growth of a tuff cone. An overyling debris flow deposit represents degradation of part of the cone. The topmost unit, a stratified pumice succession, is thought to represent another cone-building eruptive phase, and is separated from the underlying strata by a major slide surface. The southern cone succession contains less tuff and abundant pumice, and is also terminated by a debris-flow deposit, indicating cone degradation. A modern analogue for the inferred eruptive style and sequence is the 1953–1957 rhyolite eruption that formed the Tuluman Island lava-tuff cone complex in the Bismarck Sea. The eruptions were often cyclical consisting of an initial inferred submarine-lava-forming stage, passing into a pumicecone-forming stage, in some cases a subaeriallava-forming stage, and a final stage, following the cessation of volcanism, during which the cones collapsed gravitationally or were destroyed by wave erosion. Using observations from both the Tuluman Island eruptions and the preserved stratigraphies of the Devonian tuff cones, a dynamic model is proposed for the formation of subaqueous rhyolitic dome-top tuff and pumice cones.

Age and progression of volcanism, Wrangell volcanic field, Alaska

Abstract: The Wrangell volcanic field covers more than 10 000 km2 in southern Alaska and extends uninterrupted into northwest. Yukon Territory. Lavas in the field exhibit medium-K, calc-alkaline affinities, typical of continental volcanic arcs along convergent plate margins. Eleven major eruptive centers are recognized in the Alaskan part of the field. More than 90 K-Ar age determinations in the field show a northwesterly progression of eruptive activity from 26 Ma, near the Alaska-Yukon border, to about 0.2 Ma at the northwest end of the field. A few age determinations in the southeast extension of the field in Yukon Territory, Canada, range from 11 to 25 Ma. The ages indicate that the progression of volcanism in the Alaska part of the field increased from about 0.8 km/Ma, at 25 Ma, to more than 20 km/MA during the past 2 Ma. The progression of volcanic activity and its increased rate of migration with time is attributed to changes in the rate and angle of Pacific plate convergence and the progressive decoupling of the Yakutat terrane from North America. Subduction of Yakutat terrane-Pacific plate and Wrangell volcanic activity ceased about 200 000 years age when Pacific plate motion was taken up by strike-slip faulting and thrusting.

Recent crustal subsidence at Yellowstone Caldera, Wyoming

Abstract: Following a period of net uplift at an average rate of 15±1 mm/year from 1923 to 1984, the east-central floor of Yellowstone Caldera stopped rising during 1984–1985 and then subsided 25±7 mm during 1985–1986 and an additional 35±7 mm during 1986–1987. The average horizontal strain rates in the northeast part of the caldera for the period from 1984 to 1987 were: \(\dot \varepsilon\)1 = 0.10 ± 0.09 μstrain/year oriented N33° E±9° and \(\dot \varepsilon\)2 = 0.20 ± 0.09 μstrain/year oriented N57° W±9° (extension reckoned positive). A best-fit elastic model of the 1985–1987 vertical and horizontal displacements in the eastern part of the caldera suggests deflation of a horizontal tabular body located 10±5 km beneath Le Hardys Rapids, i.e., within a deep hydrothermal system or within an underlying body of partly molten rhyolite. Two end-member models each explain most aspects of historical unrest at Yellowstone, including the recent reversal from uplift to subsidence. Both involve crystallization of an amount of rhyolitic magma that is compatible with the thermal energy requirements of Yellowstone's vigorous hydrothermal system. In the first model, injection of basalt near the base of the rhyolitic system is the primary cause of uplift. Higher in the magmatic system, rhyolite crystallizes and releases all of its magmatic volatiles into the shallow hydrothermal system. Uplift stops and subsidence starts whenever the supply rate of basalt is less than the subsidence rate produced by crystallization of rhyolite and associated fluid loss. In the second model, uplift is caused primarily by pressurization of the deep hydrothermal system by magmatic gas and brine that are released during crystallization of rhyolite and them trapped at lithostatic pressure beneath an impermeable self-sealed zone. Subsidence occurs during episodic hydrofracturing and injection of pore fluid from the deep lithostatic-pressure zone into a shallow hydrostatic-pressure zone. Heat input from basaltic intrusions is required to maintain Yellowstone's silicic magmatic system and shallow hydrothermal system over time scales longer than about 105 years, but for the historical time period crystallization of rhyolite can account for most aspects of unrest at Yellowstone, including seismicity, uplift, subsidence, and hydrothermal activity.

Petrology, geochemistry, and age of the Spurr volcanic complex, eastern Aleutian arc

Abstract: The Spurr volcanic complex (SVC) is a calc-alkaline, medium-K, sequence of andesites erupted over the last 250000 years by the eastern-most currently active volcanic center in the Aleutian arc. The ancestral Mt. Spurr was built mostly of andesites of uniform composition (58%–60% SiO2), although andesite production was episodically interrupted by the introduction of new batches of more mafic magma. Near the end of the Pleistocene the ancestral Mt. Spurr underwent avalanche caldera formation, resulting in the production of a volcanic debris avalanche with overlying ashflows. Immediately afterward, a large dome (the present Mt. Spurr) formed in the caldera. Both the ash flows and dome are made of acid andesite more silicic (60%–63% SiO2) than any analyzed lavas from the ancestral Mt. Spurr, yet contain olivine and amphibole xenocrysts derived from more mafic magma. The mafic magma (53%–57% SiO2) erupted during and after dome emplacement from a separate vent only 3 km away. Hybrid block-and-ash flows and lavas were also produced. The vents for the silicic and mafic lavas are in the center and in the breach of the 5-by-6-km horseshoe-shaped caldera, respectively, and are less than 4 km apart. Late Holocene eruptive activity is restricted to Crater Peak, and magmas continue to be relatively mafic. SVC lavas are plag ±ol+cpx±opx+mt bearing. All postcaldera units contain small amounts of high-Al2O3, high-alkali amphibole, and proto-Crater Peak and Crater Peak lavas contain abundant pyroxenite and anorthosite clots presumably derived from an immediately preexisting magma chamber. Ranges of mineral chemistries within individual samples are often nearly as large as ranges of mineral chemistries throughout the SVC suite, suggesting that magma mixing is common. Elevated Sr, Pb, and O isotope ratios and trace-element systematics incompatible with fractional crystallization suggest that a significant amount of continental crust from the upper plate has been assimilated by SVC magmas during their evolution.

The influence of geometry on the ascent of magma in open fissures

Abstract: During steady eruption, the flow conditions (emitted mass flux, exit velocity and exit pressure) depend on the geometry of the conduit in which the eruption occurs. This dependence is examined for the onedimensional, isothermal ascent of a homogeneous basaltic magma with an aqueous volatile phase and newtonian rheology. By fixing the geometry of the feeding fissure, the mass flux flowing in steady conditions can be determined at any depth, as well the magma pressure and vertical velocity. Flow behaviour is analysed for three fissure shapes: constant width, slowly upward narrowing and lenticular. In all the cases examined the magma arrives at the earth's surface with a pressure greater than atmospheric. The results are compared with those obtained when a lithostatic pressure gradient is assumed for the magma column. Some speculations are made, moreover, about the change in eruption style, if conduit geometry varies during a non-steady phase.

The lateral facies of ignimbrites at Laacher See volcano

Abstract: Valley-fill ignimbrites of the Middle Laacher See Tephra (MLST) in the proximal depositional fan south of Laacher See volcano are laterally continuous with fine-grained overbank-facies deposits, 0.5–1.5 m thick, covering higher elevations and interfluves between the paleovalleys. The overbank deposits consist of up to 12 ash layers, each 4–10 cm thick, which show internal structures typical of ash-flow transport, such as poor sorting, reverse size-grading of pumice, local normal grading of coarse ash-sized lithics above a fine-grained basal layer, cross-stratification behind obstacles, and erosional unconformities. Thickness, median grain-size, and number of individual layers decrease systematically with distance from the vent. Overbank ash layers thicken at the valley slopes and form discrete valley-fill ignimbrite flow units in the paleochannels with median grain size increasing from ≤63 μm to ≤350 μm. Toward the center of paleochannels, however, the well-defined overbank facies is obscured by mutual erosion of individual flow units. Overlapping data fields in ternary grain-size variation diagrams indicate the overbank facies to have evolved from ash flows chiefly through depletion of lapilli and coarse ash. Overbank-facies ash layers do not represent dust layers resulting from elutriation clouds of ash flows (co-ignimbrite ash) or surge deposits developed on higher ground due to low concentration of solids. They are similar in some parameters to Taupo-type ignimbrite veneer deposits, but are interpreted differently. The thin, fine-grained, Laacher See ash layers are thought to have been deposited from diluted portions of the flow proceeding directly from the eruption column while the main pyroclastic flows were confined to the paleovalleys radiating away from the eruptive center. The wide distribution of the thin ash layers is attributed to the balance of deposition from various flow parts and turbulent entraining and heating of ambient air that sustained sufficient mobility of the diluted flows to spread across hills and level ground.

Volcán Las Navajas, a Pliocene-Pleistocene trachyte/peralkaline rhyolite volcano in the northwestern Mexican volcanic belt

Abstract: Volcan Las Navajas, a Pliocene-Pleistocene volcano located in the northwestern portion of the Mexican volcanic belt, erupted lavas ranging in composition from alkali basalt through peralkaline rhyolite, and is the only volcano in mainland Mexico known to have erupted pantellerites. Las Navajas is located near the northwestern end of the Tepic-Zacoalco rift and covers a 200-m-thick pile of alkaline basaltic lavas, one of which has been dated at 4.3 Ma. The eruptive history of the volcano can be divided into three stages separated by episodes of caldera formation. During the first stage a broad shield volcano made up of alkali basalts, mugearites, benmoreites, trachytes, and peralkaline rhyolites was constructed. Eruption of a chemically zoned ash flow then caused collapse of the structure to form the first caldera. The second stage consisted of eruptions of glassy pantellerite lavas that partially filled the caldera and overflowed its walls. This stage ended about 200 000 years ago with the eruption of pumice falls and ash flows, which led to the collapse of the southern portion of the volcano to form the second caldera. During the third stage, two benmoreite cinder cones and a benmoreite lava flow were emplaced on the northwestern flank of the volcano. Finally, the calc-alkaline volcano Sanganguey was built on the southern flank of Las Lavajas. Alkaline volcanism continued in the area with eruptions of alkali basalt from cinder cones located along NW-trending fractures through the area. Although other mildly peralkaline rhyolites are found in the rift zones of western Mexico, only Las Navajas produced pantellerites. Greater volumes of basic alkaline magma have erupted in the Las Navajas region than in the other areas of peralkaline volcanism in Mexico, a factor which may be necessary to provide the initial volume of material and heat to drive the differentiation process to such extreme peralkaline compositions.

Reef growth and volcanism on the submarine southwest rift zone of Mauna Loa, Hawaii

Abstract: A marine sampling program, utilizing the PISCES-5 submersible operated by the Hawaii Undersea Research Laboratory (NOAA), has confirmed the presence of a major submerged coral reef offshore from Ka Lae (South Point), Hawaii. The top of the reef is now 150–160 m below sea level. Radiocarbon and Useries dating indicates that it drowned about 13.9 ka by the combined effects of island subsidence (2.5 mm/year) and the rapid rise of sea level at the end of the last glaciation so that the relative submergence rate of more than 10 mm/year exceeded the upward growth rate of the reef. The submerged reef caps the offshore part of the southwest rift-zone ridge of Mauna Loa, which has apparently undergone little volcanic activity offshore since 170 ka, and possibly since 270 ka. This fact suggests that rift zone activity is becoming increasingly restricted toward the upper part of the volcano, a condition possibly heralding the end of the shield-building stage.

A general model for Mt. Ruapehu lahars

Abstract: A mathematical model of the motion of lahars is presented. Lahar flows and travel speeds are calculated using a kinematic wave model which equates gravitational accelerations to frictional losses. A chezyor Manning-type law of friction is assumed, in which lahar flow rate is a simple power function of lahar depth, multiplied by another simple power of the chanel slope. Use of the model requires knowledge of essentially only one parameter which appears to be relatively insensitive for flows down a given channel. Variable channel slope effects are removed by a longitudinal scaling which applies to all flows down a given channel. For lahars generated by a single explosive event it is unnecessary to perform numerical calculations to predict lahar flow and travel time, but for lahnars produced by multiple sources in which different lahar flows are interacting, numerical calculations appear necessary. The model is applied to all recorded lahar flows from Mt. Ruapehu, and satisfactorily described all lahar flows generated by a single explosive mechanism. Such flows depend essentially only on total lahar volume. The 1968 Mt. Ruapehu lahar, generated by a series of smaller eruptive mechanisms, was modelled as the interaction of seven point sources of fluid originating from positions mathematically extrapolated up the mountain. Good agreement was obtained between the predicted times of formation of these 1968 lahars, and the times of greatest seismic amplitude.

Evolution of the Quaternary melitite-nephelinite Herchenberg volcano (East Eifel)

Abstract: The Quaternary Herchenberg composite tephra cone (East Eifel, FR Germany) with an original bulk volume of 1.17·107 m3 (DRE of 8.2·106 m3) and dimensions of ca. 900·600·90 m (length·width·height) erupted in three main stages: (a) Initial eruptions along a NW-trending, 500-m-long fissure were dominantly Vulcanian in the northwest and Strombolian in the southeast. Removal of the unstable, underlying 20-m-thick Tertiary clays resulted in major collapse and repeated lateral caving of the crater. The northwestern Lower Cone 1 (LC1) was constructed by alternating Vulcanian and Strombolian eruptions. (b) Cone-building, mainly Strombolian eruptions resulted in two major scoria cones beginning initially in the northwest (Cone 1) and terminating in the southeast (Cones 2 and 3) following a period of simultaneous activity of cones 1 and 2. Lapilli deposits are subdivided by thin phreatomagmatic marker beds rich in Tertiary clays in the early stages and Devonian clasts in the later stages. Three dikes intruded radially into the flanks of cone 1. (c) The eruption and deposition of fine-grained uppermost layers (phreatomagmatic tuffs, accretionary lapilli, and Strombolian fallout lapilli) presumably from the northwestern center (cone 1) terminated the activity of Herchenberg volcano. The Herchenberg volcano is distinguished from most Strombolian scoria cones in the Eifel by (1) small volume of agglutinates in central craters, (2) scarcity of scoria bomb breccias, (3) well-bedded tephra deposits even in the proximal facies, (4) moderate fragmentation of tephra (small proportions of both ash and coarse lapilli/bomb-size fraction), (5) abundance of dense ellipsoidal juvenile lapilli, and (6) characteristic depositional cycles in the early eruptive stages beginning with laterally emplaced, fine-grained, xenolith-rich tephra and ending with fallout scoria lapilli. Herchenberg tephra is distinguished from maar deposits by (1) paucity of xenoliths, (2) higher depositional temperatures, (3) coarser grain size and thicker bedding, (4) absence of glassy quenched clasts except in the initial stages and late phreatomagmatic marker beds, and (5) predominance of Strombolian, cone-building activity. The characteristics of Herchenberg deposits are interpreted as due to a high proportion of magmatic volatiles (dominantly CO2) relative to low-viscosity magma during most of the eruptive activity.

Mixed-magma pyroclastic surge deposits associated with debris avalanche deposits at Colima volcanoes, Mexico

Abstract: The transition between the terminal cones and the ancestral edifices of Nevado de Colima and Fuego de Colima volcanoes is marked by the deposits of gigantic volcanic debris avalanches of the Mount St Helens (MSH) or Bezymianny type Unusual mafic juvenile fragments and cauliflower bombs as well as juvenile fragments of mixed and more evolved composition are abundant in dune-bedded pyroclastic-surge deposits directly associated with these catastrophic events at both volcanoes At Nevado, these mafic juvenile fragments represent the most primitive magma ever erupted by the volcano (SiO2∼5250%) The lavas directly preceding and following the debris-avalanche event are silicic andesites (SiO2∼59%) At Fuego these juvenile fregments have ∼56% SiO2 The lavas from the upper parts of the caldera wall are dacites (∼65% SiO2), whereas the terminal cone is composed of andesites (57% to 62% SiO2) At Nevado, petrologic evidence for interaction of mafic magma with andesitic or dacitic magma in a high-level magma chamber, just before the eruption of pyroclastic surge deposits, consists of: (1) banded juvenile bombs of intermediate composition; (2) the range of composition of these bombs from SiO2∼52% to ∼58%; (3) the presence of highly magnesian olivine with reaction rims; (4) inverse zoning in clinopyroxene with strong Mg enrichment towards the rim; (5) resorption of plagioclase; and (6) significant compositional heterogeneity in the vitric phase Volcanic debris-avalanche events at Nevado and Fuego de Colima may thus correspond with major breaks in the petrological evolution of the volcanoes and the start of a new magmatic cycle Injection of mafic magma into the presently perched viscous surface dome of the active Fuego cone, as occurred in 1818 and 1913, could enhance the likelihood of southward collapse of the flank of an already unstable edifice, and it must be considered in future hazard assessment of this active volcano Risk to life and property for the entire Colima region associated with such catastrophic phenomena would be immeasurably greater in comparison with hazards related to the last explosive outburst in 1913, which resulted in emplacement of pyroclastic flows over uninhabited areas of the upper flanks of the volcano

High-precision 40Ar/39Ar sanidine geochronology of ignimbrites in the Mogollon-Datil volcanic field, southwestern New Mexico

Abstract: 40Ar/39Ar age spectra have been obtained from 85 sanidine separates from 36 ignimbrites and one rhyolitic lava in the latest Eocene-Oligocene Mogollon-Datil volcanic field of southwestern New Mexico. Of the 97 measured age spectra, 94 yield weighted-mean plateau ages each giving single-spectrum 1σ precision of±0.25%–0.4% (±0.07–0.14 Ma). Replicate plateau age determinations for eight different samples show within-sample 1σ precisions averaging ±0.25%. Plateau ages from multiple (n=3–8) samples of individual ignimbrites show 1σ within-unit precision of ±0.1%–0.4% (±0.04–0.13 Ma). This within-unit precision represents a several-fold improvement over published K-Ar data for the same ignimbrites, and is similar to the range of precisions reported from single-crystal laser fusion studies. A further indication of the high precision of unit-mean 40Ar/30Ar ages is their close agreement with independently established stratigraphic order. Two samples failed to meet plateau criteria, apparently due to geologic contamination by older feldspars. Effects of minor contamination are shown by six other samples, which yielded slightly anomalous plateau ages. 40Ar/39Ar plateau ages permit resolution of units differing in age by 0.5% (0.15 Ma) or less. This high resolution, combined with paleomagnetic studies, has helped to correlate ignimbrites among isolated ranges and has allowed development of an integrated timestratigraphic framework for the volcanic field. Mogollon-Datil ignimbrites range in age from 36.2 to 24.3 Ma. Ignimbrite activity was strongly episodic, being confined to four brief (<2.6 m.y.) eruptive episodes separated by 1–3 m.y. gaps. Ignimbrite activity generally tended to migrate from the southeast toward the north and west.

The proximal facies of the Tosu pyroclastic-flow deposit erupted from Aso caldera, Japan

Abstract: The Tosu pyroclastic flow deposit, a low-aspect-ratio ignimbrite (LARI), has widely distributed breccia facies around Aso caldera, Japan. The proximal facies, 9–34 km away from the source, consists of 3 different lithofacies, from bottom to top: a lithic-enriched and fines-depleted (FD) facies, a lithic-enriched (LI) facies with an ash matrix, and a fines- and pumice-enriched (NI) facies. Modes of emplacement of FD, LI, and NI are interpreted as ground layer, 2b-lithic-concentration zone, and normal ignimbrite, respectively. These stratigraphic components in the Tosu originated from the flow head (FD) and the flow body (LI and NI), and were generated by a single column collapse event. Remarkably thick FD and LI, in contrast to thin NI, suggest that due to high mobility most ash and punice fragments in the Tosu were carried and deposited as NI in the distal area. Heavier components were selectively deposited as FD and LI in the proximal area. The rate of falloff of lithic-clast size in the Tosu shows an inflection at 20 km from the source. In a survey of well-documented pyroclastic flows, the inflection distance of a LARI is generally greater than that of a high-aspect-ratio ignimbrite, so that the eruption of the former is probably more intense than the latter.

Horizontal ground deformation patterns and magma storage during the Puu Oo eruption of Kilauea volcano, Hawaii: episodes 22-42

Abstract: Horizontal ground deformation measurements were made repeatedly with an electronic distance meter near the Puu Oo eruption site approximately perpendicular to Kilauea's east rift zone (ERZ) before and after eruptive episodes 22–42. Line lengths gradually extended during repose periods and rapidly contracted about the same amount following eruptions. The repeated extension and contraction of the measured lines are best explained by the elastic response of the country rock to the addition and subsequent eruption of magma from a local reservoir. The deformation patterns are modeled to constrain the geometry and location of the local reservoir near Puu Oo. The observed deformation is consistent with deformation patterns that would be produced by the expansion of a shallow, steeply dipping dike just uprift of Puu Oo striking parallel to the trend of the ERZ. The modeled dike is centered about 800 m uprift of Puu Oo. Its top is at a depth of 0.4 km, its bottom at about 2.9 km, and the length is about 1.6 km; the dike strikes N65° E and dips at about 87°SE. The model indicates that the dike expanded by 11 cm during repose periods, for an average volumetric expansion of nearly 500 000 m3. The volume of magma added to the dike during repose periods was variable but correlates positively with the volume of erupted lava of the subsequent eruption and represents about 8% of the new lava extruded. Dike geometry and expansion values are used to estimate the pressure increase near the eruption site due to the accumulation of magma during repose periods. On average, vent pressures increased by about 0.38 MPa during the repose periods, one-third of the pressure increase at the summit. The model indicates that the dikelike body below Puu Oo grew in volume from 3 million cubic meters (Mm3) to about 10–12 Mm3 during the series of eruptions. The width of this body was probably about 2.5–3.0 m. No net long-term deformation was detected along the measured deformation lines.

Potentially active volcanoes of Peru - Observations using Landsat Thematic Mapper and Space Shuttle imagery

Abstract: A synoptic study of the volcanoes of southern Peru (14-17 deg S), the northernmost part of the Central Volcanic Zone (CVZ 14-28 deg S) of the Andes, was conducted on the basis of Landsat TM images and color photography. The volcanoes were classified and their relative ages determined using subtle glacial-morphological features. Eight of them were postulated as potentially active. These are located in a narrow volcanic zone which probably reflects a steep dip of the Nazca plate through the zone of magma generation. The break in the trend of the volcanic arc possibly reflects the complexity of the crustal stress field above a major segment boundary in the subducting plate. There are also fields of mafic monogenetic centers in this region. In comparison with the southern part of the CVZ, the general paucity of older volcanic edifices north of 17 deg S suggested a more recent onset of volcanism, a possible result of the oblique subduction of the Nazca ridge and the consequent northward migration of its intersection with the Peru-Chile trench. This, together with the lack of any large silicic caldera systems and youthful dacite domes, suggested that there are real differences in the volcanic evolution of the two parts of the CVZ.

Maximum entropy spectral analysis of volcanic tremor using data from Etna (Sicily) and Merapi (central Java)

Abstract: The maximum entropy spectral analysis (MESA) method is applied to synthetic and observed tremor time series using autoregressive processes and recordings from the volcanoes Etna (Sicily) and Merapi (central Java). The MESA analysis can be used to estimate power spectra with sharp peaks from short data records. If the tremor source process can be modelled by an autoregressive process, the MESA method is well-suited for determining the coefficients of the underlying difference equations. As in the standard periodogram method of power spectrum estimation, a mesagram estimate using record segmentation and MESA spectrum averaging reduces the variance of the spectral estimator. In combination with periodogram estimates, mesagram estimates confirm that the tremor source may be modelled as an ensemble of randomly excited resonators. Used together, these estimates provide a valuable method for short-term monitoring of volcanic activity. In addition, they can be applied to the determination of new source parameters such as resonator frequencies, damping coefficients, excitation probabilities, correlation of exciting forces, and resonator coupling and in the pattern recognition of source types.

The 1928–1929 eruption of Kammourta volcano — evidence of tectono-magmatic activity in the Manda-Inakir rift and comparison with the Asal Rift, Afar depression, Republic of Djibuti

Abstract: There are two rifts zones in the Republic of Djibuti: the active Asal rift (birthplace of the Ardoukoba basaltic volcano in 1978) and the poorly known Manda-Inakir rift described here. The most recent volcanic event in the Manda-Inakir rift was the formation of the Kammourta basaltic cone, probably in 1928, accompanied by strong seismic activity. This historic eruption and related tectonic features show that the Manda-Inakir rift, like Asal, is presently active. The Kammourta basalt, of transitional alkaline type, belongs to the Manda-Inakir differentiated series, which ranges from basalt to rhyolite. In contrast, volcanic rocks of the Asal rift are entirely transitional tholeiitic basalt. The differences in magmatic affinity and tectonics between these two rift zones reflect the more advanced evolution of rifting in the Asal zone than in Manda-Inakir.

Characterization of ultrafine aerosol particles in Mt. Etna emissions

Abstract: Particulate emissions from Mt. Etna in the fine-size range below 100 nm were studied in June and September 1989. The aerosol particles were characterized by size, concentration and photoelectric activity. These quantities are sensitive to the physical and chemical properties of the magma. Concentrations varied from 104 to 107 cm-3. The size distributions peak below 20 nm (radius) and are very narrow. The particles are generated mainly by nucleation and condensation of magmatic volatiles in a strong temperature gradient. The photoelectric activity of these particles can indicate high magma levels and increased exsolution of volatiles. It is therefore related to the observed activity of the respective crater and may be helpful as a prediction tool when used in conjunction with other volcano-monitoring techniques.

Fumarole distribution, morphology, and encrustation mineralogy associated with the 1986 eruptive deposits of mount St. Augustine, Alaska

Abstract: Numerous rootless fumaroles were developed on pyroclastic flows and a lava flow generated during the March 1986 eruptive cycle of Mount St. Augustine. Gases issued from fumarole vents with four different shapes: fissure, phreatic explosion crater, single/multiple ovoid opening, and diffuse, multiple opening. Fumarole distribution and morphology were controlled by preeruption drainage and topography, as well as by the thickness, compaction, and settling of the flow deposits. Fumarole temperatures measured in June and July 1986 ranged from 75°–394°C. Varying amounts of colorful and often roughly zoned encrustations are associated with all fumarole vent shapes. Only six types of crystalline phases were detected by X-ray diffraction, with gypsum the most abundant mineral, followed by anhydrite, sulfur, tridymite, halite, and soda alum. Scanning electron microscopy and energy dispersive X-ray analysis revealed a number of amorphous phases, mainly halogen-rich, as well as other minor crystalline phases. The mineral assemblages in the encrustations suggest formation conditions for these deposits within a general range of 25°–250°C in an oxidizing environment. Many of the amorphous phases are metastable and upon cooling of the fumarole lose nonstructural water and crystallize to more stable forms. The high halogen contents of the fumarole condensates and the mineralogy, chemistry, and morphology of the encrustations support leaching of the andesitic ash and lava flow by condensed acid vapors as the primary source for the chemical components contained in the encrustations. Comparison of traceelement (Sr, Ba, V, Co, Ni, and Cr) contents in unaltered and altered ash suggests that trace-element distribution follows a pattern of isomorphic substitution in the encrustation phases.