Showing papers in "Journal of Inorganic and Nuclear Chemistry in 1966"

TL;DR: In this article, the interaction of triphenylphosphine, -arsine and -stibine with hydrated ruthenium trichloride in methanol leads to a variety of complexes such as [RuCl2(PPh3)4], [RuCL2(SbPh3]3], RuCl3(Pph3)2CH3OH, [RuC2(CPh3As, Ph3Sb, pyridine etc., with a carbonyl-containing solution] and the corresponding brom

TL;DR: In this paper, the experimental half-lives for alpha, beta and spontaneous fission decay are analysed for the heavy elements (A ≥ 140). From the systematic behaviour of these data, semi-empirical relationships are derived for use in the prediction of lifetimes for undiscovered nuclides.

TL;DR: The spin-free ruthenium trichloride carboxylates were described in this paper, where they have high magnetic moments over the temperature range 300-100°K.

TL;DR: In this article, the solubilities of MnO, FeO, CoO and NiO in ZnO have been determined over the temperature range of 500-800°C by hydrothermal techniques.

TL;DR: In this paper, it was found that the separation factor β of rare earths in the system: HEHφP-HCl aq. shows some regularities depending on the atomic number of the lanthanon.

TL;DR: In this paper, a quasi-theoretical relation between the oxygen pressure and the nonstoicheiometry has been derived for the phase UO 2+ x and U 3 O 8− z.

TL;DR: In this article, the interaction between Cu(II) and various bidentate chelating agents is investigated, and the reaction steps for single and mixed ligand chelates of the corresponding mixed ligands are described.

TL;DR: In this paper, the photochemical behavior of some cyanide complexes has been investigated at various wavelengths, with particular reference to irradiation in the ligand field spectral region, and a reaction mechanism involving a primary photoaquation reaction was proposed.

TL;DR: The empirical formula of anhydrous ZP materials with P/Zr = 2 is of the type Zr(HPO4)2 as mentioned in this paper, and the results are discussed.

TL;DR: In this article, Fischer's method was used to obtain the ytterbium tricyclopentadienide free from any additional Lewis base, which can only be obtained by reacting YbCl3 with KC5H5 in toluene.

TL;DR: In this paper, the magnetic properties of these powders suggest the material to be antiferromagnetic with a superparamagnetic behaviour, and the absence of a magnetic hyperfine splitting in the Mossbauer spectra is possibly due to the small size of the particles.

TL;DR: The absorption spectra of neptunium (III, (IV, (V) and (VI) in 2 molar perchloric acid have been measured in the wavelength region 400-1400 mμ as mentioned in this paper.

TL;DR: The separation efficiency of dialkyl phosphoric acids for the lanthanides does not depend much on the structure, nor on the size of the alkyl group as mentioned in this paper.

TL;DR: In this article, the preparation of three different types of carbonates, namely, praseodymium (nodes), terbium (tars), and naphase, has been described and the thermal properties of these carbonates have been studied exhaustively under a variety of conditions.

TL;DR: In this paper, the quadrupole splitting of the ferrous and ferric complexes of the Fe57 Mossbauer spectra and magnetic susceptibility data have been obtained on twenty-eight complexes of ferrous or ferric iron.

TL;DR: In this paper, the variations of Kd for Cs+ and titration curves as function of time were determined for thermally-treated samples of zirconium phosphate, and the interrelation between pyrophosphate formed, loss in total ion exchange capacity and variation in selective properties of thermally treated ZP samples was discussed.

TL;DR: The thermochemistry and thermodynamics of the exchange of Li+, K+, Rb+, Cs+, Ca2+, S2+ and Ba2+ with the Na+ ions in Linde Sieve X have been investigated in this article.

TL;DR: The structure of two cation exchangers, hydrous thorium oxide (THO) and hydrous titanium oxide (TiHO), were studied by thermogravimetric measurements, ir spectra and X-ray diffraction as mentioned in this paper.

TL;DR: In this article, the mass predictions are made by empirical extrapolation of α- and β-decay energies which fit together to form closed cycles, based upon the most recent work of Wapstra et al.

TL;DR: Dimethyl formamide complexes of five rare-earth nitrates, M(DMF)4(NO3)3 where M = La, Pr, Nd, Sm or Y have been prepared and their infra-red spectra and conductivities in nitromethane and DMF studied.

TL;DR: Several palladium (II) complexes containing co-ordinated sulphato groups are reported in this paper, and chemical and infra-red spectral evidence suggest that the complexes [PdphenSO4], Pdpy2SO4·H2O, [Pd(DMSO) 2SO4] and PdSO4−2H2

TL;DR: In this paper, the infra-red absorption spectra of fourteen inorganic anhydrous crystalline aluminates were obtained in the 10·5−24·5 μ range.

TL;DR: Complexes of the Lewis acids, sulphur trioxide, antimony (V) chloride, tin (IV) chloride and aluminium (III) chloride with formamide, acetamide, benzamide,acetanilide and benzanilide have been studied for elucidating their structure.

TL;DR: In this paper, the mixed oxide system ThO2CeO2O2O3 was investigated using X-ray powder techniques and the results showed that the reduced solid solutions had an anion vacancy structure with a = 2a0 (fluorite).

TL;DR: The isotructural hetero-9-molybdate ions are stable monomers at high concentrations in saturated aqueous Na2SO4. as mentioned in this paper made comments on the spectra of the two complexes.

TL;DR: In this article, the infra-red spectra (667-222 cm−1) of twenty-two bis(ethylenediamine) cobalt (III) complexes are reported.

TL;DR: In this paper, the tetrakis chelates were compared with the tris chelate (BTF) 3 Eu·2H 2 O. The tris-chelate showed stronger europium fluorescence.

TL;DR: In this article, a number of coordination compounds with 2,2′-bipyridine-1,1′-dioxide(bipyO2) have been synthesized.

TL;DR: In this article, a phase diagram for the system ZnMnO showing the phases which can exist in air at temperatures between 600°C and 1450°C was proposed.

TL;DR: In this article, the distribution of nitric acid and water between aqueous acid and 100% tri-n -butyl phosphate (TBP) solutions is analyzed using the Gibbs-Duhem relation.