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Showing papers in "Minerals in 2021"


Journal ArticleDOI
31 Jan 2021-Minerals
TL;DR: This study reviewed 109 research papers that discuss ML techniques for mineral exploration, exploitation, and mine reclamation over the past decade and demonstrated that ML studies have been actively conducted in the mining industry since 2018.
Abstract: Recent developments in smart mining technology have enabled the production, collection, and sharing of a large amount of data in real time. Therefore, research employing machine learning (ML) that utilizes these data is being actively conducted in the mining industry. In this study, we reviewed 109 research papers, published over the past decade, that discuss ML techniques for mineral exploration, exploitation, and mine reclamation. Research trends, ML models, and evaluation methods primarily discussed in the 109 papers were systematically analyzed. The results demonstrated that ML studies have been actively conducted in the mining industry since 2018, mostly for mineral exploration. Among the ML models, support vector machine was utilized the most, followed by deep learning models. The ML models were evaluated mostly in terms of their root mean square error and coefficient of determination.

42 citations


Journal ArticleDOI
13 Apr 2021-Minerals
TL;DR: In this article, two types of SWs, including fly ash (FA) and desulfurized gypsum (DG), were used to prepare cementitious backfilling materials for underground mined-out areas.
Abstract: The utilization of solid wastes (SWs) as a potential resource for backfilling is not only conducive to environmental protection but also reduces the surface storage of waste. Two types of SWs, including fly ash (FA) and desulfurized gypsum (DG), were used to prepare cementitious backfilling materials for underground mined-out areas. Ordinary Portland cement (OPC) was used as cement in mine backfill. To better investigate the feasibility of preparing backfill materials, some laboratory tests, such as uniaxial compressive strength (UCS), scanning electron microscopy (SEM), and energy dissipation theory, were conducted to explore both strength and microstructural properties of backfilling. Results have demonstrated that the main components of FA and DG in this study are oxides, with few toxic and heavy metal components. The ideal ratio of OPC:FA:DG is 1:6:2 and the corresponding UCS values are 2.5 and 4.2 MPa when the curing time are 7 days and 14 days, respectively. Moreover, the average UCS value of backfilling samples gradually decreased when the proportion of DG in the mixture increased. The main failure modes of various backfilling materials are tensile and shearing cracks. In addition, the corresponding relations among total input energy, dissipated energy and strain energy, and stress–strain curve were investigated. The spatial distribution of oxygen, aluminum, silicon, calcium, iron and magnesium elements, and hydration product are explored from the microstructure’s perspective. The findings of this study provide both invaluable information and industrial applications for the efficient management of solid waste, based on sustainable development and circular economy.

40 citations


Journal ArticleDOI
20 Mar 2021-Minerals
TL;DR: Amp-TB2.xlsx as discussed by the authors is a spreadsheet for calculating the physico-chemical parameters from the composition of natural amphiboles, which gives warnings whenever the input composition is incorrect or diverges from that of the calibration data.
Abstract: Amphibole (Amp) plays a crucial role in the study of several earth and planetary processes. One of its most common applications is in thermobarometry, especially for volcanic-magmatic systems. However, many thermobarometers require the input of melt composition, which is not always available in volcanic products (e.g., partially crystallized melts or devitrified glasses), or show rather high errors for characterizing the depth of magma chambers. In this work, a new version of amphibole thermobarometry based on the selection of recently published high-quality experimental data is reported. It is valid for Mg-rich calcic amphiboles in magmatic equilibrium with calc-alkaline or alkaline melts across a wide P-T range (up to 2200 MPa and 1130 °C) and presents the advantage of being a single-phase model with relatively low errors (P ±12%, T ±22 °C, logfO2 ±0.3, H2O in the melt ±14%). A user-friendly spreadsheet (Amp-TB2.xlsx) for calculating the physico-chemical parameters from the composition of natural amphiboles is also reported. It gives warnings whenever the input composition is incorrect or diverges from that of the calibration data and includes diagrams for an easy graphical representation of the results.

38 citations


Journal ArticleDOI
13 Mar 2021-Minerals
TL;DR: In this article, the authors integrated monitoring of an active landslide, located in Western Greece, using low-cost and high-repeatability remote sensing data like those obtained by UAVs.
Abstract: Landslides are posing a significant global hazard as they occur instantaneously with devastating consequences. The development of new remote sensing technologies and innovative processing techniques over the past few years opened up new horizons and perspectives in landslide monitoring research. The purpose of the current research is the integrated monitoring of an active landslide, located in Western Greece, using low-cost and high-repeatability remote sensing data like those obtained by unmanned aerial vehicles (UAVs). Repeated UAV campaigns and global navigation satellite systems (GNSS) surveys were performed to assess the activity of the landslide and determine its kinematic behavior. UAV data were processed using structure from motion (SfM) photogrammetry and the generated high-detailed orthophotos and digital surface models (DSMs) were submitted in further processing procedure in an ArcGIS environment. Regarding the GNSS data, a new low-cost technique for the estimation of the direction and the rate of movement of the displaced material was developed. The repeated measurements were displayed in a vector format in a three-axis diagram. In addition, GNSS measurements were used to verify the results of the photogrammetric processing. The final assessment was carried out taking into account geological data such as petrographic and crystallographic features of the material of the landslide. It was observed that the lithology and consequently the petrographic properties of the material plays a key role regarding the activity of the landslide.

31 citations


Journal ArticleDOI
30 Apr 2021-Minerals
TL;DR: In this article, the Wadi Hodein shear belt is a ductile shear corridor developed in response to noncoaxial convergence and northward escape tectonics that accompanied the final stages of terrane accretion and cratonization in the northern part of the Arabian-Nubian Shield.
Abstract: Space-borne multispectral and radar data were used to comprehensively map geological contacts, lithologies and structural elements controlling gold-bearing quartz veins in the Wadi Hodein area in Egypt. In this study, enhancement algorithms, band combinations, band math (BM), Principal Component Analysis (PCA), decorrelation stretch and mineralogical indices were applied to Landsat-8 OLI, ASTER and ALOS PALSAR following a pre-designed flow chart. Together with the field observations, the results of the image processing techniques were exported to the GIS environment and subsequently fused to generate a potentiality map. The Wadi Hodein shear belt is a ductile shear corridor developed in response to non-coaxial convergence and northward escape tectonics that accompanied the final stages of terrane accretion and cratonization (~680–600 Ma) in the northern part of the Arabian–Nubian Shield. The evolution of this shear belt encompassed a protracted ~E–W shortening and recurrent sinistral transpression as manifested by east-dipping thrusts and high-angle reverse shear zones. Gold-mineralized shear zones cut heterogeneously deformed ophiolites and metavolcaniclastic rocks and attenuate in and around granodioritic intrusions. The gold mineralization event was evidently epigenetic in the metamorphic rocks and was likely attributed to rejuvenated tectonism and circulation of hot fluids during transpressional deformation. The superposition of the NW–SE folds by NNW-trending, kilometer scale tight and reclined folds shaped the overall framework of the Wadi Hodein belt. Shallow NNW- or SSE-plunging mineral and stretching lineations on steeply dipping shear planes depict a considerable simple shear component. The results of image processing complying with field observations and structural analysis suggest that the coincidence of shear zones, hydrothermal alteration and crosscutting dikes in the study area could be considered as a model criterion in exploration for new gold targets.

31 citations


Journal ArticleDOI
30 Jan 2021-Minerals
TL;DR: In this paper, the authors focus on the precipitation of gypsum from a range of aspects and highlight discrepancies between microscopic and macroscopic observations, and studies carried out under low and high ionic strengths.
Abstract: Gypsum (CaSO4·2H2O) is the most common sulfate mineral on Earth and is also found on Mars. It is an evaporitic mineral that predominantly precipitates from brines. In addition to its precipitation in natural environments, gypsum also forms an undesired scale in many industrial processes that utilize or produce brines. Thus, better insights into gypsum formation can contribute to the understanding of natural processes, as well as improving industrial practices. Subsequently, the thermodynamics, nucleation and crystal growth mechanisms and kinetics, and how these factors shape the morphology of gypsum have been widely studied. Over the last decade, the precipitation of gypsum under saline and hypersaline conditions has been the focus of several studies. However, to date, most of the thermodynamic data are derived from experiments with artificial solutions that have limited background electrolytes and have Ca2+/SO42− ratios that are similar to the 1:1 ratio in the mineral. Moreover, direct observations of the nucleation and growth processes of gypsum are still derived from experimental settings that can be described as having low ionic strength. Thus, the mechanisms of gypsum precipitation under conditions from which the mineral precipitates in many natural environments and industrial processes are still less well known. The present review focuses on the precipitation of gypsum from a range of aspects. Special attention is given to brines. The effects of ionic strength, brine composition, and temperature on the thermodynamic settings are broadly discussed. The mechanisms and rates of gypsum nucleation and growth, and the effect the thermodynamic properties of the brine have on these processes is demonstrated by recent microscopic and macroscopic observations. The morphology and size distribution of gypsum crystals precipitation is examined in the light of the precipitation processes that shape these properties. Finally, the present review highlights discrepancies between microscopic and macroscopic observations, and studies carried out under low and high ionic strengths. The special challenges posed by experiments with brines are also discussed. Thus, while this review covers contemporary literature, it also outlines further research that is required in order to improve our understanding of gypsum precipitation in natural environments and industrial settings.

30 citations


Journal ArticleDOI
29 Jun 2021-Minerals
TL;DR: In this paper, the authors provide an overview of tungsten mines, including the potential for reprocessing of tailings, including its environmental risks and potential for exploration, as well as the primary and secondary resources.
Abstract: Tungsten is recognized as a critical metal due to its unique properties, economic importance, and limited sources of supply. It has wide applications where hardness, high density, high wear, and high-temperature resistance are required, such as in mining, construction, energy generation, electronics, aerospace, and defense sectors. The two primary tungsten minerals, and the only minerals of economic importance, are wolframite and scheelite. Secondary tungsten minerals are rare and generated by hydrothermal or supergene alteration rather than by atmospheric weathering. There are no reported concerns for tungsten toxicity. However, tungsten tailings and other residues may represent severe risks to human health and the environment. Tungsten metal scrap is the only secondary source for this metal but reprocessing of tungsten tailings may also become important in the future. Enhanced gravity separation, wet high-intensity magnetic separation, and flotation have been reported to be successful in reprocessing tungsten tailings, while bioleaching can assist with removing some toxic elements. In 2020, the world’s tungsten mine production was estimated at 84 kt of tungsten (106 kt WO3), with known tungsten reserves of 3400 kt. In addition, old tungsten tailings deposits may have great potential for exploration. The incomplete statistics indicate about 96 kt of tungsten content in those deposits, with an average grade of 0.1% WO3 (versus typical grades of 0.3–1% in primary deposits). This paper aims to provide an overview of tungsten minerals, tungsten primary and secondary resources, and tungsten mine waste, including its environmental risks and potential for reprocessing.

27 citations


Journal ArticleDOI
24 Nov 2021-Minerals
TL;DR: In this article, the thermal stability of hydroxyapatite prepared by a solid-state mechanochemical method and structural changes occurring during sintering were studied. But the data available in the literature are very contradictory.
Abstract: High-temperature powder sintering is an integral part of the dense ceramic manufacturing process. In order to find the optimal conditions for producing a ceramic product, the information about its behavior at high temperatures is required. However, the data available in the literature are very contradictory. In this work, the thermal stability of hydroxyapatite prepared by a solid-state mechanochemical method and structural changes occurring during sintering were studied. Stoichiometric hydroxyapatite was found to remain as a single-phase apatite structure with the space group P63/m up to 1300 °C inclusively. A further increase in the sintering temperature leads to its partial decomposition, a decrease in the crystallite size of the apatite phase, and the appearance of significant structural strains. It was shown that small deviations from stoichiometry in the Ca/P ratio upward or downward during the hydroxyapatite synthesis lead to a significant decrease in the thermal stability of hydroxyapatite. An apatite containing almost no hydroxyl groups, which is close to the composition of oxyapatite, was prepared. It was shown that the congruent melting of stoichiometric hydroxyapatite upon slow heating in a high-temperature furnace does not occur. At the same time, the fast heating of hydroxyapatite by laser radiation allows, under certain conditions, its congruent melting with the formation of a recrystallized monolayer of oxyhydroxyapatite. The data obtained in this study can be used when choosing sintering conditions to produce hydroxyapatite-based ceramics.

26 citations


Journal ArticleDOI
21 Mar 2021-Minerals
TL;DR: In this paper, the risk of harmful effects of heavy metals presence in the bottom sediments of the Warta River, the third longest river in Poland, has been assessed in terms of the indices: the Geoaccumulation Index (Igeo), Enrichment Factor (EF), Pollution Load Index (PLI), and Metal Pollution Index (MPI).
Abstract: Pollution of river bottom sediments with heavy metals (HMs) has emerged as a main environmental issue related to intensive anthropopressure on the water environment. In this context, the risk of harmful effects of the HMs presence in the bottom sediments of the Warta River, the third longest river in Poland, has been assessed. The concentrations of Cr, Ni, Cu, Zn, Cd, and Pb in the river bottom sediments collected at 24 sample collection stations along the whole river length have been measured and analyzed. Moreover, in the GIS environment, a method predicting variation of HMs concentrations along the whole river length, not at particular sites, has been proposed. Analysis of the Warta River bottom sediment pollution with heavy metals in terms of the indices: the Geoaccumulation Index (Igeo), Enrichment Factor (EF), Pollution Load Index (PLI), and Metal Pollution Index (MPI), has proved that, in 2016, the pollution was heavier than in 2017. Assessment of the potential toxic effects of HMs accumulated in bottom sediments, made on the basis of Threshold Effect Concentration (TEC), Midpoint Effect Concentration (MEC), and Probable Effect Concentration (PEC) values, and the Toxic Risk Index (TRI), has shown that the ecological hazard in 2017 was much lower. Cluster analysis revealed two main groups of sample collection stations at which bottom sediments showed similar chemical properties. Changes in classification of particular sample collection stations into the two groups analyzed over a period of two subsequent years indicated that the main impact on the concentrations of HMs could have their point sources in urbanized areas and river fluvial process.

25 citations


Journal ArticleDOI
07 Jul 2021-Minerals
TL;DR: It is established that the sustainable development of the mining and processing region is impossible without a highly efficient exploitation of natural deposits and man-made georesources in combination with an integrated approach to the development of subsurface resources.
Abstract: The possibility of replacing the traditional components of the filling mass with man-made waste and the need for the use of mechanical activation of the components of the filling composite in order to improve its rheological characteristics and the strength of the mass after solidification are proved. The demand for resource-reproducing technologies that allow the most complete use of the industrial mineral resource potential of the mining and processing enterprise, which will lead to a multiplicative ecological and economic effect, is confirmed. It is necessary to introduce the re-processing of man-made waste in order to further extract the useful component to a level that meets the standards of environmental safety and economic feasibility, which would create conditions for the actual sustainable development and give some perspectives for extending the operating time of mining regions. It is established that the sustainable development of the mining and processing region is impossible without a highly efficient exploitation of natural deposits and man-made georesources in combination with an integrated approach to the development of subsurface resources.

24 citations


Journal ArticleDOI
03 Jun 2021-Minerals
TL;DR: The literature reveals that the machine learning methods are better predictors compared to the empirical models, however, it is observed that presently these ML models are mainly applied in academic research.
Abstract: Rock fragmentation in mining and construction industries is widely achieved using drilling and blasting technique. The technique remains the most effective and efficient means of breaking down rock mass into smaller pieces. However, apart from its intended purpose of rock breakage, throw, and heave, blasting operations generate adverse impacts, such as ground vibration, airblast, flyrock, fumes, and noise, that have significant operational and environmental implications on mining activities. Consequently, blast impact studies are conducted to determine an optimum blast design that can maximize the desirable impacts and minimize the undesirable ones. To achieve this objective, several blast impact estimation empirical models have been developed. However, despite being the industry benchmark, empirical model results are based on a limited number of factors affecting the outcomes of a blast. As a result, modern-day researchers are employing machine learning (ML) techniques for blast impact prediction. The ML approach can incorporate several factors affecting the outcomes of a blast, and therefore, it is preferred over empirical and other statistical methods. This paper reviews the various blast impacts and their prediction models with a focus on empirical and machine learning methods. The details of the prediction methods for various blast impacts—including their applications, advantages, and limitations—are discussed. The literature reveals that the machine learning methods are better predictors compared to the empirical models. However, we observed that presently these ML models are mainly applied in academic research.

Journal ArticleDOI
23 Mar 2021-Minerals
TL;DR: In this paper, the authors reviewed the scientific studies carried out in order to use waste (steriles and tailings) generated in mining activities for the manufacture of clay-based ceramic materials containing mullite as a main crystalline phase.
Abstract: Mullite (3Al2O3·2SiO2) is an aluminosilicate characterized by excellent physical properties, which makes it an important ceramic material. In this way, ceramics based on mullite find applications in different technological fields as refractory material (metallurgy, glass, ceramics, etc.), matrix in composite materials for high temperature applications, substrate in multilayer packaging, protective coatings, components of turbine engines, windows transparent to infrared radiation, etc. However, mullite is scarce in nature so it has to be manufactured through different synthesis methods, such as sintering, melting-crystallization or through a sol-gel route. Commonly, mullite is fabricated from pure technical grade raw materials, making the manufacturing process expensive. An alternative to lowering the cost is the use of mining waste as silica (SiO2) and alumina (Al2O3) feedstock, which are the necessary chemical compounds required to manufacture mullite ceramics. In addition to the economic benefits, the use of mining waste brings out environmental benefits as it prevents the over-exploitation of natural resources and reduces the volume of mining waste that needs to be managed. This article reviews the scientific studies carried out in order to use waste (steriles and tailings) generated in mining activities for the manufacture of clay-based ceramic materials containing mullite as a main crystalline phase.

Journal ArticleDOI
25 Nov 2021-Minerals
TL;DR: In this article, the compressive strength of geopolymers was analyzed and the most common practice was the use of sodium hydroxide combined with sodium silicate, where the optimum SS/NaOH ratio depends on the source of aluminosilicates to be used.
Abstract: Geopolymers are created by mixing a source of aluminosilicates, which can be natural or by-products from other industries, with an alkaline solution. These materials based on by-products from other industries have proven to be a less polluting alternative for concrete production than ordinary Portland cement (OPC). Geopolymers offer many advantages over OPC, such as excellent mechanical strength, increased durability, thermal resistance, and excellent stability in acidic and alkaline environments. Within these properties, mechanical strength, more specifically compressive strength, is the most important property for analyzing geopolymers as a construction material. For this reason, this study compiled information on the different variables that affect the compressive strength of geopolymers, such as Si/Al ratio, curing temperature and time, type and concentration of alkaline activator, water content, and the effect of impurities. From the information collected, it can be mentioned that geopolymers with Si/Al ratios between 1.5 and 2.0 obtained the highest compressive strengths for the different cases. On the other hand, high moderate temperatures (between 80 and 90 °C) induced higher compressive strengths in geopolymers, because the temperature favors the geopolymerization process. Moreover, longer curing times helped to obtain higher compressive strengths for all the cases analyzed. Furthermore, it was found that the most common practice is the use of sodium hydroxide combined with sodium silicate to obtain geopolymers with good mechanical strength, where the optimum SS/NaOH ratio depends on the source of aluminosilicates to be used. Generally speaking, it was observed that higher water contents lead to a decrease in compressive strength. The presence of calcium was found to be favorable in controlled proportions as it increases the compressive strength of geopolymers, on the other hand, impurities such as heavy metals have a negative effect on the compressive strength of geopolymers.

Journal ArticleDOI
28 Sep 2021-Minerals
TL;DR: In this article, the authors acknowledge the funding from the Water Research Commission (WRC) of South Africa and express their appreciation for the academic support of the Environmental and Nano Sciences (ENS) research group at the University of the Western Cape (South Africa).
Abstract: Funding text 1 Acknowledgments: The authors acknowledge the funding from the Water Research Commission (WRC) of South Africa and express their appreciation for the academic support of the Environmental and Nano Sciences (ENS) research group at the University of the Western Cape (South Africa). Funding text 2 The authors would like to thank the Water Research Commission (WRC) of South Africa for funding the research project through WRC K5/2483. The authors acknowledge the funding from the Water Research Commission (WRC) of South Africa and express their appreciation for the academic support of the Environmental and Nano Sciences (ENS) research group at the University of the Western Cape (South Africa).

Journal ArticleDOI
01 Jan 2021-Minerals
TL;DR: In this paper, a short history of the use of cobalt as a colouring agent of glass, glaze and enamel in the Western/Mediterranean, Islamic and Asian worlds since Antiquity is presented.
Abstract: Minerals able to colour in blue (and green in combination with yellow pigments) are limited in number and geologically. After presenting a short history of the use of cobalt as a colouring agent of glass, glaze and enamel in the Western/Mediterranean, Islamic and Asian worlds since Antiquity, we will present the different forms (dissolved ions, natural and synthetic crystalline phases/pigments) of cobalt and associated elements regarding primary (transition metals) and secondary geological deposits (transition metals and/or arsenic, bismuth, silver). Attempts to identify the origin of cobalt have been made by many authors considering the associated elements but without considering the important modifications due to different processing of the raw materials (extraction/purification/formulation). We review the information available in the ancient reports and present literature on the use of cobalt, its extraction and production from the ores, the different geological sources and their relationship with associated elements (transition metals, bismuth, arsenic, and silver) and with technological/aesthetic requirements. (Partial) substitution of cobalt with lapis lazuli is also addressed. The relative application of non-invasive mobile Raman and pXRF analytical instruments, to detect mineral phases and elements associated with/replacing cobalt is addressed, with emphasis on Mamluk, Ottoman, Chinese, Vietnamese and Japanese productions. The efficiency of Ni-Zn-As diagram proposed by Gratuze et al. as a classification tool is confirmed but additionally, CoO-Fe2O3−MnO and CoO-NiO-Cr2O3 diagrams are also found as very efficient tools in this research. The relationship between the compositional data obtained from the artefacts and historical questions on the origin and date of their production are discussed in order to obtain a global historical view. The need of a better knowledge of (ancient) deposits of cobalt ores and the evolution of cobalt ore processing with time and place is obvious.

Journal ArticleDOI
14 Oct 2021-Minerals
TL;DR: In this article, the authors classified the development of deep-sea polymetallic nodule mining technology into three stages, and its characteristics are summarized, including proposals for mining systems, research into key technologies, basic scientific problems, and proof of technical feasibility from sea tests.
Abstract: Deep-sea polymetallic nodules are a mineral resource with potential for commercial development. Due to the unique deep-sea environment in which they are found, specialized technology and equipment are required for their extraction. In this paper, firstly, the development of deep-sea polymetallic nodule mining technology is classified into three stages, and its characteristics are summarized. Moreover, the results from research into deep-sea polymetallic nodule mining technology are analyzed, including proposals for mining systems, research into key technologies, basic scientific problems, and proof of technical feasibility from sea tests. Secondly, the testing of the collector prototype and the environmental impact assessment study of Global Sea Mineral Resources NV, as well as the progress of the deep-sea polymetallic nodule mining test project in China, are introduced. On this basis, the opportunities and challenges brought by the fast-growing demand for electric vehicles to the development of deep-sea polymetallic mining technology is analyzed, and a possible technical scheme for a mining system and the trends in its development towards high reliability and high standards of environmental protection according to the requirements of commercial exploitation are explored. This provides a reference for the research and development of high-efficiency technology and equipment for the mining of deep-sea polymetallic nodules.

Journal ArticleDOI
08 Aug 2021-Minerals
TL;DR: In this article, the authors discuss the need for the further development and implementation of new tailings management technologies and innovations, and for the application of whole-of-life costing of tailings facilities.
Abstract: Different regions worldwide have adopted various approaches to tailings management, as a result of the site settings and local practices as they have evolved. Tailings dam failures have continued to occur in both developing and developed countries, necessitating a range of tailings management approaches. These failures, while rare, continue to occur at a frequency that exceeds both industry and society expectations, and there is much to be learned from well-documented cases. Tailings management continues to be overly reliant on a net present value approach using a high discount factor, rather than a whole-of-life approach that may result in safer and more stable tailings facilities and may also facilitate the eventual mine closure. There is a need for the further development and implementation of new tailings management technologies and innovations, and for the application of whole-of-life costing of tailings facilities. Changes in tailings management will most readily be achieved at new mining projects, making change across the minerals industry a generational process.

Journal ArticleDOI
26 Mar 2021-Minerals
TL;DR: In this article, an up-to-date overview of major vibrational modes of rock-forming minerals in the shortwave (SWIR), mid (MIR) and thermal (TIR) infrared reflectance spectra is provided.
Abstract: Reflectance spectroscopy allows cost-effective and rapid mineral characterisation, addressing mineral exploration and mining challenges Shortwave (SWIR), mid (MIR) and thermal (TIR) infrared reflectance spectra are collected in a wide range of environments and scales, with instrumentation ranging from spaceborne, airborne, field and drill core sensors to IR microscopy However, interpretation of reflectance spectra is, due to the abundance of potential vibrational modes in mineral assemblages, non-trivial and requires a thorough understanding of the potential factors contributing to the reflectance spectra In order to close the gap between understanding mineral-diagnostic absorption features and efficient interpretation of reflectance spectra, an up-to-date overview of major vibrational modes of rock-forming minerals in the SWIR, MIR and TIR is provided A series of scripts are proposed that allow the extraction of the relative intensity or wavelength position of single absorption and other mineral-diagnostic features Binary discrimination diagrams can assist in rapidly evaluating mineral assemblages, and relative abundance and chemical composition of key vector minerals, in hydrothermal ore deposits The aim of this contribution is to make geologically relevant information more easily extractable from reflectance spectra, enabling the mineral resources and geoscience communities to realise the full potential of hyperspectral sensing technologies

Journal ArticleDOI
16 Jun 2021-Minerals
TL;DR: In this paper, airborne geophysical and remote sensing datasets were integrated for gold potentiality mapping (GPM) over the Atalla area in Central Eastern Desert, Egypt using the center for exploration targeting (CET) procedure.
Abstract: In this research, airborne geophysical and remote sensing datasets were integrated for gold potentiality mapping (GPM) over the Atalla area in Central Eastern Desert, Egypt. Utilizing aeromagnetic data, detailed structural complexity maps were constructed using the center for exploration targeting (CET) procedure. Then, spectrometric gamma-ray data primarily located hydrothermally altered tracts with discriminating various rock units. The latter are precisely outlined by implementing various techniques (false-color composite (FCC), band ratio (BR), relative absorption band depth (RBD), directed principal component analysis (DPCA), and constrained energy minimization (CEM)) to ASTER, Sentinel 2 and ALOS PRISM datasets, with reference to the geological maps. The study exhibits that gold mineralization is structurally controlled by NW-SE direction. The findings of structural complexity and hydrothermal alteration (argillic, advanced argillic, phyllic, and propylitic) were used as weighted inputs for contouring gold potentiality. The resultant GPM accentuated five gold-promising zones; two are confirmed via locations of ancient gold mines, while the remaining three zones are strongly recommended for their gold potentiality.

Journal ArticleDOI
28 Jun 2021-Minerals
TL;DR: A review of coal mine dust exposure in coal mines is presented in this article, where the primary sources of RCMD along with health risks from potential exposure are highlighted, and the current exposure regulations of the major coal producer countries are compared.
Abstract: In the late 1990s, despite years of efforts to understand and reduce coal worker’s pneumoconiosis (CWP) prevalence from more than 30% in 1970 to less than 4.2%, the level of occurrence among the US coal miners increased unexpectedly. The recent resurgence of lung diseases has raised concerns in the scientific and regulatory communities. In 2014, the United States Mine Safety and Health Administration (MSHA) issued a new dust rule changing the respirable coal mine dust (RCMD) exposure limits, measurement technology, and sampling protocol. The analysis for probable causes for the substantial increase in the CWP incidence rate is rather complicated. This paper aims to conduct a review of RCMD respiratory deposition, health effects, monitoring, regulations, and particle characteristics. The primary sources of RCMD along with the health risks from potential exposure are highlighted, and the current RCMD exposure regulations of the major coal producer countries are compared. A summary of RCMD characterization studies from 1972 to the present is provided. A review of the literature revealed that numerous factors, including geological and mining parameters, advancements in mining practices, particle characteristics, and monitoring approaches are considered to contribute to the recent resurgence of RCMD lung diseases. However, the root causes of the problem are still unknown. The effectiveness of the new dust rules in the United States will probably take years to be correctly assessed. Therefore, future research is needed to understand the relationship between RCMD particle characteristics and lung deposition, and the efficacy of current monitoring practices to measure the true dose of RCMD exposure.

Journal ArticleDOI
31 May 2021-Minerals
TL;DR: In this article, a low-cost drone-based photogrammetry was utilized for mapping geology with the objective of mineral exploration in the Shahzadeh Abbas Cu deposit, Kerman province, Iran.
Abstract: In this research, drone-based photogrammetry was utilized for mapping geology with the objective of mineral exploration in the Shahzadeh Abbas Cu deposit, Kerman province, Iran. Cu mineralization is of vein-type and follows geological structures. A low-cost drone was used to collect geological data. A spatial resolution of 3.26 cm was achieved by considering a flight altitude of 70 m. To reach the accuracy of less than 5 cm, 70% lateral and 80% front image overlaps were applied and 220 temporary ground control points (TGCPs) were used in an area of 2.02 km2. TGCPs were accurately positioned using DGPS-RTK measurements. Agisoft PhotoScan software was used for photogrammetric processing. The orthophoto product was performed for outlining geological units through visual interpretation. The digital elevation model (DEM) was converted to a hill-shade model in ArcGIS software to extract the geological structures such as faults and dikes. A draft geology map was prepared using orthophoto and hill-shade images to minimize the time and cost of the subsequent field work. Rock sampling was carried out and Cu-bearing veins were specified through field investigations. The geology map was finalized based on field work data and petrology studies. The geological survey indicated that diabase dikes with a northwest–southeast strike often host Cu mineralization in the study area. The position of Cu-bearing dikes was delineated for the next stage of the exploration program. This research demonstrated the time- and cost-effectiveness of using drone-based photogrammetry for preparing base geology maps for the exploration of vein-type mineralization in far districts with rough topography.

Journal ArticleDOI
01 May 2021-Minerals
TL;DR: The Sample Analysis at Mars (SAM) instrument on the Curiosity rover has detected evidence of oxychlorine compounds (i.e., perchlorates and chlorates) in Gale crater, which has implications for past habitability, diagenesis, aqueous processes, interpretation of in situ organic analyses, understanding the martian chlorine cycle, and hazards and resources for future human exploration as mentioned in this paper.
Abstract: The Sample Analysis at Mars (SAM) instrument on the Curiosity rover has detected evidence of oxychlorine compounds (i.e., perchlorates and chlorates) in Gale crater, which has implications for past habitability, diagenesis, aqueous processes, interpretation of in situ organic analyses, understanding the martian chlorine cycle, and hazards and resources for future human exploration. Pure oxychlorines and mixtures of oxychlorines with Mars-analog phases have been analyzed for their oxygen (O2) and hydrogen chloride (HCl) releases on SAM laboratory analog instruments in order to constrain which phases are present in Gale crater. These studies demonstrated that oxychlorines evolve O2 releases with peaks between ~200 and 600 °C, although the thermal decomposition temperatures and the amount of evolved O2 decrease when iron phases are present in the sample. Mg and Fe oxychlorines decompose into oxides and release HCl between ~200 and 542 °C. Ca, Na, and K oxychlorines thermally decompose into chlorides and do not evolve HCl by themselves. However, the chlorides (original or from oxychlorine decomposition) can react with water-evolving phases (e.g., phyllosilicates) in the sample and evolve HCl within the temperature range of SAM (<~870 °C). These laboratory analog studies support that the SAM detection of oxychlorine phases is consistent with the presence of Mg, Ca, Na, and K perchlorate and/or chlorate along with possible contributions from adsorbed oxychlorines in Gale crater samples.

Journal ArticleDOI
26 Mar 2021-Minerals
TL;DR: In this article, the pyrite textures and trace elements in the Sizhuang gold deposit (>100 t Au) were investigated to document the key factors impacting on the genesis of the Jiaodong-type orogenic deposits.
Abstract: Gold deposits in the Jiaodong Peninsula represent a primary gold resource in China and mostly exhibit similar ore-forming features related to sericite-quartz-pyrite alteration and other controls from (micro-)structural deformation. This study investigates the pyrite textures and trace elements in the Sizhuang gold deposit (>100 t Au) to document the key factors impacting on the genesis of the Jiaodong-type orogenic deposits. Three main types of pyrite are identified: (1) the first generation of pyrite (Py1) occurs as disseminated euhedral to subhedral grains in K-feldspar-albite-rutile-hematite and sericite alteration (stage 1), (2) Py2 as aggregates in quartz-sericite-pyrite altered rocks or quartz-pyrite veins (stage 2) can be subdivided into Py2a as irregular cores, Py2b as a zoned overgrowth on Py2a, and Py2c as overgrowth on early pyrite, and (3) Py3 as fine-grained crystals in siderite-polymetallic veins (stage 3). Primary gold at the Sizhuang deposit is coevally or slightly later deposited with Py2b, Py2c, and Py3. Laser ablation–inductively coupled plasma mass spectrometry (LA–ICP–MS) analyses show that the highest Co and Ni contents in Py1 and high but variable Co in Py2b favors the involvement of deep high-temperature magmatic waters at stage 1 and middle stage 2. The elevated As contents from Py2a to Py2c and depletion of trace elements (e.g., Co, Ni, As and Te) and high Au/Co, Cu/Ni, and As/Ni values in Py2a and Py3, combined with published H-O isotope data, imply a meteoric water ingress during stage 2–3. Thus, the fluid evolution at Sizhuang is a consequence of pulsed deep magmatic fluid release plus progressive meteoric fluid ingress. The rhythmic Co–As–Ni–Au bands of Py2b additionally suggest episodic changes in the composition of ore-forming fluids. Moreover, the sharp textural features (e.g., pyrite overgrowth on previously cataclastic crystals) of Py2 and As-Cu-rich and Co-poor bands in zoned Py2b probably also reflect rapid metal deposition and self-organization and subsequent mineral crystal growth due to the pressure release during phase separation in the Sizhuang deposit. Considering the significantly concentrated gold (>1300 t) in the regional Jiaojia fault zone and Au-bearing mineral formation related to phase separation (boiling) in the Sizhuang deposit, gold mineralization in the Sizhuang deposit was interpreted to be controlled by the pressure-driver owing to the seismic activities in the Jiaojia fault system.

Journal ArticleDOI
06 Aug 2021-Minerals
TL;DR: For example, this article found that ancient fluvio-lacustrine sedimentary rocks in Gale crater contain up to 35 wt. % phyllosilicates, which are key indicators of past fluid-rock interactions and suggest changes in past aqueous environments that may have been habitable to microbial life.
Abstract: Curiosity, the Mars Science Laboratory (MSL) rover, landed on Mars in August 2012 to investigate the ~3.5-billion-year-old (Ga) fluvio-lacustrine sedimentary deposits of Aeolis Mons (informally known as Mount Sharp) and the surrounding plains (Aeolis Palus) in Gale crater. After nearly nine years, Curiosity has traversed over 25 km, and the Chemistry and Mineralogy (CheMin) X-ray diffraction instrument on-board Curiosity has analyzed 30 drilled rock and three scooped soil samples to date. The principal strategic goal of the mission is to assess the habitability of Mars in its ancient past. Phyllosilicates are common in ancient Martian terrains dating to ~3.5–4 Ga and were detected from orbit in some of the lower strata of Mount Sharp. Phyllosilicates on Earth are important for harboring and preserving organics. On Mars, phyllosilicates are significant for exploration as they are hypothesized to be a marker for potential habitable environments. CheMin data demonstrate that ancient fluvio-lacustrine rocks in Gale crater contain up to ~35 wt. % phyllosilicates. Phyllosilicates are key indicators of past fluid–rock interactions, and variation in the structure and composition of phyllosilicates in Gale crater suggest changes in past aqueous environments that may have been habitable to microbial life with a variety of possible energy sources.

Journal ArticleDOI
07 Mar 2021-Minerals
TL;DR: In this article, the authors present an overview of the latest advances in the emerging technologies of CO2-mineralization via industrial solid waste in China, from the perspective of both theoretical and practical considerations.
Abstract: CO2 mineralization (aka mineral carbonation) is a promising method for the chemical sequestration of CO2 via reaction with oxides of alkaline or alkaline-earth metals to form carbonates. It has documented advantages over similar technological solutions to climate change. The huge amount of industrial solid waste, as a serious environmental issue confronted by China, can provide additional alkalinity sources for CO2 mineralization. In this study, we present an overview of the latest advances in the emerging technologies of CO2-mineralization via industrial solid waste in China, from the perspective of both theoretical and practical considerations. We summarize the types of industrial solid waste that are used (mainly coal fly ash, steel slag, phosphogypsum, and blast furnace slag) and the technological options available in the literature, with an emphasis on the discussion of the involved process-intensification methods and valuable chemicals produced. Furthermore, we illustrate the current status of pertinent policies, and research and development activities in China. Finally, we identify the current knowledge gaps, particularly in understanding the overall sustainability performance of these CO2-mineralization technologies, and indicate that the technical, economic, and environmental challenges of promoting and commercializing these technologies for the co-utilization of industrial solid waste and carbon resources call for, amongst other things, more joint efforts by chemists, chemical engineers, and environmental scientists, and more feedback from the energy and industrial sectors.

Journal ArticleDOI
19 Jan 2021-Minerals
TL;DR: In this article, the authors present a research overview, reconciling key and useful case study findings, towards uncovering major causes of gold refractoriness and maximising extraction performance of specific gold flotation and bio-oxidation products.
Abstract: This paper presents a research overview, reconciling key and useful case study findings, towards uncovering major causes of gold refractoriness and maximising extraction performance of specific gold flotation and bio-oxidation products. Through systematic investigation of the ore mineralogical and gold deportment properties, leaching mechanisms, and kinetic behaviour and pulp rheology, it was observed that the predominant cause of the poor extraction efficacy of one bio-oxidised product is the presence of recalcitrant sulphate minerals (e.g., jarosite and gypsum) produced during the oxidation process. This was followed by carbonaceous matter and other gangue minerals such as muscovite, quartz, and rutile. The underpining leaching mechanism and kinetics coupled with the pulp rheology were influenced by the feed mineralogy/chemistry, time, agitation/shear rate, interfacial chemistry, pH modifier type, and mechano-chemical activation. For instance, surface exposure of otherwise unavailable gold particles by mechano-chemical activation enhanced the gold leaching rate and yield. This work reflect the remarkable impact of subtle deposit feature changes on extraction performance.

Journal ArticleDOI
30 Jun 2021-Minerals
TL;DR: In this paper, the possibility of using minerals of other groups with different abilities to expand the structure and structural charge for the adsorption of chemical environmental pollutants was analyzed. And the structural characteristics of various groups of phyllosilicates and chain minerals that affect their ability to modify organic surfactants and the adsorsption properties of prepared organoclays were reviewed.
Abstract: An important goal in environmental research for industrial activity and sites is the investigation and development of effective adsorbents for chemical pollutants that are widespread, inexpensive, unharmful to the environment, and have the required adsorption selectivity. Organoclays are adsorption materials that can be obtained by modifying clays and clay minerals with various organic compounds through intercalation and surface grafting. Organoclays have important practical applications as adsorbents of a wide range of organic pollutants and some inorganic contaminants. The traditional raw materials for the synthesis of organoclays are phyllosilicates with the expanding structural cell of the smectite group, such as montmorillonite. Moreover, other phyllosilicates and inosilicates are used to synthesize organoclay to a limited extent. The purpose of this review was to analyze the possibility of using minerals of other groups with different abilities to expand the structure and structural charge for the adsorption of chemical environmental pollutants. The structural characteristics of various groups of phyllosilicates and chain minerals that affect their ability to modify organic surfactants and the adsorption properties of prepared organoclays were reviewed.

Journal ArticleDOI
15 Jan 2021-Minerals
TL;DR: In this article, the uniaxial compressive strength and porosity of backfills and the curing age in the three groups were studied, and change laws of the porosity variation and strength growth rate of backfill were analyzed.
Abstract: At present, the filling mining method is widely used. To study strength evolution laws of cemented tailings backfill (CTB) under different curing ages, in the experiment, mine tailings were used as aggregates, ordinary Portland cement (PC32.5) was used as cementing materials, and different additives (lime and fly ash) were added to make filling samples with the solids mass concentration at 74% and the cement-sand ratios 1:4, 1:6 and 1:8. Based on the nuclear magnetic resonance (NMR) technology, the porosity test of filling samples with curing ages of 3 d, 7 d and 28 d was carried out, and the uniaxial compressive strength test was carried out on the servo universal material testing machine. The relationship between the uniaxial compressive strength and porosity of backfills and the curing age in the three groups was studied, and change laws of the porosity variation and strength growth rate of backfills were analyzed. Based on the variation in porosity, the strength evolution model of the CTB under different curing ages was established, and the model was fitted and verified with test data. Results show that the uniaxial compressive strength, porosity, porosity variation, and strength growth rate of the three groups of backfills gradually increase with the increase of the curing age, the porosity of backfill basically increases with the decrease of the cement–sand ratio, and the porosity of backfill decreases with the increase of the curing age. Porosity variations and relative strength values of the three groups of backfills under different cement-sand ratios obey an exponential function, and the two have a good correlation, indicating that the established filling strength evolution model can well reflect strength evolution laws of the CTB with the change of curing age.

Journal ArticleDOI
28 Mar 2021-Minerals
TL;DR: In this paper, the authors present an analysis of the influence that inclusion of geosites or mining sites could have on the existing routes of the Zaruma-Portovelo region (Ecuador), together with a global assessment of these itineraries as the basis of fostering local development in communities of the region.
Abstract: Travel itineraries are fundamental in the development of tourism of a given area Traditional thematic routes (eg, architectural, archaeological) can be significantly improved and optimized by including geological and mining interest sites The present study offers an analysis of the influence that inclusion of geosites or mining sites could have on the existing routes of the Zaruma-Portovelo region (Ecuador), together with a global assessment of these itineraries as the basis of fostering local development in communities of the region The methodology consists of the following stages: (i) compilation of existing travel itineraries; (ii) analysis and assessment of those geosites and mining sites that are included in two geotouristic routes through the Spanish Inventory of Places of Geological Interest method (IELIG, acronym in Spanish), but have not been assessed previously; (iii) assessment of existing routes (two geotouristic routes and one geomining route) from a global perspective through the Geotouristic Route Assessment Matrix method (GtRAM, acronym in Spanish); and (iv) definition of strategies for the development and promotion of travel itineraries within the context of geotourism According to the results of quantitative assessment, three new sites (both geosites and mining sites) were studied and their obtained score of interest was “High” (164/400) The existing routes achieved good results both from the geological-mining perspective “High” score of (189/400) and within a global context “Very High” score of (35/5) The quantitative assessment allowed us to propose improvement strategies to disseminate and use these itineraries to unfold sustainable development based on geotourism

Journal ArticleDOI
21 Jan 2021-Minerals
TL;DR: In this paper, an evaluation of the environmental impacts of industrial-scale processing for the recycling of post-consumer gypsum waste was conducted with an established life cycle assessment software.
Abstract: Gypsum is widely used in the construction sector, and its worldwide consumption has been increasing for several decades. Depending on the lifetime of the used gypsum products, an increase of gypsum in construction and demolition waste follows. Especially against the background of a circular economy, the recycling of waste gypsum is of growing importance. However, the use of recycled gypsum only makes sense if it is environmentally friendly. Therefore, an evaluation of the environmental impacts of industrial-scale processing for the recycling of post-consumer gypsum waste was conducted. The evaluation was performed with an established life cycle assessment software. Original data provided by the industry and complementary data from a database for life cycle assessments were used for the calculations. Two scenarios for recycled gypsum with different transportation distances were calculated. These results were compared with the results of the environmental evaluation of gypsum derived from coal-fired power plants (FGD gypsum) and natural gypsum. The results showed that the utilization of recycled gypsum can be environmentally advantageous compared to the use of natural gypsum or FGD gypsum, especially in the impact categories of land transformation and resource consumption (abiotic depletion potential). For most environmental impact categories, the specific transportation distances have a strong influence.