Journal ArticleDOI
681. The structure of o-iodosobenzoic acid and of certain derivatives
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This article is published in Journal of The Chemical Society (resumed).The article was published on 1965-01-01. It has received 45 citations till now.read more
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Novel 10‐I‐3 Hypervalent Iodine‐Based Compounds for Electrophilic Trifluoromethylation
TL;DR: Preliminary results for the direct electrophilic transfer of the trifluoromethyl moiety onto organic nucleophiles show modest reactivity in polar aprotic solvents under relatively mild conditions.
Journal ArticleDOI
Stoichiometric and catalytic oxidations with hypervalent organo-lambda3-iodanes.
TL;DR: In this article, the authors reported the isolation, characterization, and reaction of the activated iodosylbenzene monomer, hydroxy(phenyl)iodonium ion, as a complex with 18-crown-6 (18C6) are reported.
Journal ArticleDOI
1-(Organosulfonyloxy)-3(1H)-1,2-benziodoxoles: Preparation and Reactions with Alkynyltrimethylsilanes
TL;DR: Organosulfonyloxy derivatives of 1,2-benziodoxol-3( 1H)-one (3a-c) and 3,3-bis(trifluoromethyl)-3(1H)-1, 2-benZiodoxole (5a- c) can be prepared in high yield by the reaction of 1-hydroxybenzodoxoles 1 or 4 and the corresponding sulfonic acids or Me(3)Si
Journal ArticleDOI
Hypervalent (tert-Butylperoxy)iodanes Generate Iodine-Centered Radicals at Room Temperature in Solution: Oxidation and Deprotection of Benzyl and Allyl Ethers, and Evidence for Generation of α-Oxy Carbon Radicals
Masahito Ochiai,Takao Ito,Hideo Takahashi,Akinobu Nakanishi,Mika Toyonari,Takuya Sueda,Satoru Goto,Motoo Shiro +7 more
TL;DR: In this article, a 1-(tert-butylperoxy)-1,2-benziodoxol-3(1H)-one (1a) was used to oxidize benzyl and allyl ethers to the esters at room temperature in benzene or cyclohexane.
Journal ArticleDOI
Hypervalent Iodine‐Mediated Aziridination of Alkenes: Mechanistic Insights and Requirements for Catalysis
TL;DR: Detailed study of the possible side reactions in the previously reported aziridination of alkenes with N-aminoheterocycles mediated by hypervalent iodine reagents gives tentative evidence that the reaction proceeds through formation of an aminoiodane that reacts directly with the alkene, contrary to previous literature reports.
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