Journal ArticleDOI
A 26·9° C isothermal calorimeter and its application to the measurement of some heats of copolymerization of sulphur dioxide with olefines, and the reassessement of the kinetic data on the butene-2 systems
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This article is published in Transactions of The Faraday Society.The article was published on 1957-01-01. It has received 31 citations till now. The article focuses on the topics: Calorimeter & Butene.read more
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Thermodynamic functions of linear high polymers: Part I—polyoxymethylene
TL;DR: In this paper, an adiabatic, vacuum calorimeter was used to determine the heat capacity of two samples of polyoxymethylene (prepared by different routes) in the temperature range 20° to 300°K. Entropy and enthalpy values have been derived for the two polymers and listed at ten degree intervals.
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The effect of alkyl substitution on the thermodynamic stability and kinetic reactivity of α-anions of metal—carbene complexes
TL;DR: In this paper, it was shown that alkyl substitution has only small effects on the thermodynamic and kinetic acidity and on the reactivity of anions generated α to the carbene carbon atom in metal-carbene complexes.
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Sulfur-containing polymers
TL;DR: Sulfur-containing polymers vary from highly reactive to chemically inert substances; they can have high softening points or be viscous oils, be thermally stable or not.
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Studies in surface chemistry of carbon blacks part III. Interaction of carbon blacks and aqueous bromine
Balwant Rai Puri,R.C. Bansal +1 more
TL;DR: In this paper, it was shown that the fixation of bromine takes place at the sites vacated by the CO 2 -complex; one molecule of Bromine is fixed for every two molecules of the complex eliminated during the history of formation of the black.
Journal ArticleDOI
Thermally Stable Polysulfones Obtained by Regiospecific Radical Copolymerization of Various Acyclic and Cyclic 1,3-Diene Monomers with Sulfur Dioxide and Subsequent Hydrogenation
TL;DR: In this article, the thermally stable alternating copolymers from various acyclic and cyclic alkyl-substituted 1,3-diene monomers with sulfur dioxide (SO2) as the starting comonomers were synthesized by radical copolymerization and subsequent hydrogenation.