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A formaldehyde-free accelerated cure aqueous composition for bonding glass fiber-heat resistant nonwovens

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TLDR
In this article, a formaldehyde-free curable aqueous composition comprising a polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts of the polyacid thereof is presented.
Abstract
A formaldehyde-free curable aqueous composition comprising: (a) a polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts of the polyacid thereof; (b) an active hydrogen compound containing at least two active hydrogen groups selected from the group consisting of hydroxyl, primary amino, secondary amino, and mixtures thereof; and (c) a fluoroborate accelerator; wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of said hydroxyl groups is from 1/0.01 to about 1/3, and wherein said carboxylic acid groups, anhydride groups, or salts thereof are neutralized to an extent of less than 35% with a fixed base is disclosed. A method for curing formaldehyde-free polyacids and a method for bonding glass fiber heat-resistant nonwovens with a formaldehyde-free binder are further disclosed.

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Binders and materials made therewith

TL;DR: In this paper, a curable aqueous composition was proposed, comprising a carbohydrate, a crosslinking agent, and an amine base, with a pH adjusted by the base.
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TL;DR: In this article, a polycarboxy binder composition that contains a dextrin as a co-binder is provided, and a prebinder composition is formed by admixing the poly carboxy polymer, the cross-linking agent, and optionally, the catalyst, in a mixing device.
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References
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Curable aqueous composition and use as fiberglass nonwoven binder

TL;DR: In this paper, a formaldehyde-free curable aqueous composition containing a polyacid, a polyol and a phosphorous-containing accelerator was proposed for heat resistant nonwovens.
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Fibrous glass binders

TL;DR: A fibrous glass binder comprises a polycarboxy polymer, a β-hydroxyalkylamide, and an at least trifunctional monomeric carboxylic acid as discussed by the authors.
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TL;DR: In this article, a method for strengthening a cellulosic substrate by treating the substrate with a formaldehyde-free curable aqueous composition and curing the composition was proposed.
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Low-formaldehyde, self-crosslinking polymer latex composition

TL;DR: In this article, a low-formaldehyde polymer latex composition is described, which comprises at least one polymer latex and at least a formaldehyde scavenging agent, which reduces formaldehyde evolution during drying and curing of these compositions.
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Water soluble binder compositions containing beta-hydroxy urethanes and polyfunctional carboxylic acids

TL;DR: The binder composition of this invention contains a beta-hydroxy urethane functional material and a polycarboxylic acid as mentioned in this paper, which is used for coating glass fibers.