Journal ArticleDOI
A NEW STABLE FREE RADICAL: DI-t-BUTYLNITROXIDE
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This article is published in Journal of the American Chemical Society.The article was published on 1961-11-01. It has received 131 citations till now.read more
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Nitroxides: applications in synthesis and in polymer chemistry.
Ludger Tebben,Armido Studer +1 more
TL;DR: Alkoxyamines derived from nitroxides are shown to be highly useful precursors of C-centered radicals in synthesis and also in polymer chemistry, and new developments in the synthesis of complex polymer architectures are highlighted.
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Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions.
TL;DR: This review provides a comprehensive survey of the electrochemical properties and electrocatalytic applications of aminoxyls, imidoxylS, and related reagents, of which the two prototypical and widely used examples are 2,2,6,6-tetramethylpiperidine N-oxyl (TEMPO) and phthalimide N- oxyl (PINO).
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Physics and chemistry of spin labels.
TL;DR: Nuclear relaxation in biological systems containing spin labels and anisotropic motion of spin labels in biological membranes are analyzed.
Journal ArticleDOI
50th Anniversary Perspective: Living Polymerization—Emphasizing the Molecule in Macromolecules
TL;DR: In this paper, the authors present the case that this concept has enabled the treatment of polymers as organic molecules, rather than impure mixtures of species, and allowed the translation of methods developed by synthetic organic chemists into ever more accessible living and/or controlled polymerization methods.