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Journal ArticleDOI

A new synthetic route to TTF-vinylogues

T. Imakubo, +3 more
- 01 Mar 2001 - 
- Vol. 120, pp 899-900
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TLDR
In this paper, a new and simple method for the synthesis of TTF-vinylogues based on the Wittig-type reaction is presented. But the method is not suitable for the TTFV synthesis with substituent substituents.
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This article is published in Synthetic Metals.The article was published on 2001-03-01. It has received 12 citations till now. The article focuses on the topics: Wittig reaction & Substituent.

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Journal ArticleDOI

Synthesis, Reactions, and Selected Physico-Chemical Properties of 1,3-and 1,2-Tetrachalcogenafulvalenes

TL;DR: In this article, the synthesis of 1,3-and 1,2-tetrachalcogenafulvalenes, the chemical transformation of substituents, reactions of the ring systems and synthesis of polymers with tetrathiafulvalene units in the backbone and in the side chain are discussed.
Journal ArticleDOI

New extended analogues of TTF via triethylphosphite-mediated reaction

TL;DR: In this paper, extended derivatives of TTF bearing cyanoethylsulfanyl or furan groups which cannot be obtained by Wittig-type reaction with Akiba's reagent were synthesized using a clean, cheap-step and rapid methodology; their electrochemical and optical behavior are studied.
Journal ArticleDOI

On the Mechanism of Trimethylphosphine-Mediated Reductive Dimerization of Ketones.

TL;DR: In this paper, it was shown that trimethylphosphine-mediated reductive dimerization of properly substituted (e.g., CF3) ketones proceeds via initial formation of an oxaphosphirane intermediate, with the oxygen atom occupying an equatorial position at phosphorus.
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