Journal ArticleDOI
A novel synthetic metal catalytic system for dehydrogenative oxidation based on redox of polyaniline
TLDR
Polyaniline serves as a synthetic metal catalyst with reversible redox under oxygen to induce dehydrogenative and/or decarboxylative oxidation of benzylamines and 2-phenylglycine into the corresponding imines as discussed by the authors.Abstract:
Polyaniline serves as a synthetic metal catalyst with reversible redox under oxygen to induce dehydrogenative and/or decarboxylative oxidation of benzylamines and 2-phenylglycine into the corresponding imines and, in combination with copper(II) chloride or iron(III) chloride, dehydrogenation of cinnamyl alcohol into cinnamaldehyde possibly due to complexationread more
Citations
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Journal ArticleDOI
Progress in preparation, processing and applications of polyaniline
TL;DR: A detailed discussion on the mechanism of electrical conduction in PANI and the factors those influence the conductivity of PANI is also included in this paper, where the problems of effective utilization and the methods adopted to overcome these problems are also provided.
Journal ArticleDOI
Conducting polymers prepared by oxidative polymerization: polyaniline
TL;DR: In this article, the behavior of PANI is shown to be subject to the same basic principles as the polymerization process itself, where the direction and establishment of equilibrium are dependent on the oxidation potentials and concentrations of the reactants.
Journal ArticleDOI
Catalytic Methods for Imine Synthesis
TL;DR: In this paper, a focus review describes different methods that have been reported for the synthesis of imines, starting with metal catalysis, including Ru, Au, V, Cu, Mn, Co and Pd.
Journal ArticleDOI
Redox Behavior of Polyaniline−Transition Metal Complexes in Solution
Journal ArticleDOI
Synthesis, characterisation and properties of polyanilines containing transition metal ions
Chunming Yang,Chunyan Chen +1 more
TL;DR: In this paper, a polyaniline containing transition metal ions was synthesized by oxidizing the complex of aniline with the corresponding metal chloride in solution, and the influence of synthetic conditions such as reaction medium, the molar ratio of reactants, temperature and time on the polymer yield and electrical conductivity was discussed.
References
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Journal ArticleDOI
Polyanilines: a novel class of conducting polymers
TL;DR: The polyanilines are a class of polymers the base form of which has the general formula [graphic omitted] containing y reduced and (1 -y) oxidized repeat groups.
Journal ArticleDOI
VO(OEt)Cl2-induced oxidative deamination
Toshikazu Hirao,Yoshiki Ohshiro +1 more
TL;DR: This paper oxidized 2-phenylglycine derivatives via oxidative deamination and/or decarboxylation giving ethyl benzoate and ethyl phenylglyoxylate.