Journal ArticleDOI
A reversible optical change in the AsSeGe glass
T. Igo,U. Toyoshima +1 more
TLDR
In this article, a novel reversible change in the optical property, transmission and refractive index, due to light irradiation has been found in the As-Se-Ge glass film, which makes the material suitable for erasable (optical) memory medium.Abstract:
A novel reversible change in the optical property, transmission and refractive index, due to light irradiation has been found in the AsSeGe glass film. The change is not related with a usual amorphous-crystalline type transformation; a weak lightr causes an edge shift to longer shorter wavelengths also occur upon heating the sample, which suggests that the shift du to the strong light irradiation is originated from the “heating effect” of light. This was confirmed by an experiment with a sample coated with metal-smoke. The change of optical transmission during the weak light irradiation was measured; it is decreased exponentially with time, and the rate of decrease became larger as the power of irradiationg light increased. Good reversibility of the optical transmission was obtained, which makes the material suitable for erasable (optical) memory medium.read more
Citations
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Journal ArticleDOI
Photostructural transformations in amorphous As2Se3 and As2S3 films
TL;DR: In this article, the influence of illumination and annealing on thin films of amorphous As2Se3 and As2S3 has been studied through their effects on the structure and optical properties.
Journal ArticleDOI
Effect of composition on the structure and electrical properties of As‐Se‐Cu glasses
TL;DR: In this paper, thermally induced changes in the structural properties have been examined using x-ray diffraction, differential thermal analysis, and scanning electron microscopy, and results were discussed on the basis of thermally-induced transformations.
Journal ArticleDOI
Spin‐coated amorphous chalcogenide films
G. C. Chern,I. Lauks +1 more
TL;DR: In this paper, a family of chalcogenides may be deposited in technologically useful thin film form by an inexpensive technique of spin deposition from solution, which has been demonstrated to be potentially useful for high resolution pattern replication in particular for microlithography.
Journal ArticleDOI
A novel inorganic photoresist utilizing Ag photodoping in Se‐Ge glass films
TL;DR: In this paper, the applicability of photodoping with silver, chalcogenide glasses become almost insoluble in alkaline solutions, and they are used as negative-type photoresists.
Journal ArticleDOI
Spin coated amorphous chalcogenide films: Structural characterization
G. C. Chern,I. Lauks +1 more
TL;DR: In this paper, a structural model based on As2S3 clusters surrounded by amine as an amine salt was proposed for thin films that are substantially amorphous arsenic sulfide.
References
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Journal ArticleDOI
Rapid Reversible Light-Induced Crystallization of Amorphous Semiconductors
TL;DR: In this paper, the phase change from amorphous to crystalline state is not only a thermal phenomenon but is directly influenced by the creation of excess electron-hole carriers by either the light, or, for the electrical device, by the electric field.
Journal ArticleDOI
Photodecomposition of Amorphous As2Se3 and As2S3
TL;DR: In this article, As2Se3 and As2S3 are shown to be reversible by thermal cycling to higher temperatures, and a mechanism is proposed to explain the photodecomposition reactions and the thermally induced reversibility in As 2Se3.
Journal ArticleDOI
Optically Induced Reversible Change in Amorphous Semiconductors
Takeo Igo,Yoshio Toyoshima +1 more
Journal ArticleDOI
Structural transformations in the chalcogenide systems GeAsTe and GeAsSe
TL;DR: In this paper, the structural transformations which occur on annealing the thin films of 8 glasses in the two chalcogenide systems GeAs-Te and GeAs-Se have been studied using X-ray analysis, electron microscopy and electrical conductivity.