Journal ArticleDOI
Abraham model correlations for enthalpies of solvation of organic solutes dissolved in methyl acetate and octane
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In this article, the enthalpies of solvation for 63 compounds dissolved in methyl acetate and 67 compounds in octane were assembled from the published literature and it was shown that an Abra...Abstract:
Data have been assembled from the published literature on the enthalpies of solvation for 63 compounds dissolved in methyl acetate and for 67 compounds dissolved in octane. It is shown that an Abra...read more
Citations
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Development of Abraham model expressions for predicting the standard molar enthalpies of vaporization of organic compounds at 298.15 K
TL;DR: In this article, the experimental and back-calculated molar enthalpies of vaporization data at 298.15 K have been compiled from the chemical and engineering literature for 703 liquid organic and organometallic compounds.
Journal ArticleDOI
Abraham model correlations for enthalpies of solvation of organic solutes dissolved in N,N-Dimethylacetamide, 2-butanone and tetrahydrofuran (UPDATED) at 298.15 K
TL;DR: In this paper, the experimental enthalpy of solution data and excess molar entropy of mixing data have been compiled from the chemical and engineering literature for systems containing N,N-dimethylacetamid.
Journal ArticleDOI
Development of Abraham model correlations for enthalpies of solvation of solutes dissolved in N-methylformamide, 2-pyrrolidone and N-methylpyrrolidone
TL;DR: In this paper, the enthalpies of solutes dissolved in three amide solvents were derived for infinite dilution solutes, including 2-propanol, ethylene glycol, 1,3-butanediol and 1,4-butane.
Abraham Model Correlations for Triethylene Glycol Solvent Derived from Infinite Dilution Activity Coefficient, Partition Coefficient and Solubility Data Measured at 298.15 K
O Zha,Melissa Y. Horton,Erin Hart,Sarah Cheeran,Ashley M. Ramirez,Timur I. Magsumov,Xin Tong,Akash Wadawadigi,Maribel Barrera,Michael H. Abraham,William E. Acree,Igor A. Sedov +11 more
TL;DR: In this paper, a gas chromatographic headspace analysis method was used to experimentally determine gas-to-liquid partition coefficients and infinite dilution activity coefficients for 29 liquid organic solutes dissolved in triethylene glycol at 298.15
Journal ArticleDOI
Abraham Solvation Parameter Model: Examination of Possible Intramolecular Hydrogen-Bonding Using Calculated Solute Descriptors
TL;DR: In this article , the Abraham model was used to predict the solubility of 4,5-dihydroxyanthraquinone-2-carboxylic acid.
References
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Journal ArticleDOI
Excess Molar Enthalpies of Binary Mixtures Containing Propylene Carbonate + 23 Alkanoates at 298.15 K
TL;DR: In this paper, the excess molar enthalpies of binary mixtures containing propylene carbonate + 23 alkanoates as a function of the mole fraction of propylene carbate have been determined at 298.15 using a flow microcalorimeter.
Journal ArticleDOI
tert-Butyl chloride as a probe of the solvophobic effects
TL;DR: In this paper, the Gibbs free energy and enthalpy of solvation of tert-butyl chloride in various protic solvents are considered in order to compare the strength of the solvophobic effects from solvent to solvent.
Journal ArticleDOI
Thermodynamic of dissolution and hydrogen bond of the pyrrole, N-methylpyrrole with proton acceptors
TL;DR: In this paper, the enthalpies of dissolution of pyrrole, N-methylpyrrole in proton acceptor solvents and propton acceptors in the medium of Pyrrole and N-methyltropyrrole were measured.
Journal ArticleDOI
Regular ArticleThermodynamic properties of (a methyl ester + an n-alkane). IV. HEm and VEm for {xCH3(CH2)u-1CO2CH3 (u = 1 to 6) + (1-x)CH3(CH2)10CH3}
E. Gonzalez,J. Ortega +1 more
TL;DR: Excess molar enthalpies and excess molar volumes of {a methyl alkanoate (from ethanoate to heptanoate) + dodecane) were measured at the temperature 298.15 K as mentioned in this paper.
Journal ArticleDOI
Thermodynamic properties of organic oxygen compounds excess enthalpies for some ester + hexane or + 1-bromohexane, and bromoester + hexane mixtures
TL;DR: In this article, the authors measured the excess enthalpies of hexane + methyl butyrate and 1-bromohexane and found that the contribution of the specific BrO(carboxylate) interaction to H E seems to be of roughly the same size as the BrO(carbonyl group) one, and in the (bromoester + hexane) mixtures the intramolecular BrO interaction increases as the separation between the bromine atom and the carboxyl