Journal ArticleDOI
Abraham model correlations for enthalpies of solvation of organic solutes dissolved in methyl acetate and octane
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In this article, the enthalpies of solvation for 63 compounds dissolved in methyl acetate and 67 compounds in octane were assembled from the published literature and it was shown that an Abra...Abstract:
Data have been assembled from the published literature on the enthalpies of solvation for 63 compounds dissolved in methyl acetate and for 67 compounds dissolved in octane. It is shown that an Abra...read more
Citations
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Development of Abraham model expressions for predicting the standard molar enthalpies of vaporization of organic compounds at 298.15 K
TL;DR: In this article, the experimental and back-calculated molar enthalpies of vaporization data at 298.15 K have been compiled from the chemical and engineering literature for 703 liquid organic and organometallic compounds.
Journal ArticleDOI
Abraham model correlations for enthalpies of solvation of organic solutes dissolved in N,N-Dimethylacetamide, 2-butanone and tetrahydrofuran (UPDATED) at 298.15 K
TL;DR: In this paper, the experimental enthalpy of solution data and excess molar entropy of mixing data have been compiled from the chemical and engineering literature for systems containing N,N-dimethylacetamid.
Journal ArticleDOI
Development of Abraham model correlations for enthalpies of solvation of solutes dissolved in N-methylformamide, 2-pyrrolidone and N-methylpyrrolidone
TL;DR: In this paper, the enthalpies of solutes dissolved in three amide solvents were derived for infinite dilution solutes, including 2-propanol, ethylene glycol, 1,3-butanediol and 1,4-butane.
Abraham Model Correlations for Triethylene Glycol Solvent Derived from Infinite Dilution Activity Coefficient, Partition Coefficient and Solubility Data Measured at 298.15 K
O Zha,Melissa Y. Horton,Erin Hart,Sarah Cheeran,Ashley M. Ramirez,Timur I. Magsumov,Xin Tong,Akash Wadawadigi,Maribel Barrera,Michael H. Abraham,William E. Acree,Igor A. Sedov +11 more
TL;DR: In this paper, a gas chromatographic headspace analysis method was used to experimentally determine gas-to-liquid partition coefficients and infinite dilution activity coefficients for 29 liquid organic solutes dissolved in triethylene glycol at 298.15
Journal ArticleDOI
Abraham Solvation Parameter Model: Examination of Possible Intramolecular Hydrogen-Bonding Using Calculated Solute Descriptors
TL;DR: In this article , the Abraham model was used to predict the solubility of 4,5-dihydroxyanthraquinone-2-carboxylic acid.
References
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Journal ArticleDOI
Thermodynamic study of (alkyl esters + α,ω-alkyl dihalides) III. HmEandVmE for 20 binary mixtures {xCu − 1H2u − 1CO2C4H9 + (1 − x)α,ω-ClCH2(CH2)v − 2CH2Cl}, where u = 1 to 4, α = 1 and v = ω = 2 to 6
Juan Ortega,A. Navas,J. Plácido +2 more
TL;DR: In this paper, the experimental data of excess molar enthalpies H m E and excess mental volumes V m E are presented for a set of 20 binary mixtures comprised of the first four butyl alkanoates (methanoate to butanoate) and five α,ω-dichloroalkanes (1,2-dicloroethane to 1,6-dici-hexane), obtained at atmospheric pressure and at a temperature of 298.15 K. The results indicate the existence of specific interactions between both kinds
Journal ArticleDOI
Abraham Model Correlations for Triethylene Glycol Solvent Derived from Infinite Dilution Activity Coefficient, Partition Coefficient and Solubility Data Measured at 298.15 K
Igor A. Sedov,Timur I. Magsumov,Erin Hart,Ashley M. Ramirez,Sarah Cheeran,Maribel Barrera,Melissa Y. Horton,Anisha Wadawadigi,Olivia Zha,Xin Tong,William E. Acree,Michael H. Abraham +11 more
TL;DR: In this article, a gas chromatographic headspace analysis method was used to experimentally determine gas-to-liquid partition coefficients and infinite dilution activity coefficients for 29 liquid organic solutes dissolved in triethylene glycol at 298.15
Journal ArticleDOI
Mathematical correlations for describing enthalpies of solvation of organic vapors and gaseous solutes into ionic liquid solvents
TL;DR: In this paper, the enthalpy of solution data for organic solutes dissolved in room temperature ionic liquids (RTILs) was used to derive equation coefficients for 1-hexyloxymethyl-3-methylimidazolium, 1,3-dihexyloxideymethyloxymethylimidsazoliam, 3-methyl-N-butylpyridinium, tris(pentafluoroethyl)trifluoro phosphate, and tetracyanoborate ions.
Journal ArticleDOI
Abraham model correlations for describing the solubilising character of 3-Methoxy-1-butanol and 1-tert-Butoxy-2-propanol solvents
Erin Hart,Megan Jodray,Karen Rodriguez,Maribel Barrera,Ellen Qian,Olivia Zha,Xin Tong,Delani Woods,Yuqing Liu,Grace Lee,William E. Acree,Michael H. Abraham +11 more
TL;DR: In this paper, the experimental data combined with published literature data were used to determine Abraham model correlations for the two alkoxyalcohol solvents, and back-calculated the observed solubilities to within 0.12 log units.
Abraham Model Correlations for Triethylene Glycol Solvent Derived from Infinite Dilution Activity Coefficient, Partition Coefficient and Solubility Data Measured at 298.15 K
O Zha,Melissa Y. Horton,Erin Hart,Sarah Cheeran,Ashley M. Ramirez,Timur I. Magsumov,Xin Tong,Akash Wadawadigi,Maribel Barrera,Michael H. Abraham,William E. Acree,Igor A. Sedov +11 more
TL;DR: In this paper, a gas chromatographic headspace analysis method was used to experimentally determine gas-to-liquid partition coefficients and infinite dilution activity coefficients for 29 liquid organic solutes dissolved in triethylene glycol at 298.15