Journal ArticleDOI
Acid Ionization Constants of Alcohols. II. Acidities of Some Substituted Methanols and Related Compounds1,2
P. Ballinger,F. A. Long +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1960-02-20. It has received 373 citations till now. The article focuses on the topics: Propanol & Methanol.read more
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The kinetics of the spontaneous, proton- and AlIII-catalysed hydrolysis of 1,5-anhydrocellobiitol Models for cellulose depolymerization in paper aging and alkaline pulping, and a benchmark for cellulase efficiency
TL;DR: In this paper, the kinetics of spontaneous, proton and AlIII-catalysed hydrolyses of the C 1 −O4′ bond in 1,5-anhydrocellobiitol have been measured at elevated temperatures (125.0220.0
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17O- and 1H-NMR Studies of the Water Structure in Binary Aqueous Mixtures of Halogenated Organic Compounds
TL;DR: In this paper, the chemical shifts of water (17O- and 1H-NMR) and the spin-lattice relaxation time of water were measured on binary aqueous mixtures of halogenated ethanols, propanol, acetamide and acetone to investigate the effect of their halogen groups on water structure.
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Steric Effects in the Hydrolysis Reactions of N-Acylimidazoles. Effect of Aryl Substitution in the Leaving Group.
TL;DR: The additive nature of the steric rate-accelerating effects in the acyl group and the leaving group indicates an effect on the ease of C-N bond breaking; the hydrolysis reactions very likely proceed in a concerted manner without the formation of a stable tetrahedral intermediate.
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Effect of pH on the photophysical properties of two new carboxylic-substituted iridium(III) complexes
TL;DR: Two cyclometalated iridium(III) complexes have been prepared based on 2-(4-diphenylamino-phenyl)-quinoline and incorporating carboxylic acid ethyl ester substituents at the 4-position of the quinoline ligand, demonstrating that they respond to the pH of the surrounding solvent environment.
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1H nmr study of hydrogen bonding of fluorinated alcohols with ethers
TL;DR: The hydrogen bonding of TFE and HFIP with t-BuOCH 3 (1) and PhOCH3 (2) was studied using 1 H nmr.