Journal ArticleDOI
Acid Ionization Constants of Alcohols. II. Acidities of Some Substituted Methanols and Related Compounds1,2
P. Ballinger,F. A. Long +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1960-02-20. It has received 373 citations till now. The article focuses on the topics: Propanol & Methanol.read more
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Catalytic C–N and C–H Bond Activation: ortho -Allylation of Benzoic Acids with Allyl Amines
TL;DR: A facile insertion of ruthenium into aromatic C-H and allylic C-N bonds are the key steps in a [Ru(p-cymene)Cl2]2-catalyzed ortho-C-H allylation of benzoic acids as mentioned in this paper.
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Glycosylidene Carbenes. Part 6. Synthesis of alkyl and fluoroalkyl glycosides
Karin Briner,Andrea Vasella +1 more
TL;DR: In this paper, the synthesis of glycosides from the diazirine 1 and a range of alcohols under thermal and/or photolytic conditions is described, and yields and diastereoselectivities depend upon the pKHA values of the alcohols, the solvent, and the reaction temperature.
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Hydrogen bonding in ethanol–water and trifluoroethanol–water mixtures studied by NMR and molecular dynamics simulation
Masaru Matsugami,Ryohei Yamamoto,Takashi Kumai,Miho Tanaka,Tatsuya Umecky,Toshiyuki Takamuku +5 more
TL;DR: In this paper, aqueous mixtures of ethanol (EtOH) and 2,2,2-trifluoroethanol (TFE) at 25.0 and −10.1 H NMR measurements were conducted on aqueously mixtures with varying alcohol mole fraction x alc.
Journal ArticleDOI
pKa Values in the Undergraduate Curriculum: What Is the Real pKa of Water?
TL;DR: In this paper, it was shown that the pKa of water must be 15.74 rather than 14.00, and that using the pure liquid standard state (mole fraction = 1) that is quite different from the standard state for acidities determined in dilute solution (molality = 1).
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Microplasma-assisted electrochemical synthesis of Co3O4 nanoparticles in absolute ethanol for energy applications
Chengsheng Ni,Chengsheng Ni,Chengsheng Ni,Darragh Carolan,Conor Rocks,Jianing Hui,Zeguo Fang,Dilli Babu Padmanaban,Jiupai Ni,Deti Xie,Paul Maguire,John T. S. Irvine,Davide Mariotti +12 more
TL;DR: In this article, the microplasma assisted anodization of Co foil with charge balanced by the micro plasma at the flowing-helium/pure-ethanol interface under ambient conditions was demonstrated.