Journal ArticleDOI
An improved kinetics for radical polymerization on the basis that the viscosity of the solvent plays an important role
Kenji Yokota,Masanori Itoh +1 more
Reads0
Chats0
About:
This article is published in Journal of Polymer Science Part B: Polymer Letters.The article was published on 1968-12-01. It has received 29 citations till now. The article focuses on the topics: Autoacceleration & Cobalt-mediated radical polymerization.read more
Citations
More filters
Journal ArticleDOI
Diffusion-Controlled Reactions in Polymer Systems
Itaru Mita,Kazuyuki Horie +1 more
TL;DR: In this article, the process of bimolecular reaction between A and B is given by Eq. (1), taking into account the diffusion step bringing the two reactions in proximity.
Journal ArticleDOI
Bimolecular free-radical termination at low conversion
TL;DR: The elementary reaction steps that make up the kinetic scheme of a freeradical polymerization (i.e., initiation, chain propagation, chain transfer, and bimolecular termination) were recognized in this article.
Journal ArticleDOI
Kinetic Relationships in Radical Polymerization
G. E. Scott,E. Senogles +1 more
TL;DR: The general features of free radical polymerization have been known and understood for at least 30 years as discussed by the authors and the acceptance of a simple chain mechanism is universal and is the basis of the controlled industrial production of most vinyl polymers.
Journal ArticleDOI
Polymerization kinetics of N-vinyl pyrrolidone
E. Senogles,R. Thomas +1 more
TL;DR: In this article, the authors show that the dependence of the termination rate on the viscosity of the polymerization medium has a relatively minor effect on the activation energy of N-vinyl pyrrolidone.
Related Papers (5)
Diffusion-controlled termination during the initial stages of free radical polymerization of methyl methacrylate
A. M. North,G. A. Reed +1 more