Journal ArticleDOI
An Improved Method for the Preparation of Trialkylchlorosilanes from Trialkylsilanes Using Cupric Chloride
TLDR
In this article, a trialkylchlorosilanes can be synthesized in high yield and excellent purity using cupric chloride in acetonitrile by the use of cupric acid.Abstract:
Trialkylchlorosilanes can be synthesized in high yield and excellent purity from corresponding trialkylsilanes by the use of cupric chloride in acetonitrile.read more
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Journal ArticleDOI
Preparation of Functionalized Dialkylzincs via a Boron-Zinc Exchange. Reactivity and Catalytic Asymmetric Addition to Aldehydes.
TL;DR: The hydroboration of olefins with Et(2)BH provides diethyl(alkyl)boranes 2 which readily undergo a boron-zinc exchange with Et (2)Zn providing a range of polyfunctional primary, secondary, and benzylic diorganozincs.
Journal ArticleDOI
Selective synthesis of halosilanes from hydrosilanes and utilization for organic synthesis
Atsutaka Kunai,Joji Ohshita +1 more
TL;DR: In this paper, selective synthesis of halosilanes has been examined and the results showed that the reaction of the corresponding hydrosilanes with Cu(II)-based reagents selectively in high yields can be applied to the synthesis of chlorofluorosilanes and chlorohydrogermanes.
Journal ArticleDOI
Hydrosilane synthesis via catalytic hydrogenolysis of halosilanes using a metal-ligand bifunctional iridium catalyst
TL;DR: In this paper, the in-situ formation of an iridium hydride species as a key intermediate was supported, which could transfer the hyddride to the silicon atom through a metal-ligand bifunctional mechanism.
Journal ArticleDOI
The synthesis of chlorosilanes from alkoxysilanes, silanols, and hydrosilanes with bulky substituents
TL;DR: In this article, it was shown that commercially important trialkylchlorosilanes can readily be synthesized by the reaction of alkoxysilanes, silanols, and hydrosilanes with aqueous concentrated hydorochloric acid.
Journal ArticleDOI
Lewis Base Catalyzed Selective Chlorination of Monosilanes
Alexander G. Sturm,Julia I. Schweizer,Lioba Meyer,Tobias Santowski,Norbert Auner,Max C. Holthausen +5 more
TL;DR: In a combined experimental and computational study, a new mode of Si-H bond activation assisted by Lewis bases such as ethers, amines, phosphines, and chloride ions is established.
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