Journal ArticleDOI
An improved scale of solvent nucleophilicity based on the solvolysis of the S-methyldibenzothiophenium ion
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This article is published in Journal of Organic Chemistry.The article was published on 1991-03-01. It has received 178 citations till now. The article focuses on the topics: Scale (ratio) & Solvolysis.read more
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Concerning the Extents of Nucleophilic Participation in Solvolyses of p-Methoxybenzyl Halides
TL;DR: The solvolyses of p-methoxybenzyl chloride in 39 solvents are well correlated using an extended form of the Grunwald-Winstein equation as discussed by the authors.
Journal ArticleDOI
The importance of the ortho effect in the solvolyses of 2,6-difluorobenzoyl chloride†
Kyoung-Ho Park,Dennis N. Kevill +1 more
TL;DR: The ortho effect of the chloro substituents in 2,6-dichlorobenzoyl chloride sufficiently hindered attack on the acyl carbon such that an ionization mechanism was observed over the full range of solvents studied.
Journal ArticleDOI
A Kinetic Study of the Solvolyses of Methyl and Ethyl Chloroglyoxalates
TL;DR: The correlation parameters obtained from application of the extended Grunwald-Winstein equation are consistent with an addition-elimination (association-dissociation) mechanism over the full range of solvents, with the addition step being rate determining.
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Solvolyses of naphthoyl chlorides. Solvent effect and Grunwald–Winstein correlation analyses with YxBnCl scales†
TL;DR: In this article, the solvolyses of 1-naphthoyl (2), 2-Naphthoysl (3), 4-methyl-1-nophthoyls (4) and 6-methoxy-2-nothoyl(5) chlorides in a variety of solvents were studied, and correlation analyses by using the single and dual-parameter Grunwald-Winstein equations were examined.
Journal ArticleDOI
Rate and Product Studies in the Solvolyses of Two Cyclic Phosphorochloridate Esters
TL;DR: In this paper, an extended Grunwald-Winstein equation treatment was proposed for the solvolyses of 2-chloro-1,3,2-dioxaphospholane-2-oxide.