Journal ArticleDOI
An overview of the chemistry of homo and heteropolynuclear platinum complexes containing bridging acetylide (μ-C≡CR) ligands
TLDR
In this paper, the chemistry of homo and heteropolynuclear platinum complexes containing bridging ligands with special emphasis in synthetic routes, structural aspects and photoluminescence properties is described.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2010-04-01. It has received 99 citations till now. The article focuses on the topics: Acetylide & Platinum.read more
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Vapor‐ and Mechanical‐Grinding‐Triggered Color and Luminescence Switches for Bis(σ‐fluorophenylacetylide) Platinum(II) Complexes
TL;DR: Interestingly, complexes 2-4 exhibit reversible, and naked-eye perceivable, mechanical stimuli-responsive color and luminescence changes, which are most likely correlated to a shorted intermolecular Pt-Pt distance as that revealed in vapochromic species 4·0.5 CH(2)Cl(2), as demonstrated by DTF computational studies.
Journal ArticleDOI
Homoleptic transition metal acetylides
TL;DR: The synthesis, structure, bonding motifs, reaction chemistry, and some potential applications of homoleptic metal alkynides, as well as current trends in this field of chemistry, are reported in this paper.
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Cationic Gold(I) π-Complexes of Terminal Alkynes and Their Conversion to Dinuclear σ,π-Acetylide Complexes
TL;DR: In this paper, a suspension of (IPr)AuCl [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene] and AgSbF6 with terminal arylacetylenes led to the formation of thermally unstable gold π-alkyne complexes in ≥86 ± 5% yield, which were characterized by spectroscopy without isolation.
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Heteropolynuclear cycloplatinated complexes: Structural and photophysical properties
TL;DR: In this paper, a review describes the synthetic routes, structural aspects and photoluminescence properties of heteropolynuclear complexes containing cycloplatinated fragments, as well as their use as molecular sensors.
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Acetylene in Organic Synthesis: Recent Progress and New Uses.
Vladimir V. Voronin,Maria S. Ledovskaya,Alexander S. Bogachenkov,Konstantin S. Rodygin,Valentine P. Ananikov,Valentine P. Ananikov +5 more
TL;DR: The increasing interest in acetylene and its involvement in organic transformations highlights a fascinating renaissance of this simplest alkyne molecule.
References
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Theoretical chemistry of gold.
TL;DR: The theoretical interpretation of the aurophilic attraction is discussed in detail and a large body of appropriate calculations now exist and their main conclusions are summarized.
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Organometallic Compounds for Nonlinear Optics—The Search for En‐light‐enment!
TL;DR: The importance of nonlinear optical phenomena has been known for some time, however, since the mid 1980s, there has been an explosion of interest in the search for and development of non-linear optical materials that possess commercial device applications as discussed by the authors.
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Luminescent polynuclear d10 metal complexes
TL;DR: A number of polynuclear d10 transition metal complexes have been found to exhibit interesting luminescence properties, such as metal-to-ligand charge transfer, ligand to metal charge transfer and metal-centred to ligand-centered as discussed by the authors.
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