Journal ArticleDOI
Anhydrous uranium(+3) chloro-complexes
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TLDR
A series of anhydrous uranium(+3) chloro-complex of the M2UCl5 type [M = NH4, K or Rb], have been isolated and characterized by spectral and magnetic measurements as discussed by the authors.About:
This article is published in Inorganica Chimica Acta.The article was published on 1978-01-01. It has received 11 citations till now. The article focuses on the topics: Anhydrous & Uranium.read more
Citations
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Magnetic Susceptibility of Uranium Complexes
TL;DR: Although variable-temperature analysis is the state-of-the-art method to evaluate the magnetism of uranium complexes, such data are not always easily obtained by all research groups and even the shapes of variable-Temperature plots are notalways consistent for a given ion.
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Tervalent uranium compounds
TL;DR: In this article, the preparation procedures and characterisations of tervalent uranium compounds are presented, focusing on crystallographic and optical properties of the compounds, and extensive physical data, such as crystallographic, thermodynamic, infrared and magnetic data as well as atomic and crystal-field parameters are summarized.
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K2UCl5, Rb2UCl5, UCl3 and a comparison with analogous rare earth chlorides
TL;DR: In this paper, the crystal structure of UCl 3 was refined from single-crystal data and the lattice constants and molar volumes suggest that the uranium chlorides should be compared with the analogous cerium compounds.
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Synthesis and characterization of potassium, rubidium and ammonium tetrachlorouranate(III) tetrahydrates
TL;DR: In this paper, a series of hydrated uranium(III) complex chlorides of the general formula M I UCl 4 · 4H 2 O (M I ≡ K,Rb or NH 4 ) were isolated and characterized.
References
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Journal ArticleDOI
Absorption Spectra of Red Uranium(III)Chloro Complexes in Strong Hydrochloric Acid.
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Magnetic properties of the trichlorides, tribromides, and triiodides of U(III), Np(III), and Pu(III)
TL;DR: Magnetic susceptibilities of uranium, plutonium, and neptunium trichlorides, tribomides, and triiodides were measured from 27°K to as high as 240°K with a vibrating sample magnetometer at applied fields up to 12 kOe as discussed by the authors.
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Magnetic properties of trivalent actinides in the octahedral compounds Cs2NaMCl6
TL;DR: The magnetic susceptibilities of actinide ions in an octahedral environment were measured from 3 to about 50°K with a vibrating sample magnetometer as mentioned in this paper, and the Curie-Weiss behavior was found for the uranium, neptunium, and plutonium compounds.
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A Spectrophotometric Study of Trivalent Actinide Complexes in Solution.: I. Uranium
M. Shiloh,Y. Marcus +1 more
TL;DR: In this article, the stability of contact-ion-pair of uranium (III) was investigated in sulfuric acid and lithium chloride and bromide solutions, and β 1 = (1.3 ± 0.3)10−3 M−1 for chloride and β 2 = ( 1.1 − 0.2 )10−4 M−2 for bromides.
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Uranium(iii) and uranium(iv) formates and their magnetic properties.
TL;DR: Two new uranium compounds have been prepared, U(HCOO) 3 and U(HOO) 4, and the magnetic susceptibilities of these compounds were measured over the temperature range 82-300°K as mentioned in this paper.