Journal ArticleDOI
Catalytic asymmetric epoxidations with chiral iron porphyrins
John T. Groves,Richard S. Myers +1 more
TLDR
Epoxydation asymetrique d'olefines prochirales par des porphyrines de fer chirales and par des composes iodosyles.Abstract:
Epoxydation asymetrique d'olefines prochirales par des porphyrines de fer chirales et par des composes iodosylesread more
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Journal ArticleDOI
Asymmetric catalysis of epoxide ring-opening reactions.
TL;DR: A search for a practical method for the kinetic resolution reaction led to the discovery of highly enantiomer-selective hydrolytic ring-opening using the corresponding (salen)Co(III) catalyst, which displays extraordinary substrate generality, and allows practical access to enantiopure terminal epoxides on both laboratory and industrial scales.
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Artificial Molecular Rotors
Journal ArticleDOI
1,1‘-Binaphthyl Dimers, Oligomers, and Polymers: Molecular Recognition, Asymmetric Catalysis, and New Materials†
Journal ArticleDOI
Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts
TL;DR: In this paper, the authors dealt with enantioselective one oxygen atom transfer reactions (epoxidation, oxidation of enolates, and oxidation of sulphide to sulphoxides) catlaysed by optically active (salen)manganese(III)complexes.
Journal ArticleDOI
Advances in Homogeneous and Heterogeneous Catalytic Asymmetric Epoxidation
TL;DR: This paper presents results of aalysis experiment conducted at the Dalian Institute of Chemical Physics of Chinese Academy of Sciences (Dalian 116023) and Jingmen Technological College (Jingmen 448000) using gas chromatography for the recovery of Na6(CO3) from Na2SO4.