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Chemical and physical effects of processing fats and oils

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TLDR
Soybean oil is processed for a variety of food uses, such as salad/cooking oil, margarine and shortening as discussed by the authors, and is composed mainly of triglycerides but also contains measurable amounts of minor constituents that may have beneficial or detrimental effects on oil characteristics.
Abstract
Soybean oil is processed for a variety of food uses, salad/cooking oil, margarine and shortening. Crude soybean oil is composed mainly of triglycerides but also contains measurable amounts of minor constituents that may have beneficial or detrimental effects on oil characteristics. The nature of these minor constituents, the role they play in oil stability or deterioration and their fate during processing are subjects of this review. Iodine value, fatty acid composition, solid fat index and congeal point are chemical and physical characteristics of oil that are affected by the hydrogenation process. Techniques and effects of degumming, alkali refining, bleaching, hydrogenation, winterization and deodorization are discussed. Utilization or disposal of by-products or wastes from each processing step is reviewed.

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Citations
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Effects of processing steps on the contents of minor compounds and oxidation of soybean oil

TL;DR: In this paper, the processes of degumming, alkali refining, bleaching and deodorization removed 99.8% phospholipids, 90.7% iron, 100% chlorophyll, 97.3% free fatty acids and 31.8 % tocopherols from crude soybean oil.
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Influence of the Vegetable Oil Refining Process on Free and Esterified Sterols

TL;DR: The influence of refining process on the distribution of free and esterified phytosterols in corn, palm, and soybean oil was studied in this paper, where a significant reduction in the content of total sterols during neutralization was observed, which was attributed to a reduction in free sterol fraction.
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Effect of altered fatty acid composition on soybean oil stability

TL;DR: In this article, a low-linolenic acid soybena oil was extracted from the seeds of three such genotypes were processed in laboratory simulations of commercial procedures to finished deodorized oils.
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The effect of sulphuric acid activation on the crystallinity, surface area, porosity, surface acidity, and bleaching power of a bentonite

TL;DR: In this article, the Hancili (Keskin, Ankara, Turkey) bentonite was activated with H2SO4 by dry method at 97°C for 6h to obtain optimum parameters for imparting a maximum bleaching power towards soybean oil.
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Variation in fatty acid composition of the different acyl lipids in seed oils from fourSesamum species

TL;DR: Based on the fatty acid composition of the total lipids and of the different acyl lipid classes, it seems that S. radiatum andS.
References
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Journal ArticleDOI

Sterol composition of 19 vegetable oils

TL;DR: The unsaponifiables from 19 vegetable oils were divided into a sterol and three other fractions by thin-layer chromatography, and campesterol, stigmasterol and β-sitosterol were present in all oils, and a minor amount of cholesterol in majority of the oils.
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Linolenic acid artifacts from the deodorization of oils

TL;DR: This article showed that linolenic acid in deodorized vegetable oils is accompanied by two major artifacts identified as cis-9,cis-12,trans-15 and trans-9-cis 12, trans-15 isomers, which were not present in unrefined oils or bleached oils but could be induced by deodorization in the laboratory.
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Quantitative changes in some unsaponifiable components of soya bean oil due to refining

TL;DR: The effects were studied of the processes of degumming, neutralisation, bleaching and deodorisation on the content and composition of the various fractions of unsaponifiables in soya bean oil.
Journal ArticleDOI

Refining and degumming systems for edible fats and oils

TL;DR: In this paper, the authors discuss the theoretical and practical factors for degumming and refining crude edible oils with particular reference to processes, flow charts, control systems and analytical testing requirements.
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