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Chloridobis(ethyl-enediamine-κN,N')(n-pentyl-amine-κN)cobalt(III) dichloride monhydrate.

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TLDR
The title complex, [CoCl(C5H13N)(C2H8N2)2]Cl2·H2O, comprises one chloridobis(ethylenediamine)(n-pentylamine)cobalt(III) cation, two chloride counter-anions and a water molecule.
Abstract
The title complex, [CoCl(C5H13N)(C2H8N2)2]Cl2·H2O, comprises one chloridobis(ethyl­enediamine)(n-pentyl­amine)cobalt(III) cation, two chloride counter-anions and a water mol­ecule. The CoIII atom of the complex is hexa­coordinated by five N and one Cl atoms. The five N atoms are from two chelating ethyl­enediamine and one n-pentyl­amine ligands. Neighbouring cations and anions are connected by N—H⋯Cl and N—H⋯O hydrogen bonds to each other and also to the water mol­ecule.

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Citations
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Synthesis and spectroscopic characterization of cobalt(III)-alkyl amine complexes showing surface affinity: Single crystal X-ray structure determinations

TL;DR: In this paper, structural integrated cobalt(III) complexes showing interesting surface affinity in the interfacial electron transfer reactions were synthesized by incorporating alkyl amines into the coordination sphere of cis-[CoIII(en)2(RNH2)Cl]Cl2.
Journal ArticleDOI

Chloridobis(ethane-1,2-diamine)(4-methyl-aniline)cobalt(III) dichloride monohydrate.

TL;DR: In the title compound, [CoCl(C2H8N2)2(C7H9N)]Cl2·H2O, the CoIII ion has a distorted octahedral coordination environment and is surrounded by four N atoms in an equatorial plane, with the other N and Cl atoms occupying the axial positions.
Journal ArticleDOI

Excited nanoscale-TiO2 induced interfacial electron transfer reaction of redox active cobalt(III)–alkyl amine complex and the solid surface

TL;DR: In this paper, the role of RNH 2 moiety in modifying compact structure of nano-TiO 2 −cobalt(III)-RNH 2 compound, redox power of semiconductor surface, and the proposed mechanism of interfacial electron transfer reactions were investigated.
Journal ArticleDOI

Electron-rich ligand modified, ferromagnetic luminescent cis-[CoIII(en)2(RNH2)Cl]Cl2 complexes and their electrochemical reduction behavior

TL;DR: In this article, the effect of RNH 2 on luminescence, electrochemical and magnetic properties of cis-[Co III (en) 2 ( R NH 2 )Cl 2 has been rationalized.
Journal ArticleDOI

cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate

TL;DR: In the title compound, [CoCl(CH5N)(C3H10N2)2]Cl2·H2O, the CoIII ion has an octahedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions.
References
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A short history of SHELX

TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
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ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI)

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An empirical correction for absorption anisotropy

TL;DR: A least-squares procedure is described for modeling an empirical transmission surface as sampled by multiple symmetry-equivalent and/or azimuth rotation-equ equivalent intensity measurements.
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Completion and refinement of crystal structures with SIR92

TL;DR: In this paper, an automatic procedure for recovering a complete crystal structure after a direct phasing process is described, which consists mainly of a Fourier recycling method that can be implemented in any direct-methods package.
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