Chloridobis(ethyl-enediamine-κN,N')(n-pentyl-amine-κN)cobalt(III) dichloride monhydrate.
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TLDR
The title complex, [CoCl(C5H13N)(C2H8N2)2]Cl2·H2O, comprises one chloridobis(ethylenediamine)(n-pentylamine)cobalt(III) cation, two chloride counter-anions and a water molecule.Abstract:
The title complex, [CoCl(C5H13N)(C2H8N2)2]Cl2·H2O, comprises one chloridobis(ethylenediamine)(n-pentylamine)cobalt(III) cation, two chloride counter-anions and a water molecule. The CoIII atom of the complex is hexacoordinated by five N and one Cl atoms. The five N atoms are from two chelating ethylenediamine and one n-pentylamine ligands. Neighbouring cations and anions are connected by N—H⋯Cl and N—H⋯O hydrogen bonds to each other and also to the water molecule.read more
Citations
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Synthesis and spectroscopic characterization of cobalt(III)-alkyl amine complexes showing surface affinity: Single crystal X-ray structure determinations
TL;DR: In this paper, structural integrated cobalt(III) complexes showing interesting surface affinity in the interfacial electron transfer reactions were synthesized by incorporating alkyl amines into the coordination sphere of cis-[CoIII(en)2(RNH2)Cl]Cl2.
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Chloridobis(ethane-1,2-diamine)(4-methyl-aniline)cobalt(III) dichloride monohydrate.
TL;DR: In the title compound, [CoCl(C2H8N2)2(C7H9N)]Cl2·H2O, the CoIII ion has a distorted octahedral coordination environment and is surrounded by four N atoms in an equatorial plane, with the other N and Cl atoms occupying the axial positions.
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Excited nanoscale-TiO2 induced interfacial electron transfer reaction of redox active cobalt(III)–alkyl amine complex and the solid surface
TL;DR: In this paper, the role of RNH 2 moiety in modifying compact structure of nano-TiO 2 −cobalt(III)-RNH 2 compound, redox power of semiconductor surface, and the proposed mechanism of interfacial electron transfer reactions were investigated.
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Electron-rich ligand modified, ferromagnetic luminescent cis-[CoIII(en)2(RNH2)Cl]Cl2 complexes and their electrochemical reduction behavior
TL;DR: In this article, the effect of RNH 2 on luminescence, electrochemical and magnetic properties of cis-[Co III (en) 2 ( R NH 2 )Cl 2 has been rationalized.
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cis-Chlorido(methylamine)bis(propane-1,3-diamine)cobalt(III) dichloride monohydrate
V. Maheshwaran,Munisamy Manjunathan,Krishnamoorthy Anbalagan,Viswanathan Thiruselvam,M. N. Ponnuswamy +4 more
TL;DR: In the title compound, [CoCl(CH5N)(C3H10N2)2]Cl2·H2O, the CoIII ion has an octahedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions.
References
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