Crystal structure of (η6-1-isopropyl-4-methyl benzene)-(N-(2,5-dichlorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) perchlorate, C22H22Cl4N2O4Ru
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In this article, the authors proposed a monoclinear monoclonality approach to monocline monophysics and showed that it can be achieved by using monocular microscopy.Abstract:
Abstract C22H22Cl4N2O4Ru, monoclinic, P21/c (no. 14), a = 15.0181(3) Å, b = 10.3983(2) Å, c = 16.6496(3) Å, β = 112.459(1)°, V = 2402.84(8) Å3, Z = 4, Rgt(F) = 0.0180, wRref(F2) = 0.0474, T = 173(2) K.read more
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Comparative structural description of five arene ruthenium(II) complexes of N,N-bidentate Schiff base ligands to related complexes from literature
TL;DR: A series of new half-sandwich Ru(II) complex salts of the general formula (η6-arene)RuX(L)]PF6 were synthesized by reacting the ruthenium arene precursors with N,N-bidentate ligands in a 1:2 ratio.
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Crystal structure of chlorido-(η6-toluene)(2,2′-bipyridine-κ2N,N′)ruthenium(II) hexafluorophosphate, C17H16ClN2RuPF6
TL;DR: In this article , a monoclinic approach was proposed for monoclonal cancer detection using monocular microscopy, and the results showed that β = 109.2690°, V = 1864.2(2) Å3, Z = 4, R gt (F) = 0.0309, wR ref (F2)= 0.0697, T = 173 K.
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Chlorido-(η6-p-cymene)-(bis(pyrazol-1-yl)methane-κ2N,N′)Osmium(II) Tetrafluoroborate, C17H22BClF4N4Os
TL;DR: The powder of the arene osmium(II) complex, [Os(II)(dpzm)(η6p-cym)Cl]BF4, with a formula of C17H22BClF4N4Os (referred to herein as 1) was isolated from the reaction of [(η 6-p-cyclm)Os(μ-Cl)(Cl)]2 with dpzm dissolved in acetonitrile and under a flow of nitrogen gas as mentioned in this paper .
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Crystal structure of chlorido-(η 6-toluene)(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)ruthenium(II) hexafluoridophosphate(V) ─ acetone (1/1) C22H26ClN2ORuPF6
TL;DR: In this paper , the triclinic trichloric triclastic trichlastic model was used to describe the trichlinic structure of tricline.
-cymene)-(bis(pyrazol-1-yl)methane-κ 2 N , N (cid:48) )Osmium(II) Tetrafluoroborate, C 17 H 22 BClF 4 N 4 Os
TL;DR: In this article , the powder of the arene osmium(II) complex, with a formula of C 17 H 22 BClF 4 N 4 Os (referred to herein as 1 ) was isolated from the reaction of [( η 6 - p -cym)Os( µ -Cl)(Cl)] 2 with dpzm dissolved in acetonitrile and under a flow of nitrogen gas.
References
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A short history of SHELX
TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
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WinGX and ORTEP for Windows: an update
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Functionalised η6-arene ruthenium complexes
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Half-sandwich arene ruthenium complexes: synthetic strategies and relevance in catalysis
TL;DR: Half-sandwich arene ruthenium complexes exhibit versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations and their applications in catalytic organic transformations are discussed.
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Discovery and Investigation of Anticancer Ruthenium–Arene Schiff-Base Complexes via Water-Promoted Combinatorial Three-Component Assembly
Mun Juinn Chow,Cynthia Licona,Cynthia Licona,Daniel Yuan Qiang Wong,Giorgia Pastorin,Christian Gaiddon,Christian Gaiddon,Wee Han Ang +7 more
TL;DR: The optimization and validation of a new combinatorial, metal-based, three-component assembly reaction for the synthesis of a library of 442 Ru-arene Schiff-base (RAS) complexes, which suggests that 4 and possibly the other lead compounds may act independently of the p53 tumor suppressor gene frequently mutated in cancer.