Journal ArticleDOI
Crystal structure of tricyclohexyltin chloride
TLDR
The structure of tricyclohexyltin chloride has been determined by X-ray analysis as mentioned in this paper, which is consistent with the tetrahedral geometry when distortions are taken into account in the treatment of the point charge model.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1979-10-16. It has received 28 citations till now. The article focuses on the topics: Tetrahedral molecular geometry & Quadrupole splitting.read more
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Book ChapterDOI
Structure and Bonding in Tin Compounds
TL;DR: In this paper, the point charge model for quadrupole splitting and the interpretation of data for transition-metal complexes involving Sn-donor ligands are discussed. But the basic principles of interpretation have been established for some time, and major reviews appeared about ten years ago.
Journal ArticleDOI
X-ray and mössbauer studies of tricyclohexyltin(IV) halides. The crystal structures of (cyclo-C6H11)3SnX (X = F, Br and I)
TL;DR: The structures of tricyclohexyltin fluoride (I), bromide (II), and iodide (III) have been determined by X-ray analysis as mentioned in this paper.
Journal ArticleDOI
Organometallic complexes with biological molecules II. Synthesis, solid‐state characterization and in vivo Cytotoxicity of Diorganotin(IV)chloro and Triorganotin(IV)chloro derivatives of Penicillin G
Francesco Maggio,A. Pellerito,Lorenzo Pellerito,Stefania Grimaudo,C. Mansueto,Roberto Vitturi +5 more
TL;DR: The rationalization of the Mossbauer parameter nuclear quadrupole splitting, ΔE (mm s−1), according to the point-charge model formalism, supported such an hypothesis, and the biological activity of diorganotin(IV)chloropenG and triorganotin( IV)-chloropenGNa derivatives has been tested using Ciona intestinalis fertilized eggs at different stages of development.
Journal ArticleDOI
Tin organometallic compounds: classification and analysis of crystallographic and structural data: part 1. monomeric derivatives
Clive E. Holloway,Milan Melnik +1 more
Abstract: This review collects together the crystallographic data of organotin compounds by type and complexity, with a view to identifying correlations between properties and structure. Because of the large number of such structures, this first part deals only with monomeric derivatives, which covers almost one thousand structural determinations. While coordination numbers range from two to eight, for two and three coordination only tin(ll) compounds are found. All others are tin(IV) except for four examples with coordination number four, and ten with coordination number five. The predominant geometries are tetrahedral, trigonal bipyramidal, pseudo-octahedral and pentagonal bipyramidal. The most common C-donor ligands are methyl and phenyl. There are examples of distortion and structural isomerism. CONTENTS 0. ABBREVIATIONS
Journal ArticleDOI
Aspects of pentacoordinated tin compounds
A. Tzschach,Klaus Jurkschat +1 more
TL;DR: In this article, it was shown that only three of the five theoretically possible pentacoordinated structures having at least one symmetry element can be adopted, i.e., the trigonal bipyramid, the rectangular pyramid and the monocapped tetrahedron.
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