Journal ArticleDOI
[CTP]: A new structural family of near-zero expansion ceramics
TLDR
In this paper, the authors report the discovery of a new structural family for use in ultra-low "α" ceramics, Ca 0.5 Ti 2 P 3 O 12 abbreviated [CTP] after which the structural family is named.About:
This article is published in Materials Research Bulletin.The article was published on 1984-04-01. It has received 161 citations till now.read more
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Journal ArticleDOI
Negative thermal expansion
TL;DR: In this article, the underlying thermodynamics, emphasizing the roles of thermal stress and elasticity, are reviewed, and vibrational and non-vibrational mechanisms operating on the atomic scale that are responsible for negative expansion in a wide range of materials.
Journal ArticleDOI
A wide-ranging review on Nasicon type materials
Navulla Anantharamulu,Navulla Anantharamulu,K. Koteswara Rao,G. Rambabu,B. Vijaya Kumar,V. Radha,Muga Vithal +6 more
TL;DR: A wide range of materials based on crystalline and glassy Nasicon compositions are considered in this paper, and their structure, compositional diversity, evolution, and applications are reviewed.
Journal ArticleDOI
On the structure of Li3Ti2(PO4)3
TL;DR: In this article, the structure of the Nasicon-type phase Li3Ti2(PO4)3 was characterized using neutron diffraction for the long range structure and 7Li NMR for more local information.
Journal ArticleDOI
Ionic conduction in the solid state
TL;DR: A survey of ionic conductivity in NASICONs can be found in this article, where the authors discuss the recent results from atomistic computer simulations on the dependence of conductivity as a function of composition, temperature, phase change and cation among others.
Journal ArticleDOI
Crystal chemistry of the NaZr2(PO4)3, NZP or CTP, structure family
J. Alamo,Rustum Roy +1 more
TL;DR: In this paper, the NaZr2(PO4)3 type structure (abbreviated as NZP or CTP, CaTi4(PO 4)6), has emerged as a new family, which has extraordinary technological utility in three fields: fast ion conductors, radwaste solidification and zero expansion ceramics.
References
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Journal ArticleDOI
Fast Na+-ion transport in skeleton structures
TL;DR: In this article, the Im3 phase of high pressure KSbO3, the defect-pyrochlore structure illustrated by RbMgAlF6, and the carnegieite structure of high-temperature NaAlSiO4 were investigated.
Journal ArticleDOI
Crystal structures and crystal chemistry in the system Na1+xZr2SixP3−xO12☆
TL;DR: In this paper, the skeleton structures for fast alkali-ion transport were identified and analyzed using single-crystal x-ray analysis, and the system Na1+xZr2Si2PO12 was prepared, analyzed structurally and ion exchanged reversibly with Li+, Ag+, and K+ ions.
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The Crystal Structure of NaM2IV(PO4)3; MeIV = Ge, Ti, Zr.
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Aids in Hydrothermal Experimentation: II, Methods of Making Mixtures for Both “Dry” and “Wet” Phase Equilibrium Studies
TL;DR: In this article, various methods for the preparation of mixtures for phase equilibrium studies are described, and special attention has been paid to compositions which cannot be preserved in a glass structure.