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Journal ArticleDOI

Density, thermal expansivity, and compressibility of liquid water from 0° to 150°C: correlations and tables for atmospheric pressure and saturation reviewed and expressed on 1968 temperature scale.

George S. Kell
- 01 Jan 1975 - 
- Vol. 20, Iss: 1, pp 97-105
TLDR
In this article, a review is given of the temperature dependence of the density of liquid water from 40" to 150°C and the error in the calculated compressibilities is estimated as 03 X lO-'bar-' at 4'C and as7 X 100°C at 4''C.
Abstract
A review is given of the temperature dependence of the density of liquid water from 40" to 150°C The inclusion of new literature data indicates that most previous correlations have been 10 ppm low at 70-80°C An expression is derived, Equation 16, expressed on the IPTS-68 and valid from 0" to 150"C, that is in improved agreement with most data sets Recent literature values of the velocity of sound permit the calculation of more reliable isothermal compressibilities The errors of these compressibilities;, from velocity of sound, density, thermal expansivity, and specific heat, are examined, and the error in the calculated compressibilities is estimated as 03 X lO-'bar-' at 4'C and as7 X 100°C This paper supersedes two papers previously given by the same author The revision of correlating and interpolating equations, and of estimated best values and their errors, must be repeated whenever standards are modified or a significant addition is made to the pool of experimental data At atmospheric pressure (=101325 bar), the volume or density, the thermal expansivity, and the compressibility are among the properties of liquid water that are known with sufficient precision for the introduction of the 1968 lnternational Practical Temperature Scale (72) to make it

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Journal ArticleDOI

A five-site model for liquid water and the reproduction of the density anomaly by rigid, nonpolarizable potential functions

TL;DR: In this paper, the authors used Monte Carlo statistical mechanics to reproduce the shape of the liquid density curve as a function of temperature and applied it to the NPT ensemble at 1 atm.
Journal ArticleDOI

Development of an improved four-site water model for biomolecular simulations: TIP4P-Ew

TL;DR: A re-parameterization of the standard TIP4P water model for use with Ewald techniques is introduced, providing an overall global improvement in water properties relative to several popular nonpolarizable and polarizable water potentials.
ReportDOI

Handbook of methods for the analysis of the various parameters of the carbon dioxide system in sea water. Version 2

TL;DR: In this paper, the authors present a survey of the state-of-the-art for ship-board measurements of oceanic carbon dioxide in sea water, together with standard operating procedures and a quality control plan for measurements made as part of this survey.
Journal ArticleDOI

Supercooled and glassy water

TL;DR: The authors summarizes the known experimental facts and reviews critically theoretical and computational work aimed at interpreting the observations and providing a unified viewpoint on cold, non-crystalline, metastable states of water.
Journal ArticleDOI

Temperature and size dependence for Monte Carlo simulations of TIP4P water

TL;DR: In this article, a series of Monte Carlo simulations has been carried out to characterize the temperature and size dependence of the results for liquid water using the TIP4P potential function.
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