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Determination of lead and cadmium in biological samples by potentiometric stripping analysis

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TLDR
In this paper, the determination of lead and cadmium in biological materials was carried out by potentiometric stripping analysis, where the supporting electrolyte was a mixture of NaCl and HCl.
Abstract
The determination of lead and cadmium in biological materials was carried out by potentiometric stripping analysis. Supporting electrolyte was a mixture of NaCl and HCl. In the presence of 4% lumatom in methanol, oxidation potentials of −0.46 V for Pb and −0.68 V for Cd were found (vs. SCE). The method was applied to different standard reference materials (leaves, needles, hair) and was also compared with the differential pulse anodic stripping technique. The latter presented considerable difficulties, in particular by the interference of oxygen.

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Journal ArticleDOI

Potentiometric Stripping Analysis: A Review

TL;DR: A bibliographic review on potentiometric stripping analysis (PSA) is performed in this paper, where theoretical, instrumental, analytical applications and advantages, and inferences of other modern PSA techniques are considered.
Journal ArticleDOI

Present potential of electrochemical methods for metal determinations in reference materials

TL;DR: In this article, the potential to determine trace metals (Zn, Cd, Pb, Cu, Ni, Co, Al, Tl, Cr, Fe) by anodic or cathodic stripping voltammetry in the square wave (SWV) and differential pulse modes (DPASV) is described.
Journal ArticleDOI

Direct inverse voltammetric determination of Pb, Cu and Cd in some edible oils after solubilization

TL;DR: In this article, a flow through cell with a mercury film electrode was used for the inverse voltammetric determination of Cu and Pb in some edible oils after solubilization.
Journal ArticleDOI

Computerized potentiometric stripping analysis using asyst software: Application to lead determination in wines and vinegars†

TL;DR: A computerized system for potentiometric stripping analysis made of commercially available components with corresponding software is described in this paper, where application to the determination of lead in wines and vinegars is also reported.
Journal ArticleDOI

Inverse-voltammetric determination of cadmium, lead and copper in animal samples after solubilization

TL;DR: In this article, the conditions for the determination of cadmium, lead, and copper in various biological samples after solubilization with Texapon are described, and the results of this procedure are compared with those obtained with conventional high- and low-pressure wet digestions.
References
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Journal ArticleDOI

Potentiometric stripping analysis. A review

Daniel Jagner
- 01 Jan 1982 - 
Journal ArticleDOI

Determination of lead, copper, and cadmium in wine and beer by potentiometric stripping analysis

TL;DR: In this article, an instrumentation and analytical procedures for the direct determination of lead, copper and cadmium in alcoholic beverages in the concentration range 1-100 μg 1-1 are outlined.
Journal ArticleDOI

Determination of zinc, cadmium, lead and copper in sea water by means of computerized potentiometric stripping analysis

TL;DR: Water samples from the Arctic Sea were analyzed by the potentiometric stripping technique as mentioned in this paper, and the results showed that zinc(II), cadmium(II) and lead (II) concentrations in eight different samples were 2.5, 0.16 and 0.04 nM, respectively.
Journal ArticleDOI

Computerized potentiometric stripping analysis for the determination of cadmium, lead, copper and zinc in biological materials

TL;DR: In this paper, two types of tinned mussels and a bovine liver reference sample have been analyzed for Zn, Cd, Pb and Cu by means of computerized potentiometric stripping analysis and atomic absorption spectrometry.
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