Journal ArticleDOI
Effect of energetic materials on the thermal stability of polymers
Reads0
Chats0
TLDR
In this article, the effect of ammonium perchlorate, ammonium persulfate, cyclotetramethylenetetranitramine, triaminoguanidine nitrate, plastisol nitrocellulose, and a nitrate lacquer at the 5% level was investigated by isothermal and dynamic thermogravimetry in a nitrogen and air atmosphere.About:
This article is published in Thermochimica Acta.The article was published on 1983-04-16. It has received 5 citations till now. The article focuses on the topics: Thermogravimetry & Thermal stability.read more
Citations
More filters
Journal ArticleDOI
Thermal characteristics of GAP, GAP/BDNPA/BDNPF and PEG/BDNPA/BDNPF and the energetic composites thereof
TL;DR: In this article, the thermal behavior of the energetic binder systems GAP, GAP/BDNPA/BDNPF and PEG were investigated by thermogravimetry.
Journal ArticleDOI
Combustion and catalytic performance of metal-free heat-resistant energetic polymeric materials
TL;DR: In this paper, four N-di/trinitrobenzene based heat-resistance energetic polymeric materials were synthesized via two facile approaches and fully characterized using FTIR, NMR, SEM and XRD.
Journal ArticleDOI
Thermal behaviour and compatibility of polyurethane PCL/BDNPA/F and PCL/TMETN blends
TL;DR: The thermal behavior of two sets of polymer blends, mixtures of poly(caprolactone) (PCL) of molecular weights 2000, 6000 and 10000 with eutectic mixtures with bis(2,2-dinitropropyl) acetal (BDNPA), and of PCL with nitrate-plasticizer trimethylolethane trinitrate (TMETN), were examined by thermogravimetry (TG), derivative thermograves (DTG) and differential scanning calorimetry(DSC) RE
Journal ArticleDOI
Evaluation method for the effect of salts on the elimination of secondary flames of energetic materials by differential scanning calorimetry
TL;DR: In this article, the effect of LiF, KC1 and KHCO 3 on the thermal decomposition of HTPB/RDX energetic composite was studied and a method suitable for the evaluation of the inhibitory behavior of alkali metal salts on the secondary flame combustion reaction of the composite was developed, utilizing thermogravimetry-derivative thermografi-metry differential scanning calorimetry (DSC) and a multi-channel recorder.
Journal ArticleDOI
Thermal characteristics of poly-BAMO and poly-BAMO/BDNPA/BDNPF blends
TL;DR: In this paper, the thermal decomposition reaction of a poly-BAMO/BDNPA/F blend at a dynamic heating rate is indicated by three major stages of weight loss in the TG-DTG traces.
References
More filters
Journal ArticleDOI
Estimating isothermal life from thermogravimetric data
TL;DR: In this paper, the authors presented a method for estimating equivalent isothermal life from thermogravimetric data and for estimating the apparent activation energy for volatilization even though the nature of the kinetic process is unknown.
Journal ArticleDOI
Degradation of Polymers
Leo A. Wall,Joseph H. Flynn +1 more
TL;DR: In this paper, a review of recent literature pertaining to both the theoretical aspects and experimental results of the degradation of polymers by heat and radiation is reviewed and critically evaluated, and the thermodynamics and energetics of these polymers are also reviewed.
Journal ArticleDOI
Pyrolysis of polyacrylonitrile and related polymers—IV. Thermal analysis of polyacrylonitrile in the presence of additives
N. Grassie,R. McGuchan +1 more
TL;DR: The thermal behavior of polyacrylonitrile was studied by DTA and TG as mentioned in this paper, and it was shown that PAN exhibits a very sharp exotherm at about 260°, caused by the oligomerization of nitrile groups.
Journal ArticleDOI
Unsolved Problems in Polymer Degradation
TL;DR: The degradation of commercial rubbers and plastics is exceedingly complex, since processing and small quantities of impurities or additives can interact and totally change the behavior of the substrate as mentioned in this paper. But it is not sufficient to examine the degradation of pure materials.
Journal ArticleDOI
The action of tridecyl phosphite in the stabilization of poly(vinyl chloride) with metal soaps
F. J. Hybart,G. N. Rowley +1 more
TL;DR: In this article, the effect of tridecyl phosphite on the stabilization of the thermal degradation of poly(vinyl chloride) under nitrogen by cadmium and zinc stearates has been studied.