Journal ArticleDOI
Effect of fluorination of the meso-phenyl groups on selective tetraphenylporphyrinatoiron(III)-catalysed reactions of propane with molecular oxygen
Paul E. Ellis,James E. Lyons +1 more
TLDR
A series of tetrakis(pentafluorophenyl)iron(III) complexes are active catalysts for the selective air oxidation of propane to isopropyl alcohol and acetone under mild conditions, and provide hundreds of catalytic turnovers in the absence of any added co-reductants as mentioned in this paper.Abstract:
A series of tetrakis(pentafluorophenyl)iron(III) complexes are active catalysts for the selective air oxidation of propane to isopropyl alcohol and acetone under mild conditions, and provide hundreds of catalytic turnovers in the absence of any added co-reductants.read more
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Journal ArticleDOI
Catalytic Oxidation of Alkylbenzenes with Molecular Oxygen under Normal Pressure and Temperature by N-Hydroxyphthalimide Combined with Co(OAc)2
TL;DR: In this paper, a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co(OAc)2 was developed to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature.
Journal ArticleDOI
Metalloporphyrins as models for the cytochromes p-450
Maxwell J. Gunter,Peter Turner +1 more
TL;DR: In this article, high-valent complexes formed in manganese porphyrin-catalysed hydrocarbon oxidations and oxidation mechanisms suggested by the iron and P-450 model systems were characterized.
Journal ArticleDOI
Selective low temperature hydroxylation of isobutane by molecular oxygen catalyzed by an iron perhaloporphyrin complex
James E. Lyons,Paul E. Ellis +1 more
TL;DR: Irontetrakis(pentafluorophenyl)β-octabromoporphyrinato complexes have been synthesized for the first time and shown to have unprecedented catalytic activity for the reaction of molecular oxygen with isobutane to givetert-butyl alcohol as discussed by the authors.
Journal ArticleDOI
Polyfluorinated Oxaziridines: Synthesis and Reactivity
Journal ArticleDOI
Synergistic effects of encapsulated phthalocyanine complexes in MIL-101 for the selective aerobic oxidation of tetralin
TL;DR: Metal phthalocyanine complexes encapsulated in MIL-101, and used as "ship-in-a-bottle" catalysts, show outstanding TONs in the aerobic oxidation of tetralin.
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Selective low temperature hydroxylation of isobutane by molecular oxygen catalyzed by an iron perhaloporphyrin complex
James E. Lyons,Paul E. Ellis +1 more