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Journal ArticleDOI

Electrocatalysis of poly(thionine)-modified electrodes for oxidation of reduced nicotinamide adenine dinucleotide

TLDR
A poly(thionine)-modified basalplane pyrolytic graphite electrode, which can be prepared by a potential-sweep electrolysis of the corresponding monomer in acetonitrile media, shows an excellent electrocatalytic activity for NADH oxidation in phosphate buffer solutions (pH 6.9), with an activation overpotential which is ca. 400 mV lower than that of the bare electrode.
Abstract
A poly(thionine)-modified basal-plane pyrolytic graphite electrode, which can be prepared by a potential-sweep electrolysis of the corresponding monomer in acetonitrile media, shows an excellent electrocatalytic activity for NADH oxidation in phosphate buffer solutions (pH 6.9), with an activation overpotential which is ca. 400 mV lower than that of the bare electrode.

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Citations
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Journal ArticleDOI

Electrocatalytic Oxidation of NADH at Glassy Carbon Electrodes Modified with Transition Metal Complexes Containing 1,10-Phenanthroline-5,6-dione Ligands

TL;DR: In this paper, the preparation and electrochemical characterization of glassy carbon electrodes modified with 1,10-phenanthroline-5,6-dione complexes of transition metals including [M(phen-dion)3]2+ (M = Fe, Ru, Co, Cr, Ni), [Re(phendione)(CO)3Cl], and [Ru(v-bpy)2(phen -dione)](PF6)2 (V-Bpy is 4-vinyl-4'4'methyl-2,2
Journal ArticleDOI

Preparation of poly(thionine) modified screen-printed carbon electrode and its application to determine NADH in flow injection analysis system

TL;DR: The modified screen-printed carbon electrode was found to be promising as an amperometric detector for the flow injection analysis (FIA) of NADH, typically with a dynamic range of 5-100 microM.
Journal ArticleDOI

Phenazines and Polyphenazines in Electrochemical Sensors and Biosensors

TL;DR: Phenazine dyes and their polymers are reviewed with respect to their application in electrochemical sensors and biosensors, for which they are finding increasing application as redox mediators due to their unique redox and also chromatic properties as mentioned in this paper.
Journal ArticleDOI

The electrochemical polymerization of methylene green and its electrocatalysis for the oxidation of NADH

TL;DR: A poly(methylene green) thin film modified electrode was successfully prepared by means of electrochemical polymerization, which was carried out with cyclic voltammetric sweeps between −0.4 and +1.2 V (vs. SCE) at a glassy carbon base electrode in methylene green aqueous solution as mentioned in this paper.
Journal ArticleDOI

Electrocatalytic oxidation of reduced nicotinamide adenine dinucleotide (NADH) at a chlorogenic acid modified glassy carbon electrode

TL;DR: In this article, an ECE mechanism was proposed for the electrode process and cyclic voltammetry was used for the deposition process and the resulting modified electrode retains the activity of the quinone/hydroquinone group anticipated for a surface-immobilized redox couple.
References
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Journal ArticleDOI

IR absorption spectroscopic identification of electroactive and electroinactive polyaniline films prepared by the electrochemical polymerization of aniline

TL;DR: The relation entre la structure et les proprietes electrochimiques de films prepares par oxydation de l'aniline dans different solutions electrolytiques is discussed in this paper.
Journal ArticleDOI

Electrocatalytic oxidation of reduced nicotinamide coenzymes by graphite electrodes modified with an adsorbed phenoxazinium salt, meldola blue

TL;DR: Meldola Blue (7-dimethylamino-1,2-benzophenoxazine) can be adsorbed on graphite to give chemically modified electrodes as discussed by the authors.
Journal ArticleDOI

A comparative study of some 3,7-diaminophenoxazine derivatives and related compounds for electrocatalytic oxidation of NADH

TL;DR: In this paper, the electrocatalytic oxidation of reduced nicotinamide adenine dinucleotide (NADH) at chemically modified electrodes (CMEs) based on some enlarged heterocyclic aromatic structures is investigated on the basis of a phenoxazinium structure.
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