Journal ArticleDOI
Electrochemical reduction of 2-nitro- and 2,2'-dinitro-biphenyl
J.W. Rogers,Wm.H. Watson +1 more
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TLDR
The electrochemical reduction of 2-nitro- and 2,2'-dinitrobiphenyl in aprotic solvents has been studied by esr, cyclic voltammetric, polarographic and potentiostatic techniques as discussed by the authors.About:
This article is published in Analytica Chimica Acta.The article was published on 1971-03-01. It has received 8 citations till now. The article focuses on the topics: Phenylhydroxylamine.read more
Citations
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PdO/CuO Nanoparticles on Zeolite-Y for Nitroarene Reduction and Methanol Oxidation
TL;DR: In this article, the reduction of various nitroarenes to amines was achieved up to 93% under autoclave condition in isopropanol using catalytic amount of palladium oxide/copper oxide nanoparticles.
Journal ArticleDOI
Ion-selective electrode study of copper(I) complexes in acetonitrile
L. F. Heerman,G. A. Rechnitz +1 more
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Electrochemical investigations of intermediates in electroreduction of aromatic nitro and nitroso compounds in DMF
TL;DR: In this paper, the overall mechanism of electroreduction of azoxybenzene in DMF is presented and the process is found to proceed in several steps and the absorption spectrum of the radical anion obtained in the first, one electron, step of reduction is presented.
Journal ArticleDOI
Electrochemical behaviour of 2-nitrobenzidine in N,N-dimethylformamide
TL;DR: In this paper, the electrochemical reduction of 2-nitrobenzidine (I) has been investigated in N,N-dimethylformamide solutions and two well-defined polarographic waves in the ratio 1:3 were obtained.
Journal ArticleDOI
Biphenylthioureas as organocatalysts for electrochemical reductions
TL;DR: Thioureas are able to act as organocatalysts in the electrochemical reduction of aromatic carboxylates as mentioned in this paper, and they have been shown to be useful in the reduction of carboxylic acid derivatives.
References
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Journal ArticleDOI
Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
R. S. Nicholson,Irving. Shain +1 more
TL;DR: In this paper, the integral equations obtained from the boundary value problems were solved and extensive data were calculated which permit construction of stationary electrode polarograms from theory, making it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
Journal ArticleDOI
Theory of Stationary Electrode Polarography for a Chemical Reaction Coupled between Two Charge Transfers.
R. S. Nicholson,Irving. Shain +1 more
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Electron Spin Resonance and Polarographic Investigation of Substituted Nitrobenzene Negative Ions
August H. Maki,David H. Geske +1 more
TL;DR: In this paper, electron spin resonance spectra were obtained for 14 para substixted nitrobenzene mononegative ions that were generated in acetonitrile solution by electrochemical reduction within a microwave cavity.
Journal ArticleDOI
Analysis of the Electron Spin Resonance Spectra of Aromatic Nitrosubstituted Anion Radicals
TL;DR: In this paper, a good quantitative correlation was obtained between the calculated spin densities and the experimental proton hyperfine splittings for most of the compounds studied, and an equation was formulated which gave excellent predictions of the splitting from N14 nuclei in the nitro groups.
Journal ArticleDOI
Intramolecular Electron Transfer in Bis(p‐Nitrophenyl) Anions and Its Effect on Electron Spin Resonance Hyperfine Structure
John E. Harriman,August H. Maki +1 more
TL;DR: In this paper, the Anderson-Weiss model for motional narrowing has been used to calculate the hyperfine structure of electrochemically generated mononegative ion radicals of the type [Complex chemical formula] where X = CH2, S, O, CH2CH2, and X is absent.
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Intermediate products of electrochemical reduction of nitrofurans in aprotic media
J. Stradins,R. Gavars,L. Baumane +2 more