Journal ArticleDOI
Electrochemical reduction of the trimethyllead(IV) cation in seawater
TLDR
In this paper, a reduction mechanism was proposed for trimethyllead in seawater using differential pulse polarography and reverse normal pulse voltammetry (RPNV) to distinguish between inorganic and organic forms of lead.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1983-09-23. It has received 13 citations till now. The article focuses on the topics: Anodic stripping voltammetry & Polarography.read more
Citations
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Journal ArticleDOI
Determination of ionic alkyllead compounds in natural waters by differential-pulse anodic stripping voltammetry
Nevenka Mikac,Marko Branica +1 more
TL;DR: In this paper, a method for the determination of ionic alkyllead compounds in natural waters is described, which is based on the extraction of organolead compounds in the form of diethyldithiocarbamate complexes into hexane, their re-extraction with dilute nitric acid (pH 1.5), purification of the aqueous acidic solution from interfering co-extracted DICs, and determination of alkylead species by differential-pulse anodic stripping voltammetry.
Journal ArticleDOI
Oxidation processes at mercury electrodes for tetraphenyllead and related compounds in dichloromethane
Alan M. Bond,N.M. McLachlan +1 more
TL;DR: In this article, two oxidation waves are observed at mercury electrodes for tetraphenyllead in dichloromethane, and the mechanisms of the oxidation processes have been investigated by dc and differential pulse polarography.
Journal ArticleDOI
A Survey of Electrodes used for Voltammetric Analysis
Alan M. Bond,Fritz Scholz +1 more
TL;DR: A review of the most common electrodes used for voltammetric analysis can be found in this article, which is intended to assist the analyst in choosing the appropriate electrode for a particular problem.
Journal ArticleDOI
Examination of interferences in the stripping voltammetric determination of trimethyllead in seawater by polarography and mercury-199 and lead-207 nuclear magnetic resonance spectrometry
Alan M. Bond,J. R. Bradbury,Peter J. Hanna,G. N. Howell,H.A. Hudson,Stan. Strother,Maxwell J. O'Connor +6 more
TL;DR: In this article, it was shown that trimethyllead ions react with trimethyl lead cations in seawater and other aqueous media according to the equation Hg/sup 2 +/ + ((CH/sub 3/)/sub 3 /Pb)/sup +/..-->..CH/ sub 3/Hg/Sup +/+ Pb/sup 1 +/2 + 2CH/Sub 3/
Journal ArticleDOI
Reversible oxidation processes in dichloromethane for triethyl-, diethyl-, trimethyl-, and dimethyllead compounds at mercury electrodes
Alan M. Bond,N.M. McLachlan +1 more
TL;DR: In this paper, the trialkyl derivatives of R3PbX give rise to a reversible oxidation process involving transfer of one electron, exchange of alkyl groups and X− and formation of a mercury-lead complex.
References
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Journal ArticleDOI
Determination of the chemical forms of dissolved cadmium, lead and copper in seawater
Graeme E. Batley,T.M. Florence +1 more
TL;DR: In this paper, the chemical forms of Cd, Pb and Cu in seawater have been examined using a novel scheme which permits the quantification of up to seven different species of one metal.
Journal ArticleDOI
Methylation of lead in the environment.
TL;DR: The methylation of mercury and arsenic by microorganisms in the environment has been documented and well summarised, but nothing is known about the existence of organic forms of lead in the environments as a result of biotransformation.
Journal ArticleDOI
Toxicity, mutagenicity and teratogenicity of lead
TL;DR: The data on man are controversial because lead is almost never the only potentially mutagenic agent to which people are exposed in an industrial environment, and the efficiency of lead in causing such aberrations appears low compared with that of other mutagenics so that genetic effects of lead do not appear of primary concern for human health.
Journal ArticleDOI
Determination of trace metals in marine samples by anodic stripping voltammetry
TL;DR: Anodic stripping voltammetry with a polished glassy carbon electrode mercury-plated in situ was applied to the determination of trace metals in seawater, seaweeds and marine organisms as discussed by the authors.
Related Papers (5)
Oxidation processes at mercury electrodes for tetraphenyllead and related compounds in dichloromethane
Alan M. Bond,N.M. McLachlan +1 more