Journal ArticleDOI
Electrochemistry of Dinuclear, Thiolato-Bridged Transition-Metal Compounds. Part 1. Electrochemical Behaviour of ((η5-C5H5)(CO)3M(μ-SR)W(CO)5) (R: Me, M: Mo or W; R: Ph, M: W) Complexes in Non-aqueous Media.
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This article is published in ChemInform.The article was published on 1987-01-27. It has received 0 citations till now. The article focuses on the topics: Electrochemistry & Transition metal.read more
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Journal ArticleDOI
Electrochemistry of dinuclear, thiolato-bridged transition-metal compounds. Part 1. Electrochemical behaviour of [(η5-C5H5)(CO)3M(µ-SR)W(CO)5](R = Me, M = Mo or W; R = Ph, M = W) complexes in non-aqueous media
TL;DR: In this article, a destructive two-electron reduction according to an electrochemical-chemical-electrochemical process with a diffusion-controlled intervening chemical step is described, leading to the dinuclear species [W2(CO)10(µ-SMe)] on the time-scale of controlled potential electrolyses.