Showing papers in "Organometallics in 1989"

TL;DR: Synthese de PdMe 2 (tmeda) as mentioned in this paper is a partir de pdCl 2 avec le methyl lithium, subit ensuite des reactions de substitution de coordinats avec l'ethylene bis-diphenylphosphine, l'methylenediamine, and de degradation thermique.

TL;DR: In this paper, a complexe de dimethylaminomethyl-2 phenyl palladium avec le diphenylacetylene was shown to yield a hexatriene-1,3,5, de pentaalkylcyclopentadiene.

TL;DR: In this paper, the reaction of Cp' 2 Zr(CH 2 Ph) 2 (Cp'=C 5 H 4 Me) with [Cp 2 Fe][BPh 4 ] in THF produces the cationic benzyl complex, which contains a normal η 1 -benzyl ligand.

TL;DR: In this paper, the reaction of Ce(OAr)3 with LiR (R = C5Me5, 1,3-diphenyl-2-methylindene) affords novel RCe(Ar)2 (R, 2; R, 3, 4, 5; R = N(SiMe3)2, 6).

TL;DR: Etude de la reduction chimique de CO 2 par des alkylsilanes par spectrometrie RMN en utilisant un marquage isotopique au carbone 13 and au deuterium as discussed by the authors.

TL;DR: In this article, the golden yellow compound In(C5Me5) has been prepared in only 62% yield from InC1 and Li(C 5Me5), in diethyl ether and fully characterized according to its physical and solubility properties.

TL;DR: Etude de la protonation et de l'heterolyse du coordinat dihydrogene des complexes [η 5 -C 5 M 5 (Ru)(CO) 2 (η 2 -H 2 )] BF 4 et as discussed by the authors, au moyen de la spectrometrie RMN

TL;DR: In this article, the reaction de Cp 2 TiCl 2 ou Cp2 VCl 2 avec NaSMe (prepare a partir de sodium et de methyle disulfure) donne les complexes Cp(2 Ti(SMe) 2 et Cp[SMe] 2 Cp&VCl 2 Cn 2 Ti(Me) 3 Cp•Ti(SME) 2 CPN 2 Ti•SME 2

TL;DR: Les diorganogermylenes sont generes dans des matrices d'hydrocarbures a 77 K par photolyse de germano-7norbornadienes ou de (bis-trimethylsilyl) germanes as mentioned in this paper.

TL;DR: Etude de l'efficacite de divers metallocenes, alkylmetallocenes and complexes hydruro de metallocene du groupe des metaux 4-6 et de luranium et du thorium, comme catalyseurs dans le couplage deshydrogenant du phenylsilane as discussed by the authors.

TL;DR: In this paper, the SN2 mechanism was used for the oxidative addition of MeI or PhCH2Br to [MMe2(L2)] (M = Pd or Pt, L2 = phen over bpy).

TL;DR: La reaction de bis-[chloro-3 propyl] dimethyl stannane avec le bis-chlorodimethylstannyl-1,3 propane [synthetise a partir du bis-trimethystannymethyl- 1, 3 propane et de dichloro dimethyl Stannane] and le sodium donne des hexachloro (ou trichloro-1.5,9 trimethyl-1 5, 9) tristanna-1., 5,9 cyclododecanes qui for