Journal ArticleDOI
Electron spin resonance studies of conformations and hindered internal rotation in transient free radicals
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This article is published in The Journal of Physical Chemistry.The article was published on 1971-10-01. It has received 128 citations till now. The article focuses on the topics: Electron nuclear double resonance & Electron paramagnetic resonance.read more
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Analysis of the geometry of the hydroxymethyl radical by the “different hybrids for different spins” natural bond orbital procedure
John E. Carpenter,Frank Weinhold +1 more
TL;DR: In this paper, the electronic structure of the radical CH 2 OH was analyzed via the "different hybrids for different spins" natural bond orbital (DHDS NBO) procedure, which finds separate Lewis structures for each of the spin systems.
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Biomimetic nonheme iron catalysts for alkane hydroxylation
TL;DR: In this review, the efforts of the last 10 years in the development of nonheme iron catalysts are summarized and discussed.
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Stereospecific alkane hydroxylation by non-heme iron catalysts: mechanistic evidence for an Fe(V)=O active species.
Kui Chen,Lawrence Que +1 more
TL;DR: These studies serve as a synthetic precedent for an Fe(V)=O species in the oxygen activation mechanisms postulated for non-heme iron enzymes such as methane monooxygenase and Rieske dioxygenases.
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Bonding Properties of Cyclopropane and Their Chemical Consequences
TL;DR: The cyclopropane ring more closely resembles the CC double bond than the cyclobutane ring: it is a small ring with "double bond character" as mentioned in this paper, and while distinct differences in reactivity do exist, there are no fundamental differences in behavior.
Journal ArticleDOI
Chemistry of organosilicon compounds
TL;DR: In this paper, two 1,2-disilacyclobutenes were prepared by the reaction of tetramethyldisilene with acetylenes, and several reactions of these new 1 2 disilacy clobutenets including oxidation, silylene insertion, iron carbonyl insertion, and addition to acetylene and dienes are reported.
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