Journal ArticleDOI
Endo-Selective Cyclization Pathways in the Intramolecular Heck Reaction
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This article is published in Journal of the American Chemical Society.The article was published on 1995-07-01. It has received 91 citations till now. The article focuses on the topics: Heck reaction & Intramolecular force.read more
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Journal ArticleDOI
Synthesis of heterocycles via palladium-catalyzed oxidative addition.
Gilson Zeni,Richard C. Larock +1 more
Journal ArticleDOI
On the efficiency of tetraalkylammonium salts in heck type reactions
TL;DR: Under appropriate conditions, tetraalkylammonium hydrogensulfate can be just as efficient as bromide for facilitating Heck-type reactions as discussed by the authors, and an appropriate selection of the [Pd / Base / QX] catalyst system can allow this type of reactions to be efficiently realised at will, in a strictly anhydrous medium, in water-orgamic solvent mixture or in water alone.
Journal ArticleDOI
Palladacycles: Efficient New Catalysts for the Heck Vinylation of Aryl Halides
Wolfgang A. Herrmann,Christoph Brossmer,Claus-Peter Reisinger,Thomas Riermeier,Karl Öfele,Matthias Beller +5 more
TL;DR: Cyclopalladated complexes of the general formula [Pd2(μ-L)2(PC)2] (L = bridging ligand, e.g. OAc, Cl, Br, I; PC = cyclometallated P donor) are highly efficient catalysts for the Heck vinylation of aryl halides.
Journal ArticleDOI
The Domino Way to Heterocycles
Albert Padwa,Scott K. Bur +1 more
TL;DR: This mini review contains a representative sampling from the last 15 years on the kinds of reactions that have been sequenced into cascades to produce heterocyclic molecules.
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Armin de Meijere,Frank E. Meyer +1 more