Journal ArticleDOI
Étude cristallographique du tétrachloroferrate(III) d'hexaacétonitrile-fer(II)
Reads0
Chats0
TLDR
Fe 3 Cl 8 (NCCH 3 ) 6, has been crystallized from a solution of ferric chloride in acetonitrile as mentioned in this paper, and the structure has been solved from 921 reflections recorded at room temperature.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1972-11-01. It has received 24 citations till now.read more
Citations
More filters
Journal ArticleDOI
Organonitrile complexes of transition metals
Journal ArticleDOI
X‐ray diffraction study of ferric chloride solutions and hydrated melt. Analysis of the iron (III)–chloride complexes formation
Mauro Magini,Tamás Radnai +1 more
TL;DR: A series of concentrated ferric chloride solutions, both neutral and acidic, as well as the hydrated melt FeCl3⋅6H2O have been studied by x-ray diffraction as discussed by the authors, and the changes in the radial distribution curves by varying iron concentration or Cl−/Fe3+ ratio and least squares fitting of the structure functions for various solute models lead to an unambiguous conclusion with respect to the dominant species which are present in the solutions.
Journal ArticleDOI
Metal clusters in catalysis VIII Reduction of triple bonds
TL;DR: In this paper, a structural and electronic rationale is presented in a potential solution to the challenge with metal cluster catalysts, and relationships of the rationale to metal surface and metalloenzyme reactions are discussed.
Journal ArticleDOI
Direct synthesis of coordination compounds from zerovalent metals and organic ligands
TL;DR: In this article, the direct synthesis of coordination compounds from zerovalent metals and organic ligands is surveyed and described systematically, and problems of competitive reactions in the course of the direct synthesisation of ambident ligand systems are discussed.
Journal ArticleDOI
Structures, Magnetic Properties, and Reactivity Studies of Salts Containing the Dinuclear Anion [M2Cl6]2- (M = Mn, Fe, Co)
Jui-Sui Sun,Hanhua Zhao,Xiang Ouyang,Rodolphe Clérac,Jennifer A. Smith,Juan M. Clemente-Juan,‡ Carlos Gómez-Garcia,and Eugenio Coronado,Kim R. Dunbar +8 more
TL;DR: In this paper, the edge-sharing bitetrahedral anion [M2Cl6]2- with M = Mn, Fe, and Co were prepared in high yields by reaction of MCl2 with 1 equiv of chloride ion.
References
More filters
Journal ArticleDOI
Scattering factors computed from relativistic Dirac–Slater wave functions
D. T. Cromer,J. T. Waber +1 more
Journal ArticleDOI
The probability distribution of X‐ray intensities. II. Experimental investigation and the X‐ray detection of centres of symmetry
TL;DR: In this paper, the authors present a set of techniques to deal with the problem of finding the right set of skills for a given task, such as finding the most suitable skills to be used by a task.
Journal ArticleDOI
Parameter errors in polar space groups caused by neglect of anomalous scattering
Journal ArticleDOI
The use of moments of X‐ray intensity in space‐group determination. I. Derivation of theoretical moments
F. Foster,A. Hargreaves +1 more
Journal ArticleDOI
Coordination compound formed by iron trichloride dissolved in liquid hydrogen cyanide
TL;DR: In this paper, a three-dimensional X-ray crystal structure analysis has shown that the unit cell contains two FeCl 4 tetrahedrons and one Fe(NCH) 6 octahedron.